Application of fluorescence lifetime measurements on single petroleum-bearing fluid inclusions to demonstrate multicharge history in petroleum reservoirs

Petroleum-bearing fluid inclusions emit fluorescent light when excited with UV or visible light. The fluorescence decay time of the emission is dependent upon the wavelengths of the excitation and emission light, and the chemical composition of the petroleum oil. In general heavy oils have short lifetimes, whereas the emission from light oils is much longer lived. One can thus use plots of the fluorescence lifetime versus emission wavelength ( τ – λ plots), to show even subtle changes in the chemical composition of the entrapped oil. As a consequence, these τ – λ plots can be used for fluid inclusion research to discriminate different oil populations in situ . In particular, it is demonstrated that τ – λ plots discriminate two sets of inclusion oils in each of four North Atlantic basins [Jeanne d'Arc Basin (Newfoundland), Porcupine Basin (Ireland), Clair field West of Shetland (UK) and Kangerlussuaq Basin (East Greenland)] where multistage oil charge is inferred from other geological evidence.     

FT-IR measurements of petroleum fluid inclusions: methane, n-alkanes and carbon dioxide quantitative analysis

A recent advancement in petroleum geochemistry is to model fossil oil composition using microthermometric and volumetric data acquired from individual fluid inclusion analysis. Fourier transform infrared (FT‐IR) microspectroscopy can record compositional information related to gas (CH₄ and CO₂) and alkane contents of petroleum inclusions. In this study, a quantitative procedure for FT‐IR microspectrometry has been developed to obtain, from individual fluid inclusions, mol percentage concentrations of methane, alkanes and carbon dioxide as constraints to thermodynamic modelling. A petroleum inclusion in a sample from the Québec City Promontory nappe area was used as standard to record a reference spectrum of methane. The analytical procedure is based on the measurement of CH₄/alkane and CH₄/CO₂ band area ratios. CH₄/alkane infrared band area ratio is obtained after spectral subtraction of the reference methane spectrum. This area ratio, affected by absolute absorption intensities of methane, methyl and methylene, provides a molar CH₄/alkane ratio. Methyl/methylene ratio (CH₂/CH₃) ratio is obtained following procedures established in previous work. CO₂/CH₄ concentration ratio is estimated from relative absolute absorption intensities. Application to natural inclusions from different environments shows good correlation between FT‐IR quantification and PIT (petroleum inclusion thermodynamic) modelling.     

Effects of episodic fluid flow on hydrocarbon migration in the Newport‐Inglewood Fault Zone,Southern California

Fault permeability may vary through time due to tectonic deformations, transients in pore pressure and effective stress, and mineralization associated with water‐rock reactions. Time‐varying permeability will affect subsurface fluid migration rates and patterns of petroleum accumulation in densely faulted sedimentary basins such as those associated with the borderland basins of Southern California. This study explores the petroleum fluid dynamics of this migration. As a multiphase flow and petroleum migration case study on the role of faults, computational models for both episodic and continuous hydrocarbon migration are constructed to investigate large‐scale fluid flow and petroleum accumulation along a northern section of the Newport‐Inglewood fault zone in the Los Angeles basin, Southern California. The numerical code solves the governing equations for oil, water, and heat transport in heterogeneous and anisotropic geologic cross sections but neglects flow in the third dimension for practical applications. Our numerical results suggest that fault permeability and fluid pressure fluctuations are crucial factors for distributing hydrocarbon accumulations associated with fault zones, and they also play important roles in controlling the geologic timing for reservoir filling. Episodic flow appears to enhance hydrocarbon accumulation more strongly by enabling stepwise build‐up in oil saturation in adjacent sedimentary formations due to temporally high pore pressure and high permeability caused by periodic fault rupture. Under assumptions that fault permeability fluctuate within the range of 1–1000 millidarcys (10^?15–10^?12 m²) and fault pressures fluctuate within 10–80% of overpressure ratio, the estimated oil volume in the Inglewood oil field (approximately 450 million barrels oil equivalent) can be accumulated in about 24 000 years, assuming a seismically induced fluid flow event occurs every 2000 years. This episodic petroleum migration model could be more geologically important than a continuous‐flow model, when considering the observed patterns of hydrocarbons and seismically active tectonic setting of the Los Angeles basin.     

