The Geochemical Fingerprint of Tufo Lionato Blocks from the Area Sacra di Largo Argentina: Implications for the Chronology of Volcanic Building Stones in Ancient Rome

We use trace element discrimination diagrams to provide a geochemical fingerprint for Tufo Lionato, the volcanic rock most commonly used in the ancient Roman dimension stone technique. Based on the comparison of their geochemical signatures, we identify different rock facies of Tufo Lionato employed since the fourth to third centuries and through the second century bce in the construction of the temples of the Area Sacra di Largo Argentina. These rock facies correspond to two previously identified building stones: Aniene Tuff and Monteverde Tuff, named after their supposed source areas located in the Aniene River Valley and in the homonymous locality of the Tiber River Valley, respectively. However, the results of our study demonstrate previous misidentification of these volcanic rocks in the different construction phases of Temple C, providing a revision of the dating system currently accepted for the diffusion of Tufo Lionato architecture. We show that the Aniene facies has been exploited since the end of the fourth century bce and that it was employed along with Tufo Giallo della Via Tiberina in the podium and staircase of Temple C, whereas observations at Largo Argentina suggest that the ‘Monteverde Tuff’ was only sporadically used in the early phases of the dimension stone construction technique.     

Multiphase flow simulation through porous media with explicitly resolved fractures

Accurate simulation of multiphase flow in fractured porous media remains a challenge. An important problem is the representation of the discontinuous or near discontinuous behaviour of saturation in real geological formations. In the classical continuum approach, a refined mesh is required at the interface between fracture and porous media to capture the steep gradients in saturation and saturation‐dependent transport properties. This dramatically increases the computational load when large numbers of fractures are present in the numerical model. A discontinuous finite element method is reported here to model flow in fractured porous media. The governing multiphase porous media flow equations are solved in the adaptive mesh computational fluid dynamics code IC‐FERST on unstructured meshes. The method is based on a mixed control volume – discontinuous finite element formulation. This is combined with the P_N+1DG‐P_NDG element pair, which has discontinuous (order N+1) representation for velocity and discontinuous (order N) representation for pressure. A number of test cases are used to evaluate the method's ability to model fracture flow. The first is used to verify the performance of the element pair on structured and unstructured meshes of different resolution. Multiphase flow is then modelled in a range of idealised and simple fracture patterns. Solutions with sharp saturation fronts and computational economy in terms of mesh size are illustrated.     

Interconnected Epistyles of Marble Monuments Under Axial Loads

The restoration of destroyed connections of epistyles joined together by means of metallic connectors is among the most difficult problems encountered by scientists working for the conservation/restoration of monuments made of marble. The complexity of the geometry and the interaction of three completely different materials (metal-filling material-marble) constituting the connection render the study (either experimental or analytic) extremely complicated. In this direction a numerical analysis is presented here in order to deeply understand the response of a typical ancient connection subjected to axial loads as well as to quantify the influence of some geometric parameters on its response. The parameters studied include the length of the connector, the width of its flanges, the depth of the groove (mortise), the existence or not of relieving space and the filling material’s volume. The numerical model was calibrated and validated according to the results of an earlier experimental study realized on the worksite of the Parthenon Temple. It was concluded that the interventions required to relieve the stress field by changing the size of the connector are disproportional to the respective positive effect on the response of the connection. Moreover it was proved that the most beneficial parameter is the relieving space.     

Updating Numerical Models of Masonry Arch Bridges by Operational Modal Analysis

This article aims at presenting and discussing the strategies for updating the finite element numerical modeling of stone masonry arch bridges using operational modal analysis. The study comprehended three bridges: two old ones, the St. Lázaro and the Lagoncinha bridges, and a recently constructed bridge in Vila Fria, Portugal. Updating of the bridge models is performed by comparing the numerical and experimental modal parameters. Three-dimensional detailed numerical models are used to perform modal analysis of the bridges. Experimental modal identification of the bridges is based on the measurement of their acceleration responses during normal operation. The assigned material properties are also based on available results obtained from in situ and laboratory tests and on the results of visual inspection and historical research carried out for both old bridges.     

Petrochemical Identification and Insights on Chronological Employment of the Volcanic Aggregates Used in Ancient Roman Mortars

Through the assistance of trace element and petrographic analyses on 14 samples of mortar aggregates from Roman monuments, including the Porticus Aemilia, the Temple of Concordia, the Temple of the Dioscuri, Temple B and other structures of the Area Sacra di Largo Argentina, and the Villa di Livia, we establish the source area and we investigate the chronological employment of the volcanic materials used in ancient Rome's masonry. In contrast to previous inferences, the petrochemical data presented here show that systematic exploitation of the local ‘Pozzolane Rosse’ pyroclastic deposit has occurred since the early development of concrete masonry, at the beginning of the second century bc , through the early Imperial age. Subsequently, exploitation was extended to the overlying Pozzolane Nere and Pozzolanelle deposits. Only during the early phase of development of the concrete masonry in Rome, volcaniclastic sediments outcropping near the construction sites were mixed with the sieved remains of the tuff employed as the coarse aggregate, to produce the fine aggregate. The results of the study on the investigated monuments suggest the possibility of establishing the chronological identification of three different types of mortars, as a function of the composition of the volcanic material employed in the fine aggregate, which, when implemented by future studies, may contribute to the dating of monuments and archaeological structures.     

