| Abstract: | Acid sulphate soils form when iron pyrite oxidises to sulphuric acid on atmospheric exposure, lowering soil pH below 4. In the Richmond River estuary, northern New South Wales, flood mitigation, drainage works and floodplain excavations have augmented acid sulphate soil formation by increasing pyrite availability for oxidation. These engineering works have facilitated the transport of acidified water and have impeded recovery from tributary acidification. The increased frequency and duration of acidification are associated with elevated concentrations of inorganic monomeric aluminium and dissolved iron, and major iron hydroxide precipitation, with deleterious effects on exposed aquatic biota and habitat. Fish kills and an outbreak of epizootic ulcerative syndrome (EUS) have been recorded from acidified sites in the estuary. |
