First Insights into the Technique Used for Heat Treatment of Chert at the Solutrean Site of Laugerie‐Haute,France

The earliest evidence of flint and chert heat treatment was found in the ~21.5–17 ka old European Solutrean culture. The appearance of pyrotechnology as part of the production of stone tools has important implications for our understanding of Upper Palaeolithic technological evolution and the specific adaptations during the last glacial maximum in Europe. However, the techniques and procedures used to heat‐treat rocks during the Solutrean remain poorly understood. No direct archaeological evidence has so far been found and the most promising approach is to understand these techniques by determining the parameters with which flint and chert were heated at that time. In this study, we investigate the heating temperature of 44 heat‐treated laurel‐leaf points from Laugerie‐Haute, using a non‐destructive technique based on infrared spectroscopy. Our results document that most of the artefacts were heated to a narrow interval of temperatures between 250 °C and 300 °C. This indicates a standardized technique that allowed to created similar conditions during successive heating cycles. The implications of these results for our understanding of the technical complexity during the Solutrean must be discussed in the light of different heating techniques used at different places and periods.     

A Unique Case of Prone Position in the Primary Cremation Tomb 252 of Monte Sirai Necropolis (Carbonia,Sardinia, Italy)

A series of graves belonging to the Phoenician period were investigated after the campaign excavation of 2007 in the Phoenician‐Punic necropolis of Monte Sirai (Carbonia, Sardinia, Italy). One tomb in particular (labelled 252) is presented here because of its uniqueness. Tomb 252 contained the cremated remains of an individual, probably male, and comparison of the excavation records alongside reconstruction of the bone material itself makes clear that the individual was cremated in a prone position. It represents the first case of prone cremation reported in the literature. To investigate whether the temperature of the cremation was homogenous across the entire body, we have conducted a combined physical–chemical analysis using X‐ray diffraction spectroscopy and Fourier transform infrared. Copyright © 2012 John Wiley & Sons, Ltd.     

高分子彩绘类文物保护涂层材料的性能及应用研究

针对彩绘类陶器保护的特殊要求,筛选性能优良的保护材料。在人工气候箱中对所选择的9种有机高分子文物保护涂层材料进行人工老化试验,分别采用傅立叶红外光谱仪测量试验材料的分子结构,分光光度仪测量颜料的主波长、色纯度和高度的变化,粘接强度仪测量颜料的粘接强度变化。结果表明:PrimalAC33、B72、有机硅的耐老化性能好,颜色变化小,粘接强度高,能很好的起到保护彩绘文物的作用,建议在文物保护领域推广使用。     

FT-IR measurements of petroleum fluid inclusions: methane, n-alkanes and carbon dioxide quantitative analysis

A recent advancement in petroleum geochemistry is to model fossil oil composition using microthermometric and volumetric data acquired from individual fluid inclusion analysis. Fourier transform infrared (FT‐IR) microspectroscopy can record compositional information related to gas (CH₄ and CO₂) and alkane contents of petroleum inclusions. In this study, a quantitative procedure for FT‐IR microspectrometry has been developed to obtain, from individual fluid inclusions, mol percentage concentrations of methane, alkanes and carbon dioxide as constraints to thermodynamic modelling. A petroleum inclusion in a sample from the Québec City Promontory nappe area was used as standard to record a reference spectrum of methane. The analytical procedure is based on the measurement of CH₄/alkane and CH₄/CO₂ band area ratios. CH₄/alkane infrared band area ratio is obtained after spectral subtraction of the reference methane spectrum. This area ratio, affected by absolute absorption intensities of methane, methyl and methylene, provides a molar CH₄/alkane ratio. Methyl/methylene ratio (CH₂/CH₃) ratio is obtained following procedures established in previous work. CO₂/CH₄ concentration ratio is estimated from relative absolute absorption intensities. Application to natural inclusions from different environments shows good correlation between FT‐IR quantification and PIT (petroleum inclusion thermodynamic) modelling.     

