Internal oxidation of cast iron artifacts from an 18th-century steel cementation furnace

Heavily corroded metal artifacts recovered from the site of an 18th-century steel cementation furnace in Trenton, New Jersey, are cast iron altered by internal oxidation. The progress of the internal oxidation process was followed by comparison with the microstructure of cast iron exposed to high temperature in a wood-burning fireplace. The graphite flake structure of the cast iron allows deep, rapid penetration of oxygen that reacts at the iron–carbon interfaces within the iron to form iron oxides that eventually replace the graphite flakes. Microprobe analyses show that the silicon in the cast iron is converted to knebelite that also serves as the host for phosphorus. Sulfur dispersed in the internal oxidation product and porosity appear to be responsible for rapid rusting of the artifacts. Internal nitriding accompanies the oxidation. The Trenton artifacts are interpreted as grate bars from the fire box of a cementation furnace.