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有机-无机杂化物在铁质文物保护中的应用研究
引用本文:程蓓,何积铨.有机-无机杂化物在铁质文物保护中的应用研究[J].文物保护与考古科学,2008,20(3):6-12.
作者姓名:程蓓  何积铨
作者单位:1. 北京科技大学冶金与材料史研究所,北京,100083
2. 北京科技大学材料科学与工程学院腐蚀与防护中心,北京,100083
基金项目:"十一五"国家科技支撑计划资助项日--"文化遗产保护关键技术研究"  
摘    要:常用的铁质文物表面保护材料性能尚需完善,其与材料科学发展的关系甚密。有机-无机杂化物是材料学领域的新兴产物,它能将有机物和无机物的性能融为一体或赋予其新的性能。本工作根据溶胶-凝胶法的基本原理制备出一种有机广无机杂化物MT,经过盐雾加速腐蚀测试、电化学测试等大量模拟、对比实验,证明该文物保护剂能够有效减缓铁质文物的腐蚀,并解释了其封护保护原理。

关 键 词:铁质文物  溶胶-凝胶法  有机-无机杂化物  文物保护

Research on application of inorganic-organic hybrids to the conservation of cultural iron relics
CHENG Bei,HE Ji-quan.Research on application of inorganic-organic hybrids to the conservation of cultural iron relics[J].Sciences of Conservation and Archaeology,2008,20(3):6-12.
Authors:CHENG Bei  HE Ji-quan
Institution:CHENG Bei~1 HE Ji-quan~2
Abstract:Commonly used conservation materials for ion relics need to be improved,and development of such ma- terials has very close relationship to the material sciences,inorganic-organic hybrids are new products of material science that mingle the properties of organic and inorganic materials,leading to new functions.In this article an in- organic-organic hybrid material PMTES/SiO_2(or simply,MT)was prepared following basic rules for making sol- gels...In comparison tests,for example using salt mist accelerating corruption test and electrochemistry test,it has been shown that the hydrid is effective in lowering the corrosion rate of iron cultural relics.The preserving mecha- nism was explained.
Keywords:Cultural iron relics  sol-gel process  Inorganic-organic hybrid  Conservation of cultural relics
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