Strontium isotope analysis in ancient glass from South Asia using portable laser ablation sampling

In order to carry out strontium (Sr) isotope analysis, glass artefacts from South Asia were sampled with portable laser ablation (pLA), a relatively novel sampling technique that leaves damage invisible to the naked eye. Subsequently, thermal ionization mass spectrometry (TIMS) was used to obtain Sr isotope ratios after sample dissolution and separation. In this study, the goal was twofold: to determine whether the measurements of Sr isotope ratios were impacted by using a portable laser as a sample tool; and to assess the pertinence of using Sr isotope ratios to provenance Indian glass. Despite a deterioration in the precision of the measurement of the Sr isotope ratios for artefacts sampled with pLA compared with the traditional sampling method, the Sr isotope ratios of certain Indian glass are so different that this does not affect their separation but a comparison of data sets obtained using standard methods and pLA might be challenging.     

Petrochemical Identification and Insights on Chronological Employment of the Volcanic Aggregates Used in Ancient Roman Mortars

Through the assistance of trace element and petrographic analyses on 14 samples of mortar aggregates from Roman monuments, including the Porticus Aemilia, the Temple of Concordia, the Temple of the Dioscuri, Temple B and other structures of the Area Sacra di Largo Argentina, and the Villa di Livia, we establish the source area and we investigate the chronological employment of the volcanic materials used in ancient Rome's masonry. In contrast to previous inferences, the petrochemical data presented here show that systematic exploitation of the local ‘Pozzolane Rosse’ pyroclastic deposit has occurred since the early development of concrete masonry, at the beginning of the second century bc , through the early Imperial age. Subsequently, exploitation was extended to the overlying Pozzolane Nere and Pozzolanelle deposits. Only during the early phase of development of the concrete masonry in Rome, volcaniclastic sediments outcropping near the construction sites were mixed with the sieved remains of the tuff employed as the coarse aggregate, to produce the fine aggregate. The results of the study on the investigated monuments suggest the possibility of establishing the chronological identification of three different types of mortars, as a function of the composition of the volcanic material employed in the fine aggregate, which, when implemented by future studies, may contribute to the dating of monuments and archaeological structures.     

The Architectural Reuse of Roman Marble and Stone Spolia in the Early Medieval Monte Sorbo Church (Sarsina,Central Italy)

We present the results of a multi‐method archaeometric study concerning the architectural elements reused in Monte Sorbo church (Sarsina, central Italy) between the eighth and ninth centuries AD . The provenance study has focused on classical marbles and stones, which clearly do not originate from the local Apennine geological formations and are thought to come from extra‐regional sources. A large fraction of the tested marbles is from Asia Minor, coming from both the Proconnesian district on Marmara Island and, probably, the Hasançavuslar site near Ephesus (Greco scritto). Of the four remaining marbles investigated, one is from the Carrara district and three are from different Greek quarrying areas, such as Mount Pentelikon (Athens) and the Thasos and Paros islands. The data also highlight the reuse of decorated gravestones made of Pietra di Aurisina as architectonic elements. This limestone is a fossiliferous carbonate stone outcropping in the Trieste Karst region (north‐eastern Italy), which was exploited by both the Romans and the Byzantines. The assignment of all of the columns of the central nave to the same source area provides an argument in favour of their provenance from a single monument, which was probably located in Sarsina or Ravenna, with the ‘colourful taste’ that is typical of the late Antonine and Severian periods.     

NMR as a new tool for cultural heritage application: The provenance of ancient white marbles

Identifying the origin of marble used in antiquity brings back to light details of the economic, social and political organization of classical societies, and characterizing in depth the chemistry of marble is key to discovering its provenance. Beyond X‐ray diffraction, which could reveal the presence of discriminant secondary crystalline phases and the quantification of accessory minerals combined with a multivariate analysis approach, solid‐state nuclear magnetic resonance (NMR) enables one to recognize the local structure arrangement of both crystalline and amorphous materials by looking at one or more selected atoms. In present paper targets the ¹³C nuclide, and thus the major component of marble, calcium carbonate. Whatever their geological origin, marbles ¹³C‐NMR spectra present only one resonance corresponding to the carboxyl function whose intensity and line width vary from one marble to another. If the variation of the NMR signal intensity observed is the result of great T1 variations (from 220 to 5300 s) and is linked to iron content, the line width reflects defects in the calcite crystal in which calcium has been replaced by another element such as magnesium, aluminium or strontium. The specific profile of the NMR signal has been used successfully to help determine the origin of some archaeological items.     

