Fluid mixing induced by hydrothermal activity in the ordovician carbonates in Tarim Basin,China

Permian hydrothermal activity in the Tarim Basin may have been responsible for the invasion of hot brines into Ordovician carbonate reservoirs. Studies have been undertaken to explain the origin and geochemical characteristics of the diagenetic fluid present during this hydrothermal event although there is no consensus on it. We present a genetic model resulting from the study of δ¹³C, δ¹⁸O, δ³⁴S, and ⁸⁷Sr/⁸⁶Sr isotope values and fluid inclusions (FIs) from fracture‐ and vug‐filling calcite, saddle dolomite, fluorite, barite, quartz, and anhydrite from Ordovician outcrops in northwest (NW) Tarim Basin and subsurface cores in Central Tarim Basin. The presence of hydrothermal fluid was confirmed by minerals with fluid inclusion homogenization temperatures being >10°C higher than the paleo‐formation burial temperatures both in the NW Tarim and in the Central Tarim areas. The mixing of hot (>200°C), high‐salinity (>24 wt% NaCl), ⁸⁷Sr‐rich (up to 0.7104) hydrothermal fluid with cool (60–100°C), low‐salinity (0 to 3.5 wt% NaCl), also ⁸⁷Sr‐rich (up to 0.7010) meteoric water in the Ordovician unit was supported by the salinity of fluid inclusions, and δ¹³C, δ¹⁸O, and ⁸⁷Sr/⁸⁶Sr isotopic values of the diagenetic minerals. Up‐migrated hydrothermal fluids from the deeper Cambrian strata may have contributed to the hot brine with high sulfate concentrations which promoted thermochemical sulfate reduction (TSR) in the Ordovician, resulting in the formation of ¹²C‐rich (δ¹³C as low as ?13.8‰) calcite and ³⁴S‐rich (δ³⁴S values from 21.4‰ to 29.7‰) H₂S, pyrite, and elemental sulfur. Hydrothermal fluid mixing with fresh water in Ordovician strata in Tarim Basin was facilitated by deep‐seated faults and up‐reaching faults due to the pervasive Permian magmatic activity. Collectively, fluid mixing, hydrothermal dolomitization, TSR, and faulting may have locally dissolved the host carbonates and increased the reservoir porosity and permeability, which has significant implications for hydrocarbon exploration.     

Chemical and isotopic signatures of Na/HCO3/CO2‐rich geofluids,North Portugal

Geochemical and isotopic studies have been undertaken to assess the origin of CO₂‐rich waters issuing in the northern part of Portugal. These solutions are hot (76°C) to cold (17°C) Na–HCO₃ mineral waters. The δ²H and δ¹⁸O signatures of the mineral waters reflect the influence of altitude on meteoric recharge. The lack of an ¹⁸O‐shift indicates there has been no high temperature water–rock interaction at depth, corroborating the results of several chemical geothermometers (reservoir temperature of about 120°C). The low ¹⁴C activity (up to 9.9 pmC) measured in some of the cold CO₂‐rich mineral waters (total dissolved inorganic carbon) is incompatible with the presence of ³H (from 1.7 to 4.1 TU) in those waters, which indicates relatively short subsurface circulation times. The δ¹³C values of CO₂ gas and dissolved inorganic carbon range between ?6‰ and ?1‰ versus Vienna‐Peedee Belemnite, indicating that the total carbon in the recharge waters is being diluted by larger quantities of CO₂ (¹⁴C‐free) introduced from deep‐seated (upper mantle) sources, masking the ¹⁴C‐dating values. The differences in the ⁸⁷Sr/⁸⁶Sr ratios of the studied thermal and mineral waters seem to be caused by water–rock interaction with different granitic rocks. Chlorine isotope signatures (?0.4‰ < δ³⁷Cl < +0.4‰ versus standard mean ocean chloride) indicate that Cl in these waters could be derived from mixing of a small amount of igneous Cl from leaching of granitic rocks.     

