LIME PLASTER AS AN ADHESIVE FOR HAFTING EIGHTEENTH-DYNASTY FLINT SICKLES FROM TELL EL DAB'A,EASTERN NILE DELTA (EGYPT)*

A combination of analytical techniques, including thin-section observations, scanning electron microscopy, X-ray diffraction and X-ray fluorescence analysis, was applied to study the nature and origin of an adhesive used for mounting flint sickle blades to a wooden handle, recovered from early Eighteenth Dynasty culture layers of the multi-layer settlement at Tell el Dab'a, Lower Eygpt. The results obtained from these investigations led to the conclusion that the adhesive is a pure lime plaster, thus providing the oldest evidence for the use of this material as a binding agent so far known in ancient Egypt.     

PHYSICO‐CHEMICAL CHARACTERIZATION OF THE ACQUALADRONE ROSTRUM

The archaeological discovery of the Acqualadrone rostrum (an offensive naval weapon mounted on the prow at the waterline), off the Italian coast near Messina in 2008, has led to the need for scientific research in order to plan the conservation treatment of this artefact. The discovery is exceptional because of the presence of a wooden section from the original ship. This paper describes the physico‐chemical characterization of a metallic and two wooden samples by inductively coupled plasma – optical emission spectroscopy, inductively coupled plasma – mass spectrometry, Fourier transform infrared spectroscopy, ¹³C {¹H} cross‐polarization magic angle spinning NMR spectroscopy, energy‐dispersive X‐ray spectroscopy, gas chromatography – mass spectrometry and X‐ray diffraction. The results reveal the use of leaded bronze (Cu, 70%; Pb, 20%; Sn, 10%) in the manufacturing process of the alloy and the use of lead whose isotopic composition is referable to either Spanish or Cypriot mines. The analysis of the results relating to the wooden samples indicates their different state of preservation and, at least in some places, the spreading of caulking on the wood, probably using a vegetable resin.     

MEDIEVAL LEAD GLASS IN CENTRAL EUROPE

In Trommsdorfstraße, Erfurt, a glass‐processing workshop has been excavated, which produced lead glass rings and beads in the 13th century. This workshop produced two different lead glasses. The first, a high‐lead glass, could be found throughout Europe, from England to Russia. However, another newly defined type of glass could be identified (Central European lead–ash glass). This can be demonstrated by analysing the literature, and it has been found in eastern Germany, Poland, Slovakia and the Czech Republic. A Slavic lead–ash glass with the same ash content as the Central European lead–ash glass but lower amounts of lead was produced in Eastern Europe. In western Germany, another type of ash (beech ash) was used to produce a wood‐ash lead glass. Lead‐isotope analysis proved that the same source of lead was used for the wood‐ash lead glass and the high‐lead glass in western Germany and the two types of glass from Erfurt.     

POROSITY DETERMINATION WITH HELIUM PYCNOMETRY AS A METHOD TO CHARACTERIZE WATERLOGGED WOODS AND THE EFFICACY OF THE CONSERVATION TREATMENTS

The helium pycnometer allows us to measure the cell‐wall density of dry woods and the basic density of wood samples soaked with water and/or a consolidant solution if a non‐volatile solvent is used. These parameters were correlated to the porosity, which for degraded waterlogged wood is related to the maximum water content. Moreover, this has revealed the possibility of investigating, by means of accurate cell‐wall density determination, the efficacy of several consolidants in the treatment of waterlogged woods.     

Fuel Management (Bone and Wood) During the Lower Aurignacian in the Pataud Rock Shelter (Lower Palaeolithic, Les Eyzies de Tayac, Dordogne, France). Contribution of Experimentation

The use of bone as fuel during the lower Aurignacian in the Pataud rock shelter was studied. An anterior study allowed us to dismiss the hypothesis of an imbalance between wood availability and the use of bone as fuel. An experimental study of bone combustion shows the specific properties of bone as fuel. We have proposed that the combustion of a mixture of material (wood and bone) is more effective as source of heat than the combustion of wood alone and the higher the proportion of bone the longer the combustion lasts. Lastly, we observed that the combustion of bone favours two kinds of heat transfer: radiation and convection, but that it is completely ineffective for conduction. The results show that the use of bone could result from an intentional management of fuel in relation with the function of the settlement. It also could be a response to the disadvantage of using wood in a Palaeolithic camp.     

