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Influence of Taoism on the invention of the purple pigment used on the Qin terracotta warriors
Authors:Z. Liu  A. Mehta  N. Tamura  D. Pickard  B. Rong  T. Zhou  P. Pianetta
Affiliation:1. Stanford Synchrotron Radiation Lab, Stanford University, Stanford, CA 94305, USA;2. Ernest Orlando Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720, USA;3. Department of Electrical Engineering, Stanford University, Stanford, CA 94305, USA;4. The Museum of Terracotta Warriors and Horses of Emperor Qin Shihunag, Lintong 710600, Xi''an, China
Abstract:Until the 19th century, most pigments were based on naturally occurring colored minerals and dyes, with three significant exceptions: Egyptian Blue, Chinese Blue/Purple and Maya Blue. The former two are alkaline-earth copper silicates, and because of this similarity it has been proposed that the Chinese pigments were derived from Egyptian Blue. Herein, we analyzed clumps of pigment from the Qin warriors and discovered that in spite of the structural similarity to Egyptian Blue, the micro-structural morphology of Chinese Purple is very different. Therefore, we believe that the synthesis technology for the Chinese pigments was a by-product of high-refractive index glasses (artificial jades) produced by Taoist monks. Further, the disappearance of these pigments from Chinese art and monuments concurrently with the decline of Taoism not only substantiates the link between the two, but also gives a striking example of how cultural changes in the society affected the scientific developments in ancient China.
Keywords:Chinese Blue   Chinese Purple   Egyptian Blue   Maya Blue   Pigment   Taoism   Chinese glass   Silk road
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