From commodity to money: The rise of silver coinage around the Ancient Mediterranean (sixth–first centuries bce)

The reasons why the Western Mediterranean, especially Carthage and Rome, resisted monetization relative to the Eastern Mediterranean are still unclear. We address this question by combining lead (Pb) and silver (Ag) isotope abundances in silver coinage from the Aegean, Magna Graecia, Carthage and Roman Republic. The clear relationships observed between ¹⁰⁹Ag/¹⁰⁷Ag and ²⁰⁸Pb/²⁰⁶Pb reflect the mixing of silver ores or silver objects with Pb metal used for cupellation. The combined analysis of Ag and Pb isotopes reveals important information about the technology of smelting. The Greek world extracted Ag and Pb from associated ores, whereas, on the Iberian Peninsula, Carthaginians and Republican‐era Romans applied Phoenician cupellation techniques and added exotic Pb to Pb‐poor Ag ores. Massive Ag recupellation is observed in Rome during the Second Punic War. After defeating the Carthaginians and the Macedonians in the late second century bce , the Romans brought together the efficient, millennium‐old techniques of silver extraction of the Phoenicians, who considered this metal a simple commodity, with the monetization of the economy introduced by the Greeks.     

Limits to climate action - Narratives of bioenergy with carbon capture and storage

In recent years, bio-energy with carbon capture and storage (BECCS) has been awarded a key role in climate mitigation scenarios explored by integrated assessment models and referenced in reports by the Intergovernmental Panel on Climate Change. Because a majority of scenarios limiting global warming to 2 °C or 1,5 °C include vast deployment of BECCS, a critical discussion has emerged among experts about the moral implications of thus introducing an unproven technology into the policy realm.In this paper, we analyse this discussion as it has played out between 2013 and 2019, with a focus on how expert narratives are constructed in the mass media about the possibilities for decarbonisation within the current political-economic order. We find there are almost no narratives that support massive deployment of BECCS, and that all narratives presuppose limits to decarbonisation imposed by the current political-economic system. The perception of such limits lead some to argue, through deterministic and apolitical narratives, for the necessity of negative emissions technologies, while others argue instead that “degrowth” is the only solution. Thus, there is a distinct lack of positive narratives about how capitalism can bring about decarbonisation.     

Nitrogen cycling in western India as revealed by nitrogen isotopes,and the historic production of saltpetre

Saltpetre (KNO₃) manufacture was a principal monopoly industry in early Modern India when the United Kingdom governed the social and economic systems. The process represented microbial transformation of excrementitious livestock and human wastes deposited around habitats, resulting in formation of salt efflorescence at an economic scale. Low caste people collected these wastes for extraction and production of rough saltpetre under the administrative control of British India. Stable isotope composition (δ¹⁵N and δ¹⁸O) was used to trace details of the microbial transformation processes, often involving the isotopic fractionation of nitrogen and oxygen. Marked elevation in δ¹⁵N and δ¹⁸O values for nitrates in soils and deposits, relative to those of primary organic nitrogen in diets and water sources, characterizes the unique processes of historic saltpetre manufacture in British India.     

Human biology in the Classic Maya collapse: Evidence from paleopathology and paleodiet

We review evidence from human biology—paleopathological and isotopic paleodietary studies on ancient Maya skeletons—to assess the validity of ecological models of the Classic Maya collapse, in which elevated disease and deteriorating diet are commonly assumed. To be upheld, the health arguments of ecological models require that the Maya disease burden (1) was greater than that for many other societies and (2) increased over the span of occupation. The dietary argument requires (1) consistent change in diet from Preclassic and Early Classic Periods to the Terminal Classic and (2) increasing social divergence in diet. A correlation between diet and disease is necessary to link these arguments. Neither pathology nor isotopic data consistently support these criteria. Instead, it appears that local environmental and political factors created diversity in both disease burden and diet. In view of the human biological data, we are skeptical of ecological models as generalized explanations for the abandonment of Classic Maya sites in the southern lowlands.     