1944年《美国对外石油政策》报告探析

1944年4月11日美国国务院公布了《美国对外石油政策》报告。该报告将石油利益确定为美国国家安全利益的核心,其主要内容是:在中东地区推行"门户开放"政策,将大西洋宪章的"机会均等"原则运用于战后美国对外石油资源的争夺中;提出了美国对外石油供应的"半球"石油政策,即"东半球"的石油主要由中东地区供应,"西半球"的石油由美洲地区供应。美国对外石油政策的目标是攫取和控制中东地区的石油资源,保护美国国内的石油资源储备。考察《美国对外石油政策》报告的主要内容及其形成的过程,揭示美国战后对外石油政策的本质,有益于全面认识美国构建战后石油安全战略的全貌。     

Bilateral Trade and Trade Frictions between China and Japan, 1972–2012

A specialist on Japan’s economic relations with China offers an overview of the two countries’ bilateral trade from 1972 to the present. The bilateral trade has evolved from inter-industry trade (in which China exported primary goods and Japan exported machinery) to intra-industry trade (in which both sides mainly exported machinery to the other). Compared with incidents of acute trade frictions involving Japan and the U.S. and China and the U.S., the trade relations between Japan and China have remained relatively calm, serving as a stabilizer for the broader relationship involving the two countries. Nonetheless, the author documents a recent intensification of trade frictions, as it becomes increasingly evident that China has caught up with (and now surpassed) Japan as an economic power. The analysis shows that, up to 1993, most of the trade disputes involved Japan’s exports to China, and were raised by the Chinese side. Since 1994, most trade disputes were over Japan’s imports from China, and were raised by the Japanese side. Journal of Economic Literature, Classification Numbers: F140, F510. 3 figures, 27 references.     

Reconstruction of palaeo-burial history and pore fluid pressure in foothill areas: a sensitivity test in the Hammam Zriba (Tunisia) and Koh-i-Maran (Pakistan) ore deposits

The burial and pore fluid pressure history of fluorite ore deposits is reconstructed: (i) at Hammam Zriba–Djebel Guebli along the eastern margin of the Tunisian Atlas; and (ii) at Koh‐i‐Maran within the northern part of the Kirthar Range in Pakistan. Both the deposits are hosted by Late Jurassic carbonate reservoirs, unconformably overlain by Late Cretaceous seals. Microthermometric analyses on aqueous and petroleum fluid inclusions with pressure–volume–temperature–composition (PVTX) modeling of hydrocarbon fluid isochores are integrated with kinematics and thermal 2D basin modeling in order to determine the age of mineralization. The results suggest a Cenozoic age for the fluorite mineralization and a dual fluid migration model for both ore deposits. The PVTX modeling indicates that the initial stage of fluorite cementation at Hammam Zriba occurred under fluid pressures of 115 ± 5 bars and at a temperature close to 130°C. At Koh‐i‐Maran, the F3 geodic fluorite mineralization developed under hydrostatic pressures of 200 ± 10 bars, and at temperatures of 125–130°C. The late increase in temperature recorded in the F3 fluorites can be accounted for by rapid rise of hotter fluids (up to 190°C) along open fractures, resulting from hydraulic fracturing of overpressured sedimentary layers.     

Relationship between deformation bands and petroleum migration in an exhumed reservoir rock,Los Angeles Basin,California, USA

An oil‐bearing sandstone unit within the Monterey Formation is exposed in the Los Angeles Basin along the Newport‐Inglewood fault zone in southern California. The unit preserves structures, some original fluids, and cements that record the local history of deformation, fluid flow, and cementation. The structures include two types of deformation bands, which are cut by later bitumen veins and sandstone dikes. The bands formed by dilation and by shear. Both types strike on average parallel to the Newport‐Inglewood fault zone (317°–332°) and show variable dip angles and directions. Generally the older deformation bands are shallow, and the younger bands are steep. The earlier set includes a type of deformation band not previously described in other field examples. These are thin, planar zones of oil 1–2 mm thick sandwiched between parallel, carbonate‐cemented, positively weathering ribs. All other deformation bands appear to be oil‐free. The undeformed sandstone matrix also contains some hydrocarbons. The oil‐cored bands formed largely in opening mode, similar to dilation bands. The oil‐cored bands differ from previously described dilation bands in the degree of carbonate cementation (up to 36% by volume) and in that some exhibit evidence for plane‐parallel shear during formation. Given the mostly oil‐free bands and oil‐rich matrix, deformation bands must have formed largely before the bulk of petroleum migration and acted as semi‐permeable baffles. Oil‐cored bands provide field evidence for early migration of oil into a potential reservoir rock. We infer a hydrofracture mechanism, probably from petroleum leaking out of a stratigraphically lower overpressured reservoir. The deformation bands described here provide a potential field example of a mechanism inferred for petroleum migration in modern systems such as in the Gulf of Mexico.     

