| Abstract: | Some archaeological silver objects are found to be brittle. The brittleness is a consequence of long‐term corrosion and microstructural changes. The types and mechanisms of embrittlement are defined and explained. The severity of embrittlement is increased by a larger grain size and by synergistic action of corrosion‐induced and microstructurally induced embrittlement. Micromechanical models of fracture that incorporate the grain size provide an insight into these effects and help to explain why severely embrittled objects are frangible or even friable. |