The Karschau Ship, Schleswig-Holstein: Dendrochronological Results and Timber Provenance

The felling of the oak trees used to build the Karschau ship took place in or around the AD 1140s. The tree-ring curves from the oak planks from the Karschau Ship match best with site-means from Odense, a medieval town on the island of Funen, Denmark. New research being carried out by the author is allowing the determination of the provenance of ancient oak to a more local level. Through this dendrochronological research, it is now possible to differentiate between small regions of timber sources for shipbuilding, allowing a more nuanced interpretation.
© 2006 The Author     

The provenance and distribution of Early Bronze ceramics in the Kolyaei Plain,central Zagros,Iran

Within Iran, there is little archaeological evidence for relationships between newly arrived Early Trans-Caucasian (ETC) or Kura-Araxes settlers and earlier inhabitants and contact with neighbouring cultures, or for their apparently abrupt end. Based on the evidence, the Iranian Kura-Araxes was not a simple ‘copy' of the Caucasian Kura-Araxes package. Ceramic traditions show local peculiarities, and all are elements suggesting that the Kura-Araxes traditions went through processes of adaptation, change and re-elaboration according to local tastes and technologies. In this study, an archaeometric approach to ceramics in the Kolyaei Plain of central Zagros contributes to the discussion of contact and exchange between indigenous communities and several cultural spheres of influence on the Early Bronze Age (beginning in the fourth millennium bce ). Morphological data, as well as the mineralogical and chemical composition of ceramics, were applied to determine the major and trace elements of the pottery shards. Based on the trace element profiles, it can be suggested that all the pottery shards are in the same group and they strongly are local products. The ceramic provenance indicates the same patterns of material interactions during the ETC or Kura-Araxes in all the sites within the Kolyaei Plain.     

Geological constraints on the use of lead isotopes for provenance in archaeometallurgy

The first part of this paper is a brief critical history of the use of Pb isotopes for inferring the geological provenance of archaeological materials, with an emphasis on non-ferrous metals. The second part examines variation in the Pb isotopic ratios of oxide and sulphide ore minerals in selected regions of the world, and relates these to the geological histories of ore formation in each region. This exercise shows that in regions where most ore deposits are of similar geological age—as in the Andes, Europe and the circum-Mediterranean—provenance analysis with Pb isotopes is inherently difficult because geographically distant sources often exhibit similar isotopic ratios. Conversely, regions with many periods of ore formation—such as southern Africa—appear to be very promising regions for future studies of provenance with Pb isotopes. The wider implication of this exploratory survey is that archaeologists should carefully consider the range and clustering of geological Pb isotopic ratios in their regions of interest before investing large sums of money into Pb isotopic analysis of artefacts.     

Ancient ‘Black’ Decorative Stones and the Ephesian Origin of Sculptural bigio antico

Isotopic, EPR and petrographic studies aimed at establishing the provenance of sculptural bigio antico are reported, including 18 possible quarry sites and 21 ancient sculptures. The results demonstrate that the Belevi quarry, north‐east of Ephesos, above the more famous white marble quarry, was the major source of this marble. Nineteen artefacts belong to Belevi, whereas the precise origin of the remaining two is unknown, but must probably be found within the same area. The peculiar distribution of δ¹³C values both for Belevi and artefacts was crucial for inferring the correct provenance, subsequently confirmed by additional analytical and petrographic data.     

Geochemical Methods for Sourcing Lava Paving Stones from the Roman Roads of Central Italy

This paper documents the results of in situ analysis of 306 lava paving stones and 74 possible source rocks using pXRF. Data were collected from sites both in the city of Rome—on major roads beyond the city (including the Viae Flaminia, Cassia, Clodia, Praenestina and Appia)—and in the city of Ostia. Comparison of the pXRF data with lava compositional data from the geological literature allows broad identification of possible sources. The results point to quite distinctive patterns of exploitation for the city of Rome and Ostia, utilizing the Alban Hills lava flows, and the roads of the middle Tiber Valley, drawing on lava flows associated with the Vico and Sabatini volcanoes. The results show the potential of pXRF to produce data to elucidate the exploitation of lava flows for paving the Roman roads.     

A dendrochronological investigation of stringed instruments from the collection of the Cherubini Conservatory in Florence,Italy

A total of forty-nine stringed instruments of the Conservatory Cherubini collection, at the Musical Instruments Department of the Accademia Gallery in Florence, were submitted to a dendrochronological investigation in order to date them, check the validity of their attribution and to find out more about their construction characteristics. Thirty-seven instruments were successfully dated, thereby determining the terminus post quem date of manufacture. The correlation values of the statistical cross-dating tests were generally very high. The dendrochronological analyses determined which instruments had been made from wood of the same provenance and, in some cases, from the same tree trunk. The mean chronology built from the musical instrument series, named “Accademia Master Chronology”, is 558 years long and dates from 1396 to 1953AD. The interval between the youngest ring dated dendrochronologically and the given date of manufacture increased constantly in the course of the centuries, from a mean value of just over eleven years for instruments built in the eighteenth century, to nearly 74 years in the twentieth century, when the use of old wood from other artefacts became more frequent. Furthermore, in the Cherubini Collection, the average tree rings on violins are smaller than those of other stringed instruments; in fact, they increase in proportion to instrument size and are widest in cello and double bass.