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Lapis lazuli usage for blue decoration of polychrome painted glazed pottery: a recurrent technology during the Middle Ages in Apulia (Southern Italy)
Authors:I.M. Catalano  A. Genga  C. Laganara  R. Laviano  A. Mangone  D. Marano  A. Traini
Affiliation:1. Dipartimento di Fisica, Università di Bari, via Orabona 4, 70126 Bari, Italy;2. Dipartimento Scienza dei materiali, Università di Lecce, via Arnesano, 73100 Lecce, Italy;3. Dip. Beni Culturali e Scienza del Linguaggio, Università di Bari, Ateneo, 70121 Bari, Italy;4. Dipartimento Geomineralogico, Università di Bari, via Orabona 4, 70126 Bari, Italy;5. Dipartimento di Chimica, Università di Bari, via Orabona 4, 70126 Bari, Italy
Abstract:Seven fragments of atypical proto-majolica from the archaeological site of Siponto (Manfredonia, Foggia) were analysed by chemical and physical methods. All fragments have blue, brown and yellow painted decorations. Raman microscopy and Scanning Electron Microscopy–Energy Dispersed Spectroscopy (SEM–EDS) investigations identified the blue pigment to lapis lazuli. We previously identified this mineral in the blue coloration of the tin–lead glaze of proto-majolica finds at other Medieval sites in Apulia (Castel Fiorentino and Lucera). The discovery of the fragments from Siponto, in spite of their peculiar technological-decorative features, proves that the use of lapis lazuli as a ceramic pigment was not an isolated occurrence, but was quite common in the Middle Ages in the production of typologically heterogeneous ceramics in Southern Italy.
Keywords:Lapis lazuli   Medieval glazed pottery   Proto-majolica   SEM&ndash  EDS   Raman microscopy   Atomic spectroscopy   Multivariate statistical analysis
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