日本“走入非洲”的石油能源战略

非洲石油经济的依附性发展是日本“走入非洲”石油能源战略出台和实施的重要原因之一。具体表现为：非洲产油国以石油开采和出口为主的依附性经济结构是石油资源极度匮乏的日本出台这一战略的主要原因;非洲产油国工业制成品严重依附发达国家,是以出口为制造业主导的日本出台这一战略的重要原因;非洲产油国对发达国家的财政依附及依附性的转化,则是这一战略出台和实施的重要条件。不考虑其他因素,单从非洲石油经济的依附性发展角度看,日本“走入非洲”石油能源战略的前景并非一片光明,而是喜忧参半,前途未卜。     

Petroleum type determination through homogenization temperature and vapour volume fraction measurements in fluid inclusions

Physical parameters of petroleum‐bearing fluid inclusions such as bulk density (ρ), molar volume (V_m), vapour volume fraction (?_vap) and homogenization temperature (T_h) are essential information to model petroleum composition (x) in inclusions and to reconstruct palaeotemperature and palaeopressure of trapping. For the main petroleum types contained in a fluid inclusion, we can follow how ?_vap and T_h are simultaneously influenced by a change of bulk density in a ?_vap versus T_h projection. We have correlated T_h and ?_vap for different petroleum compositions for a large range of bulk density values. However, postentrapment events under new pressure (P) and temperature (T) conditions can greatly modify the initial fingerprints of physical conditions and chemical composition of fluid inclusions. Re‐equilibration is frequent, especially in the case of fragile minerals. Stretching and leakage phenomenon have been simulated using the Petroleum Inclusion Thermodynamics (pit ) software, from virtual petroleum inclusions with known hydrocarbon composition. The aim of these simulations is to understand how ?_vap and T_h evolve with these re‐equilibration phenomena, with respect to the oil composition. Results of stretching simulations show a characteristic increase of T_h and ?_vap along correlation curves, with the curve shape dependent on petroleum composition. Leakage simulations show an increase of T_h and a smaller increase or even a decrease in ?_vap. Consequently, the better preserved inclusions in a given population can be presumed to be those that have the lowest T_h. Applications of T_h and ?_vap measurements of natural inclusions in calcite and in quartz showed that the fragility of the host mineral is a key factor allowing the recording of post‐entrapment events. Inclusions that have stretched or leaked are identified and the best preserved inclusions selected for evaluation of P–T–x trapping conditions. Moreover, petroleum types trapped in inclusions can be identified from ?_vap and T_h measurements without compositional modelling.     

Generation and accumulation of oil and condensates in the Wenchang A Sag, western Pearl River Mouth Basin, South China Sea

The Pearl River Mouth (PRM) Basin is one of four Cenozoic basins in the South China Sea, and the Wenchang A Sag is a secondary depression in the western part of the basin. Both the Wenchang and Enping formations contain good source rocks in the western PRM Basin; however, only the latter has been considered a likely source of the discovered oil and gas. New data from fluid inclusions and the analysis of oil–source rock correlations for the WC10-3 oil and gas pools indicate two stages of petroleum charging, the earlier originating from the Wenchang Formation and the later from the Enping Formation. Kinetics of petroleum generation and structural evolution modeling were employed to further investigate the mechanism of formation of the WC10-3 oil and gas pools. It was shown that the crucial condition for the formation of pools is the time of development of the structural trap. The Wenchang Formation source rocks generated oil from 25 to 14 Ma in the possible source area of the WC10-3 oil and gas pools in the Wenchang A Sag, so that only traps formed earlier than this period could capture oil sourced by the Wenchang Formation. The Enping Formation source rock experienced its oil window from 18 Ma to the present with the main stage of oil generation from 15 to 5 Ma. During this period structural traps in the sag continued to form until movements became weak, so that most pools in the Wenchang A Sag originated from the Enping Formation source rock. The likely dissipation of oil and gas from the earlier stage of charging should be taken into account in assessing the oil potential of the Wenchang A Sag.