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LEAD GLAZES IN ANTIQUITY—METHODS OF PRODUCTION AND REASONS FOR USE*
Authors:M. S. TITE  I. FREESTONE  R. MASON  J. MOLERA  M. VENDRELL-SAZ  N. WOOD
Abstract:Transparent high lead and tin-opacified lead-alkali glazes have been extensively used throughout Europe and the Near East from their first appearance in the Roman era and the tenth- to eleventh-century Islamic world, respectively, up until the present day. Using, to a large extent, information which is widely scattered through a diverse range of literature, the methods employed in the production of these two glaze types are first outlined and their merits are then compared with those of alkali glazes in terms of ease of preparation of the glaze mixture, ease of application of the glaze, ease of firing, cost of production, glaze-body fit and visual appearance. The principal advantages of transparent high lead glazes as compared to alkali glazes are shown to be ease of preparation and application of the glaze suspension, low susceptibility to glaze ‘crazing’ and ‘crawling’ and high, optical brilliance. Factors that influence the choice of tin-opacified lead-alkali glazes include ease of production of tin oxide by melting tin and lead metals together; a reduced risk of reduction of lead oxide to lead metal and consequent blackening of the glaze; and, again, low susceptibility to ‘crazing’ and ‘crawling’. Limits of current knowledge regarding these two glaze types and requirements for future research are outlined.
Keywords:EUROPE  NEAR EAST  ROMAN  ISLAMIC  BYZANTINE  MEDIEVAL  POST-MEDIEVAL  SCANNING ELECTRON MICROSCOPY  X-RAY SPECTROMETRY  CERAMICS  GLAZE  ALKALI  LEAD  TIN  OPACITY  TECHNOLOGY
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