CONIFEROUS WOOD PULP IN TRADITIONAL KOREAN PAPER BETWEEN THE 15TH AND 18TH CENTURIES ad*

One hundred and sixty‐nine fibre samples from books in the Korean collection and 68 samples from books in the Japanese collection at the British Library were analysed. A further 15 samples of Korean paper from a private collection were also examined. The analysis confirmed that most of the papers contained mulberry species (Moraceae family) as the main papermaking material, and other materials, such as hemp, rice straw and reed, which have been commonly known as supplements to traditional Korean papermaking. However, 15 Korean papers and one Japanese paper dating between ad 1498 and 1798 appeared to include coniferous wood fibres. This substantial find supports a previous single find of a coniferous wood fibre in Korean paper. The dates of most of these papers containing wood fibres precede the use of wood pulps in European paper.     

EVALUATION OF THE APPLICABILITY OF CONVENTIONAL METHODS FOR THE CHEMICAL CHARACTERIZATION OF WATERLOGGED ARCHAEOLOGICAL WOOD

A series of 112 waterlogged archaeological wood samples of different provenances, wood species, burial times and states of preservation were analysed with the aim of assessing the validity (in terms of limits and reliability) of procedures conventionally used in the pulp and paper industry, to evaluate the state of preservation of decayed wood. In particular, the extent of any damage wrought on decayed wood tissue by the repetitive cycles that characterize these procedures was evaluated as a function of the degradation of the samples. The results indicated that standard methodologies give reliable measurements regardless of the extent of wood decay. However, it is essential to compare these data with those of non‐decayed wood that has been measured using the same procedures to take account of the errors that are inherent in these methodologies and that affect measurements.     

The Use and Deployment of Modern Wood Samples as a Proxy Indicator for Biogeochemical Processes on Archaeological Sites Preserved in situ in a Variety of Environments of Differing Saturation Level

Abstract

In situ preservation of archaeological sites is becoming an ever increasing trend as a means of preserving our cultural heritage. In connection with this the environmental conditions, such as water level, dissolved oxygen, temperature, pH and water chemistry, of a site are often monitored. It is generally agreed that a waterlogged and anoxic environment is essential for optimal preservation conditions but the set-up and maintenance of an environmental monitoring programme can be costly.

This paper discusses the design and use of a system whereby modern samples of wood can, with a minimal disturbance of the soil, easily be deployed and retrieved from archaeological sites. The system was deployed in an unsaturated environment, an environment with fluctuating water levels and a fully saturated peat bog. The samples were assessed after two years using microscopic, physical and molecular biological methods, and the types of wood-degrading organisms seen were compared with the results of environmental measurements. Modern wood samples were used, as the microbial ecology of wood-degrading organisms in these different types of environments is relatively well documented. Preliminary conclusions show that the deterioration processes of modern wood samples in these environments act as a good proxy indicator of the environmental conditions and biogeochemical processes ongoing at a site.     

Potassium–Calcium Glass: New Data and Experiments*

The chemical composition of potassium–calcium ‘wood‐ash’ glass reflects the elemental pattern of the involved non‐volatile base materials in quartz sand, wood ash and possibly potash. The essential elemental ratio K₂O/CaO of wood ash varies between 0.2 and 0.8, and depends on the habitat and geological substratum of the wood rather than on the tree species; ratios between 1.0 and 3.0 in wood‐ash glass are only possible when potash is added as a third base material. Melting temperatures of wood‐ash glass sensu stricto, termed K–Ca‐2, produced with the two raw materials quartz sand and wood ash, are between 1250°C and 1400°C, while those of three‐component‐glasses, termed K–Ca‐3, are between 900°C and 1250°C, according to the amount of added potash. Experimentally produced glass displays different hues, from colourless to brown, olive‐green and pink, according to the chemical composition of the wood ash. Elevated MnO concentrations between 0.5 and 3 wt% may originate from wood ash and are hence not necessarily an indicator of colour‐inhibiting additives. Phosphate stemming from wood ash is an essential discriminator between wood‐ash glass and potash–lime glass. Because wood ash contains only minor amounts of sodium, wood‐ash glass with equal concentrations of potassium and sodium is a hybrid glass type, where besides quartz sand, wood ash, possibly potash and also soda‐rich cullet have been applied for glass production.     

DETERIORATION ASSESSMENT OF WATERLOGGED ARCHAEOLOGICAL LIGNOCELLULOSIC MATERIAL VIA 13C CP/MAS NMR*

This study investigates the residual chemical composition of waterlogged archaeological lignocellulosic material found in Greece. Hazelnut pericarps and oak wood found in a 16th‐century wreck, along with endocarps of olives dated at 300 bc , were examined. ¹³C CP/MAS NMR was applied to compare fresh and waterlogged archaeological materials. Results show qualitative alterations in their composition. The virtual absence of peaks at ~21 ppm and ~173 ppm, corresponding to hemicelluloses in all archaeological materials, indicates that these constituents can be an important indicator in assessing the type and degree of deterioration.