Capillary trapping is a physical mechanism by which carbon dioxide (CO2) is naturally immobilized in the pore spaces of aquifer rocks during geologic carbon sequestration operations, and thus a key aspect of estimating geologic storage potential. Here, we studied capillary trapping of supercritical carbon dioxide (scCO2), and the effect of initial scCO2 saturation and flow rate on the storage/trapping potential of Berea sandstone. We performed two‐phase, scCO2‐brine displacements in two samples, each subject to four sequential drainage–imbibition core‐flooding cycles to quantify end‐point saturations of scCO2 with the aid of micro‐ and macro‐computed tomography imaging. From these experiments, we found that between 51% and 75% of the initial CO2 injected can be left behind after the brine injection. We also observed that the initial scCO2 saturation influenced the residual scCO2 saturation to a greater extent than the rate of brine injection under the experimental conditions examined. In spite of differences in the experimental conditions tested, as well as those reported in the literature, initial and residual saturations were found to follow a consistent relationship. 相似文献
Twenty‐six samples from domestic assemblages of 9th–12th century Córdoba were subjected to electron microprobe analysis. The results reveal two main compositional types. The first, encountered in 13 of the samples, seems to result from the combination of plant ashes with high‐impurity sand, and has some contemporary parallels from Syria and Egypt. The second type is a lead–soda–silica glass, encountered in a relatively high proportion of the glasses (11 of the 26 sampled), possibly formed by the addition of lead metal to existing glasses and with very few known parallels. These are among a very small number of results available to date on the chemical composition of glasses from medieval Spain, and the presence of a high proportion of lead–soda–silica glasses is particularly interesting, possibly indicating a technological practice unique to, or originating in, the western Muslim world. 相似文献
The capillary sealing efficiency of fine‐grained sedimentary rocks has been investigated by gas breakthrough experiments on fully water saturated claystones and siltstones (Boom Clay from Belgium, Opalinus Clay from Switzerland and Tertiary mudstone from offshore Norway) of different lithological compositions. Sand contents of the samples were consistently below 12%, major clay minerals were illite and smectite. Porosities determined by mercury injection lay between 10 and 30% while specific surface areas determined by nitrogen adsorption (BET method) ranged from 20 to 48 m2 g ? 1. Total organic carbon contents were below 2%. Prior to the gas breakthrough experiments the absolute (single phase) permeability (kabs) of the samples was determined by steady state flow tests with water or NaCl brine. The kabs values ranged between 3 and 550 nDarcy (3 × 10?21 and 5.5 × 10?19 m2). The maximum effective permeability to the gas‐phase (keff) measured after gas breakthrough on initially water‐saturated samples extended from 0.01 nDarcy (1 × 10?23 m2) up to 1100 nDarcy (1.1 × 10?18 m2). The residual differential pressures after re‐imbibition of the water phase, referred to as the ‘minimum capillary displacement pressures’ (Pd), ranged from 0.06 to 6.7 MPa. During the re‐imbibition process the effective permeability to the gas phase decreases with decreasing differential pressure. The recorded permeability/pressure data were used to derive the pore size distribution (mostly between 8 and 60 nm) and the transport porosity of the conducting pore system (10‐5–10‐2%). Correlations could be established between (i) absolute permeability coefficients and the maximum effective permeability coefficients and (ii) effective or absolute permeability coefficients and capillary sealing efficiency. No correlation was found between the capillary displacement pressures determined from gas breakthrough experiments and those derived theoretically by mercury injection. 相似文献
To thermally upgrade exterior masonry walls, interior insulation is often the only possible retrofitting technique, especially when dealing with historic buildings. Unfortunately, it is also the riskiest post-insulation technique, as frost damage, interstitial condensation, and other damage patterns might be induced. To diminish those risks, nowadays so-called capillary active interior insulation systems are often promoted. These systems aim a minimal reduction of the inward drying potential, while interstitial condensation is buffered.
