Elemental Analysis of Ochre Outcrops in Southern British Columbia,Canada

Ochre is a red mineral pigment that was a key element of social and ceremonial practices among cultures of the Pacific Northwest Coast. It is recovered routinely from archaeological excavations, is visible as pigment for pictographs, and is described in the historical record as a trade item and component of ceremonial practices. Despite its ubiquity in the archaeological record, it is difficult to interpret its significance without first understanding the nature of its procurement and distribution. As a step towards identifying procurement practices, trade and resource use, it is necessary to thoroughly characterize ochre outcrops with regard to their intra‐source and regional variability. We analysed ochre from three outcrops using INAA to determine their elemental chemistry. The purpose of this study is threefold: to provide an example of the range of elemental variability within and between outcrops, to illustrate the effect of scale and geomorphological processes on elemental compositions and statistical interpretation, and to create a database of known deposits in southern British Columbia. The results demonstrate that ochre deposits may be differentiated on the basis of their chemistry, and that conservative statistical interpretation needs to be employed to assess true elemental variability within and between ochre deposits and regions.     

Ochre,Ground Stone,and Wrapping the Dead in the Late Epipalaeolithic (Natufian) Levant: Revealing the Funerary Practices at Shubayqa 1, Jordan

The appearance of rich and diverse funerary practices is one of the hallmarks of the Late Epipalaeolithic Natufian in the Levant. Numerous burials at a number of sites excavated mostly in the Mediterranean zone of the southern Levant have fed into the interpretation of the Natufian as a sedentary society of complex hunter-gatherers. Here, we report on the human remains recovered from Shubayqa 1, a well-dated early to late Natufian site in northeast Jordan. The majority of the minimum of 23 individuals that are represented are perinates and infants, which represents an atypical population profile. Ground stone artifacts and traces of colorants are associated with some of these individuals, providing a rare insight into funerary treatment of subadults in Natufian contexts. We interpret the Shubayqa 1 evidence in the light of current and ongoing debates concerning Natufian burial practices and the issue of social complexity.     

Raman spectroscopy and scanning electron microscopy confirm ochre residues on 71 000‐year‐old bifacial tools from Sibudu,South Africa

Micro‐residue analysis of stone tools is generally performed with optical light microscopy and the visual observations are then compared with experimental, replicated pieces. This paper complements such archaeological research by providing physico‐chemical evidence. Raman spectroscopy and scanning electron microscopy have been used to confirm the presence of hematite on red‐stained medial and proximal parts of 71 000‐year‐old Still Bay bifacial tools from Sibudu Cave. Our results confirm the conclusion from optical light microscopy that the tools were hafted with an ochre‐loaded adhesive. However, we point to some instances when hematite residues are incidental or may be inclusions in the rock used to make the stone tools.     

合肥北门大房郢水库汉代墓葬出土红色颜料研究

中国先民使用红色颜料的历史悠久,最早可以追溯到新石器时期,它在中国的物质生产和文化发展中发挥了重要的作用。在2006年发掘的大房郢水库汉墓群中发现了两种红色颜料,通过采用X射线衍射、X射线荧光分析和傅立叶变换红外分析等分析方法对其进行了研究,发现它们是赤铁矿(α-Fe2O3)和朱砂(HgS),其用途分别为制造化妆品和红色漆膜。     

Red ochre decorations in Spanish Neolithic ceramics: a mineralogical and technological study

Some Neolithic ceramics from south-eastern Spain have red to brown external decorations called “almagras” (red ochre). The pigment layer is essentially composed of a mixture of clay and iron oxides: haematite (red) and maghemite (brown). It is suggested that maghemite was formed during the firing process of ceramic in a reducing atmosphere. Several laboratory tests have been carried out to obtain maghemite by adding charcoal or pinewood sawdust to similar ceramic pastes. In fact, maghemite was formed, even when the piece was simply covered with pinewood sawdust before firing. The diverse original red colours are due to variations in iron oxide (or calcite) content and to redox conditions in the firing procedure. Brown- coloured ceramics owe their colour to maghemite and must be considered as a “fabrication defect”, due to the position of the ceramic piece in a zone where a reducing atmosphere prevailed in the course of firing.     

