一种油画颜料层裂纹的修复技术分析

油画颜料层裂纹是一种常见的病害类型,严重的裂纹会影响作品的视觉效果。裂纹修复所采取的措施应以缓解病害,延续寿命为目标,避免不当修复对其文物价值的改变。本研究通过红外光谱和便携式X荧光能谱分析,初步确定了裂纹产生的原因与材料技法和机械作用力有关,长期的温湿度波动则是最终形成老化裂纹的重要因素。对两类常见的裂纹加固方法比较后得出结论,色蜡改变了原画的光泽度和肌理层,动物胶调碳酸钙更适宜作为裂纹的填补材料。观察修复后的油画保存状况,发现经过修复的颜料层仍存在继续劣化的风险,必须维持保存环境的相对稳定,方可延长修复周期。     

The Santa María pottery of El Bolsón valley (Catamarca,Argentina): Compositional characterization and implications on the elaboration processes,ca. 1000–1600 ce

The results obtained from the multi-analytic compositional characterization of ceramic pastes and paints of the Santa María style, from the El Bolsón valley (Belén Department, Catamarca Province, Argentina), are presented here. This pottery style had a wide regional distribution in Northwestern Argentina between ca. 1000 and1600 ce and is characterized by its complex iconography painted in black, cream and red. The analyses show that the containers correspond to the technical tradition of using grog temper and suggest that its manufacture involved a double firing process. This reveals a new practice for the time.     

江苏淮安财富广场南北朝墓群发掘报告

江苏淮安财富广场南北朝家族墓是一处典型的家族墓地,墓葬排列有序,随葬器物较为丰富精美,时代特征明显,文化因素较为复杂,对研究南北朝时期丧葬礼俗及淮安地方历史文化具有重要的价值。     

Market Liberalism,Marginalised Citizens and Countermovements in India

How has neo-liberalism transformed the economic structure and policies of India? And what are the politico-economic implications of such policies for marginalised populations? Following Karl Polanyi’s theory of “double movement”, this paper argues that while market liberalism has helped India overcome the slow so-called “Hindu rate of growth”, it has adversely affected the economic interests of the poor. It further argues that the expansion of the market (first movement) has led to various social dislocations in the lives of the poor. Such dislocations have generated several countermovements (second movement), which have found expressions not just in electoral politics but also in various grassroots movements. While it may be true that such countermovements have not always been successful in overturning the tide of neo-liberalism, they have certainly influenced the policy priorities of the state in favour of the poor and the marginalised in India.     

Degradation processes in colourless Roman glass: cases from the Bocholtz burial

A group of Roman glass objects from the Bocholtz burial in the SW of Limburg (The Netherlands) was found to have been subject to varying degrees of degradation. Many of the 25 colourless glass objects were fragmented to pieces <0.1 cm (“sugared”), whereas the three transparent blue-green glass objects were in near-pristine state. Analyses using SEM, XRF and EDS revealed that the fragmentation was the direct result of the intense leaching of Na₂O from the glass structure and its replacement with water. The resulting gel layers with low-Na₂O contents and large amounts of water are sensitive to cracking when they dry out. Thin-walled glass appears to be less sensitive to cracking from the resulting stress than thick-walled glass. Local differences in the moisture regime during burial also influence the severity of the glass degradation. Glass with low concentrations of CaO seems to be the most sensitive to this form of degradation. The typical blue-green Roman glass is less sensitive as it generally has considerably higher concentrations of CaO.     

An experimental and modeling study of Na-rich hydrothermal alteration

Sodic alteration assemblages including clinoptilolite, mordenite, analcime and Na‐montmorillonite were locally observed in sediments in the eastern part of the Hachimantai geothermal region, northeast Japan. This study investigated the mechanisms of sodic enrichment in the sediments during alteration. Kinetic results for water/rock interaction experiments are reported here. Batch‐type experiments were conducted at 150–250°C under saturated vapor pressure. Pyroclastic rocks dissolved incongruently in these experiments, and the solubility and dissolution rates among elements varied as follows: the apparent steady‐state concentrations of major elements are Si > Na ? K > Ca > Al and the order of the dissolution rates is Si > Al > Na ? K > Ca. Na had the highest steady‐state concentration and fastest dissolution rate of the alkali and alkali earth metal ions. Based on surface analysis of plagioclase, dissolution was effected via a reaction layer of Na‐montmorillonite on the mineral surface. Additionally, a reaction model constructed based on the experimentally observed reaction mechanism quantitatively explains the dissolution behavior. These results show that Na‐montmorillonite can be precipitated by pyroclastic rock/meteoric water interactions without seawater involvement: the Na is derived from the host rocks.     

青铜器锈蚀结构组成及形态的比较研究

采用X射线衍射(XRD)、扫描电镜(SEM)、X射线电子能谱(EDS)和金相显微镜(OM)等方法,分析比较了染有“粉状锈”与未染“粉状锈”的典型青铜残片的锈蚀产物的矿物组成、腐蚀层分层结构及金相组织。结果发现,未染有“粉状锈”的青铜样品腐蚀层一般分为二层,外层是二价铜化合物,合金组织中未见α (α δ)组织,锈蚀产物中不含碱式氯化铜;而染有“粉状锈”的青铜样品都含有碱式氯化铜,其断面腐蚀层分三至四层,且每层锈体的结构和元素组成各不相同,在靠近合金基体层的锈层中发现了大量的CuCl存在。结果表明,青铜文物表面锈蚀覆盖层的致密性、空气中的湿度及锈层中CuCl层状分布的存在,是青铜器表面“粉状锈”形成和发展的根本原因。     

Chemical modification of pyroclastic rock by hot water: an experimental investigation of mass transport at the fluid–solid interface

Hydrothermal water–(pyroclastic) rock interactions were examined using flow-through experiments to deduce the effect of mass transport phenomena on the reaction process. A series of experiments were conducted over the temperature range 75–250°C, with a constant temperature for each experiment, and at saturated vapour pressure, to estimate the apparent rate constants as a function of temperature.
Based on the chemistry of analysed solutions, the water–rock interaction in the experiments was controlled by diffusion from the reaction surface and by the existence of a surface layer at the rock–fluid interface, which regulated the chemical reaction rate. The reaction progress depended to a high degree on flow velocity and temperature conditions, with element abundances in the fluid significantly affected by these factors. Mass transport coefficients for diffusion from the rock surface to the bulk solution have been estimated. Ca is selectively depleted under lower temperature conditions ( T  < 150°C), whereas Na is greatly depleted under higher temperature conditions ( T  > 150°C), and K reaction rates are increased when flow velocity increases. Using these conditions, specific alkali and alkali earth cations were selectively leached from mineral surfaces. The 'surface layer' comprised a 0.5–1.8 mm boundary film on the solution side (the thickness of this layer has no dependence on chemical character) and a reaction layer. The reaction layer was composed of a Si, Al-rich cation-leached layer, whose thickness was dependent on temperature, flow velocity and reaction length. The reaction layer varied in thickness from about 10⁻⁴ to 10⁻⁷ mm under high temperature/low fluid velocity and low temperature/high fluid velocity conditions, respectively.     

郭世宝博士与加拿大华人新移民研究述评

论文评述了加拿大卡尔加里大学教育学院教授郭世宝在加拿大华人新移民研究方面的学术成果。认为他在华人新移民、华人社团、移民的外国文凭认证、文化多元化与高等及成人教育研究方面成就突出,其中在华人新移民研究方面有两项理论创新：在华人新移民融合研究方面提出了＂三重玻璃效应＂理论;在华人新移民回流研究方面运用了＂双重离散＂理论。