Degradation of mud brick houses in an arid environment: a geoarchaeological model

A common assumption in Near Eastern tell archaeology is that the majority of sediments originate from degraded mud bricks. Little is known about the mechanism of mud brick wall degradation. Here we present a detailed macro- and microscopic ethnoarchaeological study of the degradation of a mud brick house and propose a comprehensive mechanism for tell formation processes in arid environments. The study took place in southern Israel by trenching a ca. 60 year old abandoned mud brick house, followed by extensive sediment sampling. Macroscopic observations showed that mud brick walls degrade by collapse of single bricks and/or collapse of intact wall parts, either inwards or outwards. In addition, infill sediments within the house and outside it, in close proximity to its walls, form alternating sedimentary layers of various colors and textures. The degraded mud brick material lost its distinctive macroscopic structure, which makes it impossible to accurately identify this material by field observations alone. Mineralogical and elemental analyses established the sources of the house infill sediments, namely mud bricks and wind blown sediments. Alternating layers mostly originate from mixing between degraded mud brick material and wind blown sediments. Micromorphological observations revealed microscopic mechanisms of mud brick degradation and include processes of mud slurry gravity flows, sediment coatings and infillings, wind abrasion of walls, small-scale puddling, and bioturbation. This study provides a working scheme for site formation of abandoned mud brick structures in arid environments. It provides a set of criteria by which it is possible to differentiate floors from post-abandonment sedimentary features and thus improves the reliability of activity area research.     

Multi-method (FTIR,XRD, PXRF) analysis of Ertebølle pottery ceramics from Scania,southern Sweden

A combination of Fourier-transform infrared spectroscopy (FTIR), powder X-ray diffraction (XRD) and portable X-ray fluorescence spectroscopy (PXRF) was used on the clay fraction of Ertebølle ceramics from several Late Mesolithic sites in Scania, southern Sweden. The aim was to provide up-to-date information about clay types used during that period within the Scanian Ertebølle cultural unit, and to elucidate social aspects relevant to the organization of pottery production and the role of ceramics in the local societies. The results suggest similar clay preferences across the sites, site-based pottery production using local clays and zero mobility of ceramics between the sites. The chemical separation of the ceramics from the site of Soldattorpet into two compositional groups suggests possible multigroup occupation. The origins of aromatic hydrocarbons, extracted previously from the ceramic matrix of the vessels during a lipid residue study, were also investigated, and a discussion is provided.     

Identification of Suspected Horn from the Queen Anne's Revenge (1718), North Carolina,USA

Infrared spectroscopy can be a valuable tool for conservators and archaeologists to help identify archaeological artefacts. We present a case‐study on the identification of an artefact recovered by North Carolina Department of Cultural Resources (NCDCR) Underwater Archaeology Branch from an early‐18th‐century shipwreck (31CR314). The wreck is assumed to be the remains of Queen Anne's Revenge, which sank off the North Carolina coast in 1718. A sample of the artefact was analysed by infrared spectroscopy to identify it. Prior to spectroscopic analysis it was speculated that the sample could be animal horn or leather. © 2011 The Authors     

A spectroscopic study of the nimrud ivories

Electron spin resonance and infrared spectroscopic techniques have been used to examine the thermal and environmental deterioration of ivory from Nimrud, Iraq. It has been possible to ascertain the extent of ancient pyrolysis of the ivory with the former technique, and infrared spectroscopy has allowed an insight into the deterioration of the protein matrix of the ivory both in relation to, and independent from, thermal breakdown. Comparative spectroscopic studies of both ancient and modern ivory are also reported. The structural information obtained is discussed in the light of previously reported studies based upon chemical analyses.     

Adipocere Inside Nineteenth Century Femora: The Effect of Grave Conditions.

Adipocere has, infrequently, been reported from archaeological contexts normally on the external surface of bodies. In contrast to those cases, this study focuses on a white, powdery and greasy substance found inside two right human femora during sampling. These samples were obtained from two identified individuals buried in the late 19th century, who were exhumed from a rock‐cut and a brick‐lined grave in a steeply sloping graveyard with wet soil conditions. Both individuals were buried in coffins. Fourier transform infrared spectroscopy was used to test the composition of the substances, and both were found to conform to the spectrum of adipocere. This is likely to be a breakdown product of the fats in bone marrow in an anaerobic, moist environment mediated by bacteria. None of the other individuals (n = 6) buried in similar graves displayed evidence of adipocere; this includes those whose femora were in a similar state of preservation (n = 4). Contemporaneous data on precipitation for the month of burials do not highlight any obvious trends, but one of the individuals was found in a water‐logged grave. The similar preservation of other femora buried in brick‐lined graves highlights the interplay of multiple factors in the formation and degradation of adipocere. More importantly, it demonstrates differential preservation, which may impact on DNA and other biomolecular research. Furthermore, this adds to the limited data currently available on adipocere found in archaeological contexts. Copyright © 2013 John Wiley & Sons, Ltd.