First large‐scale provenance study of pigments reveals new complex behavioural patterns during the Upper Palaeolithic of south‐western Germany

The use of red iron‐based earth pigments, or ochre, is a key component of early symbolic behaviours for anatomically modern humans and possibly Neanderthals. We present the first ochre provenance study in Central Europe showing long‐term selection strategies by inhabitants of cave sites in south‐western Germany during the Upper Palaeolithic (43–14.5 ka). Ochre artefacts from Hohle Fels, Geißenklösterle and Vogelherd, and local and extra‐local sources, were investigated using neutron activation analysis (NAA), X‐ray diffraction (XRD) and scanning electron microscopy (SEM). The results show that local ochre sources were continuously and systematically accessed for c.29 500 years, with periodic events of long‐distance (about > 300 km) ochre acquisition during the Aurignacian (c.35–43 ka), suggesting higher mobility than previously suspected. The results reveal previously unknown long‐term, complex spatio‐temporal behavioural patterns during the earliest presence of Homo sapiens in Europe.     

Processing ochre in the Middle Stone Age: Testing the inference of prehistoric behaviours from actualistically derived experimental data

The increase in the presence of ‘ochre’ in African Middle Stone Age contexts has been employed, together with changes in human biology and behaviour, to support the hypothesis that ‘modern’ cognitive abilities arose in Africa. The consistent exploitation of ochre is interpreted as evidence for colour symbolism, a proxy for the origin of language and a defining aspect of ‘modern’ human behaviour. That humans attached considerable symbolic value to red ochres in particular is illustrated by ethnographic examples. Research has shown that wear patterns indicative of abrasive processing methods prevail, but many archaeological specimens also exhibit wear traces not derived from grinding or scraping alone. Building on former research, I present here the results of an experimental study devised to infer the methods employed to extract powder from ochre during the African Middle Stone Age. The prospect of ascertaining at least some of the likely uses to which ochre may have been put, is also explored. I conclude that functional data derived from actualistic experiments can be used to enhance our understanding of some aspects of prehistoric behaviour.     

A multi-technique characterization and provenance study of the pigments used in San rock art, South Africa

During the course of a conservation project at the rock shelter known as RSA TYN2 (Eastern Cape, South Africa), a sample of 33 painted fragments that had become detached from the wall were collected. They have been studied using a multi-technique approach (optical microscopy, SEM-EDS, Raman spectroscopy and FTIR), with the aim of achieving a better understanding of their paint stratigraphy, composition, and provenance. The paintings are on a Clarens Formation sandstone and are embedded in calcium sulphates and oxalates. The red pigments show two different ‘hues’, corresponding to two different compositions. The light red is a red ochre, possibly pure, which is probably a degradation product of the Clarens Formation sandstone. The dark red contains more iron oxides and may be a mixture between the red ochre and pure haematite. Because of the presence of crystals which may be identified as augite we suggest this haematite came from the basaltic upper part of the Drakensberg, at least 4 km away from the rock shelter. The black pigments have been identified as carbon black, that is to say, incomplete combustion products of organic compounds, and are radiocarbon dated to between 2120 and 1890 cal BP, making these samples the oldest directly dated South African rock art.     

Engraved ochre from a Middle Stone Age context at Klein Kliphuis in the Western Cape of South Africa

This paper reports on a piece of engraved ochre recovered from a Middle Stone Age context at the rock shelter site of Klein Kliphuis (Western Cape, South Africa). The ochre was associated with a mixed assemblage of Howiesons Poort and post-Howiesons Poort MSA artefacts, suggesting that it is substantially younger than similar finds at Blombos Cave. The implications of the find for arguments concerning the nature of Late Pleistocene behavioural evolution are discussed.