From a White Desert to the Largest World Deposit of Lithium: Symbolic Meanings and Materialities of the Uyuni Salt Flat in Bolivia

The Uyuni salt flat (Salar de Uyuni) in Bolivia possesses the largest lithium deposit in the world. Over the past 40 years, this location has been commodified and radically transformed. This paper examines how a landscape, understood from its material attributes and qualities, shapes and is shaped by social relations unfolding in a process of commodification and mining expansion. Based on primary qualitative data, the paper explores two elements: (1) how the symbolic meaning of this landscape has changed over time for the surrounding indigenous communities; and (2) how the different materialities of the salt flat as landscape, as ulexite and as lithium allow understanding of the drivers of socio‐environmental change and conflict in this region. The paper argues that social relations and governance frameworks are interlinked with changing symbolic meanings and the different materialities of the Uyuni salt flat.     

Temperature‐dependent Li isotope ratios in Appalachian Plateau and Gulf Coast Sedimentary Basin saline water

Lithium (Li) concentrations of produced water from unconventional (horizontally drilled and hydraulically fractured shale) and conventional gas wells in Devonian reservoirs in the Appalachian Plateau region of western Pennsylvania range from 0.6 to 17 mmol kg^?1, and Li isotope ratios, expressed as in δ⁷Li, range from +8.2 to +15‰. Li concentrations are as high as 40 mmol kg^?1 in produced waters from Plio‐Pleistocene through Jurassic‐aged reservoirs in the Gulf Coast Sedimentary Basin analyzed for this study, and δ⁷Li values range from about +4.2 to +16.6‰. Because of charge‐balance constraints and rock buffering, Li concentrations in saline waters from sedimentary basins throughout the world (including this study) are generally positively correlated with chloride (Cl), the dominant anion in these fluids. Li concentrations also vary with depth, although the extent of depth dependence differs among sedimentary basins. In general, Li concentrations are higher than expected from seawater or evaporation of seawater and therefore require water–mineral reactions that remove lithium from the minerals. Li isotope ratios in these produced waters vary inversely with temperature. However, calculations of temperature‐dependent fractionation of δ⁷Li between average shale δ⁷Li (?0.7‰) and water result in δ⁷Li_water that is more positive than that of most produced waters. This suggests that aqueous δ⁷Li may reflect transport of water from depth and/or reaction with rocks having δ⁷Li lighter than average shale.