Currently, several capillary active systems are on sale. These different types have, however, widely varying properties. In this article, a closer look at the hygrothermal properties and the working principle of a number of “capillary active” interior insulation systems is made. The spread in capillary absorption coefficients and the vapor diffusion resistances of the different systems is discussed and their influence is illustrated. Based on all this, a more nuanced view on capillary active insulation systems is pursued.
Fluid inclusions of the H2O‐NaCl‐CaCl2 system are notorious for their metastable behavior during cooling and heating processes, which can render microthermometric measurement impossible or difficult and interpretation of the results ambiguous. This study addresses these problems through detailed microscopic examination of synthetic solutions during cooling and warming runs, development of methods to enhance nucleation of hydrates, and comparison of microthermometric results with different degrees of metastability with values predicted for stable conditions. Synthetic H2O‐NaCl‐CaCl2 solutions with different NaCl/(NaCl + CaCl2) ratios were prepared and loaded in fused silica capillaries and glass‐sandwiched films for microthermometric studies; pure solutions were used with the capillaries to simulate fluid inclusions, whereas alumina powder was added in the solutions to facilitate ice and hydrate crystallization in the sandwiched samples. The phase changes observed and the microthermometric data obtained in this study have led to the following conclusions that have important implications for fluid inclusion studies: (i) most H2O‐NaCl‐CaCl2 inclusions that appear to be completely frozen in the first cooling run to ?185°C actually contain large amounts of residual solution, as also reported in some previous studies; (ii) inability of H2O‐NaCl‐CaCl2 inclusions to freeze completely may be related to their composition (low NaCl/(NaCl + CaCl2) ratios) and lack of solid particles; (iii) crystallization of hydrates, which is important for cryogenic Raman spectroscopic studies of fluid inclusion composition, can be greatly enhanced by finding an optimum combination of cooling and warming rates and temperatures; and (iv) even if an inclusion is not completely frozen, the melting temperatures of hydrohalite and ice are still valid for estimating the fluid composition. 相似文献
Accurate reconstruction of diagenetic P‐T conditions in petroleum reservoirs from fluid inclusion data relies on valid measurements of methane concentration in aqueous inclusions. Techniques have been developed (Raman spectrometry) to provide sufficiently accurate data, assuming measured methane concentration has not been modified after aqueous inclusion entrapment. This study investigates the likelihood that organic acids derived from petroleum fluids and dissolved in formation water might suffer decarboxylation upon postentrapment heating within the fluid inclusion chamber, thereby generating excess CH4 in the inclusions. Four different experiments were conducted in fused silica capillary capsules (FSCCs), mimicking fluid inclusions. The capsules were loaded with acetic (CH3COOH) or formic (HCOOH) acid solution and were heated to 250°C for short durations (<72 h) in closed‐system conditions, with or without applying a fixed PH2. Reaction products were characterized by Raman and FT‐IR spectrometry. Results indicate that decarboxylation reactions did take place, at variable degrees of progress, and that measurable excess CH4 was produced in one experiment using acetic acid. This suggests that methane may be produced from dissolved organic acids in natural aqueous inclusions in specific situations, possibly inducing errors in the thermodynamic interpretation. 相似文献
The petroleum industry uses subsurface flow models for two principal purposes: to model the flow of hydrocarbons into traps over geological time, and to simulate the production of hydrocarbon from reservoirs over periods of decades or less. Faults, which are three-dimensional volumes, are approximated in both modelling applications as planar membranes onto which predictions of the most important fault-related flow properties are mapped. Faults in porous clastic reservoirs are generally baffles or barriers to flow and the relevant flow properties are therefore very different to those which are important in conductive fracture flow systems. A critical review and discussion is offered on the work-flows used to predict and model capillary threshold pressure for exploration fault seal analysis and fault transmissibility multipliers for production simulation, and of the data from which the predictions derive. New flow simulation models confirm that failure of intra-reservoir sealing faults can occur during a reservoir depressurization via a water-drive mechanism, but contrary to anecdotal reports, published examples of production-induced seal failure are elusive. Ignoring the three-dimensional structure of fault zones can sometimes have a significant influence on production-related flow, and a series of models illustrating flow associated with relay zones are discussed. 相似文献