Seismic vulnerability assessment and fragility analysis of stone masonry monastic temples in Sikkim Himalayas

Buddhist monasteries in Sikkim Himalayas constitute important religious and architectural heritage. These random rubble (RR) stone masonry structures located in high seismically active regions of the Himalayas have suffered varied degrees of damages in the past earthquakes. The study presents seismic vulnerability assessment of four archetypal monastic temples using finite element (FE) analyses. Linear and nonlinear analyses of these structures were conducted in Abaqus FE environment. These analyses identified the damage prone areas of the structures and provided load-deformation behavior under lateral loads. Fragility analyses indicate a high probability of collapse for the specified design level earthquake of the region. The study shows that performance of the structure can be enhanced by improving the strength and stiffness of the stone masonry walls.     

Fluid effect on hydraulic fracture propagation behavior: a comparison between water and supercritical CO2‐like fluid

The initiation of hydraulic fractures during fluid injection in deep formations can be either engineered or induced unintentionally. Upon injection of CO₂, the pore fluids in deep formations can be changed from oil/saline water to CO₂ or CO₂ dominated. The type of fluid is important not only because the fluid must fracture the rock, but also because rocks saturated with different pore fluids behave differently. We investigated the influence of fluid properties on fracture propagation behavior by using the cohesive zone model in conjunction with a poroelasticity model. Simulation results indicate that the pore pressure fields are very different for different pore fluids even when the initial field conditions and injection schemes (rate and time) are kept the same. Low viscosity fluids with properties of supercritical CO₂ will create relatively thin and much shorter fractures in comparison with fluids exhibiting properties of water under similar injection schemes. Two significant times are recognized during fracture propagation: the time at which a crack ceases opening and the later time point at which a crack ceases propagating. These times are very different for different fluids. Both fluid compressibility and viscosity influence fracture propagation, with viscosity being the more important property. Viscosity can greatly affect hydraulic conductivity and the leak‐off coefficient. This analysis assumes the in‐situ pore fluid and injected fluid are the same and the pore space is 100% saturated by that fluid at the beginning of the simulation.     

Koan amphorae from Halasarna – investigations in a Hellenistic amphora production centre

Ceramic amphorae have been the most popular transport and storage containers for a large variety of liquid and solid products. The amphorae of the present study were used as transport containers for wine from the island of Kos (East Aegean). Therefore, they had to fulfil certain requirements in terms of mechanical strength and toughness but also in terms of standardization of vessel size and shape. An assemblage of amphora fragments from the excavation of ancient Halasarna, an amphora production centre, will be presented. The ceramics were studied by means of their chemical and mineralogical composition and fabric. Furthermore, their material properties were measured and their mechanical performance was simulated in computer models.     

股东资格确认的法律问题研究

本文针对新《公司法》第33条确立的股东资格确认标准,就实践中出现的股东资格确认问题,对股东资格确认应当遵循的原则、要件及可能证据的效力进行了阐述,并进一步提出解决股东资格确认问题的对策。     

Deposition of annual growth lines in the apex of the common limpet (Patella vulgata) from Shetland Islands,UK and Norway: Evidence from field marking and shell mineral content of annual line deposition

The abundance, accessibility and value of limpets as a source of food and bait for coastal peoples have resulted in their high frequency in shell middens worldwide. The limpet Patella vulgata is found in middens from the Mediterranean to Norway, and morphometric and sclerochronological analyses of its shell can provide insight into harvesting patterns and paleoenvironmental variables valuable in reconstructing climate. Previous work with P. vulgata has relied on lines on the exterior of the shell, or on lines exiting on the shell surface in shell cross-section, as annual or sub-annual markers. Shell damage may compromise these lines and limit the use of some shells, but growth lines are also found in the better-preserved shell apex. We investigated whether the growth lines in the apex of P. vulgata from two locations in Northern Europe are annual using calcein-marking and recapture. Investigations were performed at one site in the Shetland Islands (UK) and at one site at the northern limit of P. vulgata's range in Northern Norway. We also used laser ablation to measure the concentration of minerals in the shells of two individuals from Shetland to determine if patterns of minerals suggested as bioproxies for temperature and productivity varied annually. All individuals deposited one growth line in the apex during their year in the field, and the lowest ratios of Sr/Ca and Ba/Ca and to a lesser extent Mg/Ca were coincident with annual lines on the shells from Shetland. Growth at both sites was modelled using the von Bertalanffy growth function, and apex growth was nearly five times faster in Shetland than in Norway, probably a result of differences in temperature between the two locations.