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X-RAY FLUORESCENCE AND DENSITY MEASUREMENTS ON SURFACE-TREATED ROMAN SILVER COINS*
Authors:C. N. ZWICKY-SOBCZYK  W. B. STERN
Abstract:Some 630 Roman silver coins excavated at Augusta Raurica (Switzerland) have been analysed by non-destructive X-ray fluorescence and X-ray diffraction. Furthermore, the density and the weight have been determined. The measured average density of plated and massive depletion-silvered coins is lower than the density calculated from the chemical composition, whereas massive coins display equal values for both of the densities. Based on experimental X-ray investigations of modern silver (tempering, acid treatment, production of corrosion layers), the nature of corrosion products on silver, their impact on surface analysis, and aspects of wearing-off by circulation are briefly discussed.
Keywords:SWITZERLAND  AUGUSTA RAURICA, ROMAN  ENERGY-DISPERSIVE X-RAY FLUORESCENCE  NON-DESTRUCTIVE ANALYSIS  X-RAY DIFFRACTION  COINS  SILVER  CHEMICAL COMPOSITION  CORROSION  DENSITY  DEPLETION-SILVERING  PLATING  WEIGHT
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