Towards lower carbon cities: urban morphology contribution in climate change adaptation strategies

Non-urbanized areas (NUAs) play an important role in reducing the effects of climate change by providing both carbon storage and sequestration. Urban areas are responsible for the emission of 60% of global greenhouse gas, 50% of which are produced by buildings. During the past decades, increasing urban growth and sprawl processes produced several urban layouts characterized by different morphological features and a common lack of sustainable energy and environmental solutions. Investigating the relationship between urban morphology, energy demand and carbon emission/sequestration represents a relevant topic for urban planning practices implemented to face urban climate change effects. This study proposes a method for a transformability assessment aimed at investigating the transformation suitability of different urban morphology types. The case study is the metropolitan area of Catania (Italy), characterized by an impressive urban growth since the 1960s. The proposed method identification of limits and options for increasing sustainability of urban areas considering the contribution of both NUAs and built-up areas. This approach allows to identify appropriate planning tools for new layouts of urban fabrics while increasing the objectivity of the decision process. In the framework of climate change mitigation and adaptation, the outcomes of this research may lead to innovative urban planning practices.     

A Persistent Place for Hunter-Gatherers During the Late Holocene: The Case of Burials in Pit on the Coast of Lángara Bay,Argentine Patagonia

In Argentine Patagonia, the type of archaeological burial “in pit” has been only identified on the coast of Lángara Bay. This modality is characterized by the presence of single and multiple primary burials. Studies on five human burials in pits are presented in this article. The aim is to compare the contexts of burials in pit at the site level and the spatial characteristics of their distribution in the Lángara Bay locality from a diachronic perspective. The approach focuses on mortuary practices and social relations of hunter-gatherer groups during the Late Holocene. A characterization of the burials, their chronologies, bioarchaeological determinations, stable isotope studies, and their spatial distribution are included. The results allow us to chronologically place the contexts between ca. 3000 and 2000 cal BP. A spatial pattern in the distribution of burials in the coastal landscape was identified. Finally, it is proposed that this part of the Patagonian coast was a persistent place of burials in pit.     

Invasive cordgrass (Spartina spp.) in south‐eastern Australia induces island formation,salt marsh development,and carbon storage

Invasive vegetation species can lead to major changes in the geomorphology of coastal systems. Within temperate estuaries in the southern hemisphere, especially Australia and New Zealand, the cordgrass Spartina spp. has become established. These species are highly invasive, and their prolific growth leads to the development of supratidal environments in formerly intertidal and subtidal environments. Here, we quantified the impact of Spartina invasion on the geomorphology and sequestration capacity of carbon in the sediments of Anderson Inlet, Victoria, Australia. Spartina was first introduced to the area in the 1930s to aid in land reclamation and control coastal erosion associated with coastal development. We found that Spartina now dominates the intertidal areas of the Inlet and promotes accretion (18 mm/year) causing the formation of over 108 ha of supratidal islands over the past 100 years. These newly formed islands are calculated to potentially contain over 5.5 million tonnes of CO₂ equivalent carbon. Future management of the inlet and other Spartina‐dominated environments within Australian presents a dilemma for resource managers; on the one hand, Spartina is highly invasive and can outcompete native tidal marshes, thereby warranting its eradication, but on the other hand it is likely more resilient to rising sea levels and has the potential for carbon sequestration. Whether or not the potential advantages outweigh the significant habitat change that is anticipated, any management strategies will likely require additional research into costs and benefits of all ecosystem services provided by Spartina including in relation to nutrient cycling, shoreline stabilisation, and biodiversity as well as in response to the longevity of carbon found within the sediments.     

