Klinkenberg gas slippage measurements as a means for shale pore structure characterization

Established techniques that have been successfully used to characterize pore systems in conventional reservoir rocks lack the resolution and scalability required to adequately characterize the nano‐ to micrometer scale pore systems found in shale and cannot be applied on stressed samples. We have therefore investigated the utility of Klinkenberg gas slippage measurements for shale pore structure characterization. In contrast to other approaches, slippage measurements characterize the effective porosity of core samples and can be applied at stress conditions experienced in the reservoir during production. Slippage measurements on horizontally and vertically oriented samples from the Eagle Ford Shale Formation, Texas, USA, at a range of stress states revealed two orders of magnitude in slippage variation over five orders of magnitude permeability range. Slippage measurements are negatively correlated with permeability and follow similar trends to those found in other studies on higher permeability rocks. The samples had varying degrees of slippage anisotropy, which allowed interpretation of the relative contribution of tortuosity and pore size to permeability anisotropy. Slippage and therefore average effective pore size was found to vary up to one order of magnitude at a given permeability, warranting investigation of the significance this might have on flow properties and ultimately hydrocarbon production from shale.     

Massive dolomitization of a Messinian reef in the Great Bahama Bank: a numerical modelling evaluation of Kohout geothermal convection

The hypothesis that Kohout thermal convection may have induced the massive dolomitization of the 60 m thick lowest more reefal unit in well Unda [top of Great Bahama Bank (GBB)] is evaluated through numerical modelling. A two‐dimensional (2‐D) section, including lithological and petrophysical data, together with datings for the sediments of the GBB, was used in the basin model TEMISPACK to reconstruct the history of the whole platform, with a focus on the reef unit. Simulations showed that during high sea‐level periods, Kohout convection is a valid mechanism in the settings of the GBB, although the convection cell remains flat in most cases because of high permeability anisotropy. This mechanism induces rapid fluid flow in the superficial as well as in the deeper parts of the platform, with velocities of at least two orders of magnitude higher than with compaction alone. Lithology appears as a strong control of fluid circulations at the margin scale through the permeability anisotropy, for which a critical value lies between values of 10 and 100. The reefal unit in Unda is part of a larger area determined by the lithologic distribution, in which flow velocities are significantly higher than in the rest of the platform. These velocities are high enough to bring the magnesium necessary to precipitate the observed amounts of dolomite, within durations in agreement with the available time of post‐reef deposition high sea level(s). However, neither fluid flow pattern nor flow velocities are able to explain the preferential massive dolomitization of the lower reef unit and the complete absence of dolomite in the upper one.     

A Comparative Study on the Compressive Strength of Bricks from Different Historical Periods

The aim of this article is to present the results of compressive strength tests for bricks from different historical periods. The studies were conducted on hand-molded and mechanically formed bricks. The bricks that were used for the studies came from historical structures from the center of the royal city of Crakow. Compressive strength was determined on rectangular prisms and on cylinders cut out from bricks in various directions—anisotropy and shape effects were then analyzed.

?The basic aim of the conducted studies was to estimate the possibility of carrying out the strength tests on relatively small samples and re-calculating these results on normalized brick strength determined according to EN772–1. Based on the tests results, a range of correlation coefficient values for cylinder samples with diameters of 30 mm and 50 mm was given. It was indicated that for the tested historical bricks characterized by significant material non-homogeneity within the element and sensitivity to damages while cutting out the samples, correlation coefficients are higher than for bricks used contemporarily.

?The results of these studies are presented alongside the findings from existing studies on the compressive strength of bricks.