圆明园新证——万方安和考

万方安和是清代皇家离宫圆明园中独具特色的园林景建筑之一,其主题以万字房为重心,十字亭为结点,一字长楼山高水长为回应,形成山环水聚、万年如意的园林宫殿形局。其经营意象援引佛教宇宙图式、兼及禅宗沩仰宗风"圆相"奥旨,同时溯源汉地明堂,既是对"圆明主题"的进一步深化,又是雍正皇权极度膨胀在造园理念方面的突出表现。     

In Situ Preservation of Marine Archaeological Remains Based on Geodynamic Conditions,Raja Ampat,Indonesia

Marine archaeological remains in the Raja Ampat waters play an important role in the development of maritime history and culture in Indonesia. Three World War II American P47-Razorback planes are preserved here and the site has been developed for tourists and a research laboratory for scientists. However, the site is tectonically active which threatens the wrecks.     

The hydropolitical Cold War: The Indus Waters Treaty and state formation in Pakistan

This paper develops the framework of the “developmentalist passive revolution” to analyze the politics of water development during the Cold War. This framework is developed by drawing on Marxist geopolitics and critical water geography, and is offered as a way to facilitate comparative analysis of engineering and nationalism in the context of Cold War hydropolitics. The concrete historical engagements of the paper relate to the signing of The Indus Waters Treaty (IWT) of 1960 between Pakistan and India and the associated Indus Basin Plan to transform the Pakistani waterscape. What historical and geopolitical-economic conditions enabled the signing of the IWT? What legacies did the IWT have for state formation in Pakistan? Drawing on the negotiation records of the IWT, archival materials relating to Pakistani river development during the 1960s, and fieldwork conducted in Pakistan in 2012, this paper argues that Cold War hydropolitics are best analyzed through the cultural and economic interactions of asymmetrically empowered developmentalist state elites at multiple scales.     

水与城:成都平原史前聚落形态研究综述

为了探索正在急剧消失的成都平原"林盘"聚落形态与史前聚落的关系,本文借由聚落考古与环境考古,比较集中地综览了平原上史前各聚落城址之间的历时性共性,对史前城址聚落群与成都平原的地貌、水系、文化习尚、宗教信仰等关系的研究,以及各聚落城址的内部特征予以研究述评,以求探究成都平原上这种"林盘"聚落形态与史前聚落城址及水的关系。     

Geochemistry of the Bagnères-de-Bigorre thermal waters from the North Pyrenean Zone (France)

Thermal springs are poorly known in the sedimentary sites of the Pyrenees. In this paper, we describe the ‘Bagnères‐de‐Bigorre’ springs which occur in a remarkably active seismotectonic context. A chemical and isotopic study of 15 spring waters (both cold and thermal, ranging in temperature from 7.0 to 49.9°C), and continuous monitoring of a single spring allow us to characterise water–rock interactions, fluids paths and mixing processes. Three groups of waters are distinguished: (I) SO₄²⁺–Ca²⁺–Cl^– thermal waters (II) SO₄²⁺–Cl^––Ca²⁺ thermal waters and (III) HCO₃^––Ca²⁺ cold shallow waters. Their characteristics suggest interactions with Mesozoic evaporite and carbonate formations. O and D isotopes from thermal waters indicate a local meteoric origin of Atlantic signature and a recharge elevation of 800 to 1000 m, which corresponds to a single feeding area. Their δ¹³C values (?2.8 to ?9.6‰) are consistent with carbonate dissolution, slight fractionation and a surficial organic input leading to δ¹³C depletion. Sr isotopes (0.70751 to 0.70777), Na⁺/Cl^– and (Ca²⁺ + Mg²⁺)/SO₄^2– ratios as well as thermodynamic calculations show that the dissolution of anhydrite and halite‐bearing Triassic layers control the chemical composition of group‐I and ‐II waters. The contrasting trends of cation/Cl^– ratios and TDS of waters from groups I and II suggest the existence of two different circulation paths at depth as well as dilution with surficial waters similar to group III. Calculated mixing proportions show that three waters from group I are diluted from 17 to 66%, whereas all waters from group II are mixed. The aquifer temperature is estimated to be in the range 55–64°C using the retrograde and prograde solubilities of anhydrite and chalcedony, respectively. Accordingly, the mean depth of the reservoir is around 1.7 km, which allows us to constrain the depth of the Triassic layer.     

