NUCLEAR MAGNETIC RESONANCE SPECTROSCOPIC AND ISOTOPIC ANALYSIS OF CARBONIZED RESIDUES FROM SUBARCTIC CANADIAN PREHISTORIC POTTERY

Late prehistoric pottery is found in abundance at archaeological sites around Southern Indian Lake. Black residues, found on the two dominant vessel forms, flat plates and round pots, are presumed to be the remains of prehistoric meals. ¹³C cross-polarization magic-angle-spinning nuclear magnetic resonance spectroscopy (CPMAS NMR) and¹³C and¹⁵ N isotopic ratios and C/N ratios are used to reconstruct prehistoric diet and to shed light on possible uses for the plates. Samples of foods were cooked in clay pots, on a wood fire, to simulate the conditions of burning that could have produced the residue. Decomposition of carbohydrates, protein, and fat during cooking is studied with ¹³C CPMAS NMR, and the effect of cooking on isotopic and C/N ratios documented. Predominantly fish and fat were cooked in the pots, whereas the residues from plates contain a greater proportion of fat and could have been used as frying pans or possibly as fat-burning lamps placed on the ashes of a wood fire.     

Charcoal analysis of industrial fuelwood from medieval and early modern iron-working sites in Bilsdale and Rievaulx,North Yorkshire,UK: evidence for species selection and woodland management

Abstract

This paper presents the results of species diversity and dendrological analyses of archaeological charcoal excavated from medieval and early modern iron production sites in Bilsdale, and at Rievaulx in the neighbouring valley of Ryedale, North Yorkshire, UK. Standard methods of quantification are used to assess species diversity, sampling sufficiency and taxa presence. The assessment of dendrological features provides additional evidence for growth trends and cutting cycles analogous with cyclical woodland management, as well as environmental and growing conditions. Analysis of archaeological charcoal from four medieval bloomery furnace sites in Bilsdale, and from the site of the hammersmithy and blast furnace at the early modern iron works at Rievaulx, provide comparable data-sets which indicate a change in cutting practise and dominant species selection for industrial fuelwood occurred between the 12th- and mid-16th centuries AD. Results show that dominant species presence changed from an admixture of predominantly birch (Betula sp.) and hazel (Corylus avellana) sourced from small calibre branchwood and stemwood used in the medieval bloomery furnaces, to a dominant oak (Quercus sp.) presence from standard sources used at the Rievaulx iron works by the mid-16th century. Whilst it is uncertain whether this change in dominant species composition and the source of industrial fuelwood is related to changes in local availability, or the result of the technological transition to blast furnace processing which occurred at this time, estate records reveal a woodland management campaign was instigated to supply and maintain fuelwood supplies to the iron works at Rievaulx which coincides with the introduction of Tudor arboricultural legislation in the 1540s.