Experimental investigation of carbon dioxide trapping due to capillary retention in saline aquifers

Capillary trapping is a physical mechanism by which carbon dioxide (CO₂) is naturally immobilized in the pore spaces of aquifer rocks during geologic carbon sequestration operations, and thus a key aspect of estimating geologic storage potential. Here, we studied capillary trapping of supercritical carbon dioxide (scCO₂), and the effect of initial scCO₂ saturation and flow rate on the storage/trapping potential of Berea sandstone. We performed two‐phase, scCO₂‐brine displacements in two samples, each subject to four sequential drainage–imbibition core‐flooding cycles to quantify end‐point saturations of scCO₂ with the aid of micro‐ and macro‐computed tomography imaging. From these experiments, we found that between 51% and 75% of the initial CO₂ injected can be left behind after the brine injection. We also observed that the initial scCO₂ saturation influenced the residual scCO₂ saturation to a greater extent than the rate of brine injection under the experimental conditions examined. In spite of differences in the experimental conditions tested, as well as those reported in the literature, initial and residual saturations were found to follow a consistent relationship.     

Surface controls on the characteristics of natural CO2 seeps: implications for engineered CO2 stores

CO₂ injected into rock formations for deep geological storage must not leak to surface, since this would be economically and environmentally unfavourable, and could present a human health hazard. In Italy natural CO₂ degassing to the surface via seeps is widespread, providing an insight into the various styles of subsurface ‘plumbing’ as well as surface expression of CO₂ fluids. Here we investigate surface controls on the distribution of CO₂ seep characteristics (type, flux and temperature) using a large geographical and historical data set. When the locations of documented seeps are compared to a synthetic statistically random data set, we find that the nature of the CO₂ seeps is most strongly governed by the flow properties of the outcropping rocks, and local topography. Where low‐permeability rocks outcrop, numerous dry seeps occur and have a range of fluxes. Aqueous fluid flow will be limited in these low‐permeability rocks, and so relative permeability effects may enable preferential CO₂ flow. CO₂ vents typically occur along faults in rocks that are located above the water table or are low permeability. Diffuse seeps develop where CO₂ (laterally supplied by these faults) emerges from the vadose zone and where CO₂ degassing from groundwater follows a different flow path due to flow differences for water and CO₂ gas. Bubbling water seeps (characterized by water bubbling with CO₂) arise where CO₂ supply enters the phreatic zone or an aquifer. CO₂‐rich springs often emerge where valleys erode into CO₂ aquifers, and these are typically high flux seeps. Seep type is known to influence human health risk at CO₂ seeps in Italy, as well as the topography surrounding the seep which affects the rate of gas dispersion by wind. Identifying the physical controls on potential seep locations and seep type above engineered CO₂ storage operations is therefore crucial to targeted site monitoring strategy and risk assessment. The surface geology and topography above a CO₂ store must therefore be characterized in order to design the most effective monitoring strategy.     

Stable Isotopes,Chronology, and Bayesian Models for the Viking Archaeology of North-East Iceland

This paper reviews the results of a long-term research project that used stable isotope analyses (δ¹³C, δ¹⁵N, δ³⁴S) and Bayesian mixing models to better model the chronology for a presumed Viking Age cemetery at Hofstaðir, near Lake Mývatn in north-east Iceland. δ¹³C and radiocarbon dating indicated that many of the individuals consumed a large amount of marine protein, which results in a marine reservoir effect (MRE), making ages older than expected. In addition to the MRE, geological activity in the region has the potential to introduce massive quantities of radioactive ‘dead’ carbon into the freshwater system, resulting in a very large freshwater reservoir effect (FRE) that can offset radiocarbon ages on the order of a few thousand years. The radiocarbon dates of organisms that derive an unknown proportion of their carbon from both marine and freshwater reservoirs are extremely difficult to ‘correct’, or, more appropriately, model. The research not only highlights the complexities of dealing with multiple reservoirs, but also how important it is to develop models that are temporally and geographically relevant to the site under study. Finally, it shows how this data can be used to inform the development of chronological models for refining the dating for archaeological activity.