The sources and formation processes of brines from the Lunnan Ordovician paleokarst reservoir,Tarim Basin,northwest China

The most important petroleum exploration target in the Tarim Basin, northwest China, is the paleokarst reservoir. To understand the source and evolution of brine in this type of reservoir, a total of 37 formation‐water samples were collected from the Middle‐Lower Ordovician paleokarst reservoir in the Lunnan oilfield. The δD‐δ¹⁸O correlation and Cl/Br ratios reflect the mixture of two fluids: meteoric water and evaporated seawater. The different degree of mixture divided samples into two groups. Group 1 samples, from deep strata (5150–6667 m.b.s.l.) in the east of the field, with elevated δD (?53.5 to ?38.0‰), δ¹⁸O values (0.66–5.99‰), and lower Cl/Br ratios (336–478 for Cl/Br, except LN634‐1 and LN631‐1) were formed by evaporation of seawater plus a small contribution from meteoric water. Group 2 samples, from shallow strata (5038–6067 m.b.s.l.), in the west of the field, have contrasting features (?59.6 to ?48.5‰ for δD, ?0.47 to 2.17‰ for δ¹⁸O, and 501 to 871 for Cl/Br), which reflect a mixture of evaporated seawater with a high proportion of meteoric water. Both of the fluid types exchanged oxygen isotope with minerals. The investigation into cation composition reveals that, before entering into the current reservoir, waters suffered albitization of plagioclase; moreover, meteoric water dissolved evaporites and seawater experienced dolomitization. A mixing trend showed by strontium isotopes (0.709801–0.711628) gave further evidence for the mixture of two fluid types. Based on the correlation of geological history with our data, two infiltration models of meteoric waters can be constructed. According to the chemical and isotopic compositions of the waters, an east fluid regime (Group 1) and a west fluid regime (Group 2) have thus been defined. Better understanding of the subsurface fluid movement patterns may be helpful for the local exploration.     

Development of successive karstic systems within the Baix Penedès Fault zone (onshore of the Valencia Trough,NW Mediterranean)

The Baix Penedès Fault zone records successive karstic systems. The outcrops studied correspond to different segments of the fault, which were temporarily connected and disconnected, allowing for different diagenetic processes to occur. The first karstic system affected the Mesozoic rocks due to subaerial exposure after Paleogene compression, an event characterized by widespread dissolution and the generation of vug and cavern porosity. The δ¹⁸O values of the dolomitic sediment filling the initial vuggy porosity are similar to those of the host dolomite, indicating that the sediment comes from the erosion and reworking of the host rock. The second karstic system is related to the upward propagation of the Baix Penedès Fault. This deformation was characterized by random‐fracture fabrics with dolomite cement and sediment. The stable isotopes values and Sr/Ca ratios of both the dolomite cement and sediments are similar to those of the host rock. In contrast, the more depleted δ¹³C values indicate the influence of soil‐derived CO₂ and the opening of the system to meteoric waters. During the third karstic event, the δ¹⁸O, δ¹³C, Sr/Ca ratios, and ⁸⁷Sr/⁸⁶Sr values of diagenetic cements suggest a marine signature, indicating that the karstic sediments were dolomitized under the influence of late Burdigalian‐Langhian marine waters. These marine waters were probably expelled from poorly buried sediments and circulated through faults producing dolomitization of the karstic sediments. A final karst system developed during a period of uplift and subaerial exposure. The δ¹⁸O values, the Mg/Ca and Sr/Ca ratios, and the high radiogenic values of the calcite cements formed during this period indicate precipitation from meteoric waters. The results of this study have implications for carbonate hydrocarbon reservoir analogs subject to karstic influence in the Valencia Trough and elsewhere.     

近代长江流域行轮内港时空变迁研究(1898—1929年)——基于《<内河行轮章程>项下华洋轮船行驶 内港名录》的复原

1898年清廷颁布《内港行船章程》后,长江内河轮运骤兴,开放轮船行驶的内港日渐增多,截至1929年全流域有超过418处内港开放行轮,内河航运格局为之一变。长江流域开放行轮的内港在空间上集中于下游地区,中游也有较多分布,上游地区则十分稀少。行轮内港的开放在时间上则呈现出下游到上游、干流到支流两种趋势。近代行轮内港的时空变迁趋势反映了轮运这一新式交通在长江流域的发展情况。