一种油画颜料层裂纹的修复技术分析

油画颜料层裂纹是一种常见的病害类型,严重的裂纹会影响作品的视觉效果。裂纹修复所采取的措施应以缓解病害,延续寿命为目标,避免不当修复对其文物价值的改变。本研究通过红外光谱和便携式X荧光能谱分析,初步确定了裂纹产生的原因与材料技法和机械作用力有关,长期的温湿度波动则是最终形成老化裂纹的重要因素。对两类常见的裂纹加固方法比较后得出结论,色蜡改变了原画的光泽度和肌理层,动物胶调碳酸钙更适宜作为裂纹的填补材料。观察修复后的油画保存状况,发现经过修复的颜料层仍存在继续劣化的风险,必须维持保存环境的相对稳定,方可延长修复周期。     

Influence of Taoism on the invention of the purple pigment used on the Qin terracotta warriors

Until the 19th century, most pigments were based on naturally occurring colored minerals and dyes, with three significant exceptions: Egyptian Blue, Chinese Blue/Purple and Maya Blue. The former two are alkaline-earth copper silicates, and because of this similarity it has been proposed that the Chinese pigments were derived from Egyptian Blue. Herein, we analyzed clumps of pigment from the Qin warriors and discovered that in spite of the structural similarity to Egyptian Blue, the micro-structural morphology of Chinese Purple is very different. Therefore, we believe that the synthesis technology for the Chinese pigments was a by-product of high-refractive index glasses (artificial jades) produced by Taoist monks. Further, the disappearance of these pigments from Chinese art and monuments concurrently with the decline of Taoism not only substantiates the link between the two, but also gives a striking example of how cultural changes in the society affected the scientific developments in ancient China.     

Can the Raman spectrum of anatase in artwork and archaeology be used for dating purposes? Identification by Raman microscopy of anatase in decorative coatings on Neolithic (Yangshao) pottery from Henan,China

Scanning electron microscopy/energy dispersive X-ray analysis has earlier shown that the white background layer (slip) on painted pottery sherds (Yangshao culture, Henan, China, 4200 BC) is composed of kaolinitic clay containing titanium in the assumed form of TiO₂ at just 1 wt%. The same samples of white slip have now been studied by Raman microscopy, revealing bands characteristic of anatase, but none from the majority species, the matrix of kaolinitic clay. These results highlight the extraordinarily intense Raman scattering from even trace amounts of anatase and thus the need to recognise that, although the colours of archaeological artefacts are almost always determined by the nature of the matrix, the Raman spectrum may be determined by a highly scattering trace component such as anatase. The significance of anatase as a potential date-marker pigment on works of art and archaeological artefacts is discussed.     

光导纤维光谱技术无损鉴定彩绘文物颜料的研究

为了克服传统的有损文物分析技术对文物造成的破坏,研制出一种简易光导纤维反射光谱仪。建立了光导纤维反射光谱技术对颜料分析鉴定的基本方法,提供了一种简捷的文物颜料无损分析鉴定的新技术。通过对西安、重庆等地彩绘文物颜料成分的鉴定,表明光导纤维反射光谱法测量结果准确、可靠,在文物颜料鉴定等方面具有广阔的应用前景。     

陕西蓝田水陆庵彩绘泥塑颜料分析研究

水陆庵位于陕西蓝田王顺山下,庵内现存三百余平方米精美绝伦的明代彩绘泥塑,是我国泥塑保存最多、最完整的明代彩绘泥塑群之一。为明确水陆庵彩绘泥塑的颜料使用情况,采用光学显微镜、X射线衍射仪、显微红外光谱仪、扫描电镜-能谱仪和显微拉曼光谱仪对颜料样品进行科学分析。结果表明,除中隔壁背面重妆区域的蓝色颜料主要成分是普鲁士蓝之外,水陆庵彩塑使用的颜料大多为矿物颜料,包括铅丹、朱砂、铁红、氯铜矿、雌黄和云母等。研究结果将为水陆庵后续保护修复提供科学依据,并为丰富关中地区明代彩绘泥塑颜料类型补充科学信息。     

A Pigment Characterization Approach to Selection of Dating Methods and Interpretation of Rock Art: The Case of the Mikinak Site,Lake Wapizagonke,Quebec, Canada

Dating is perhaps the most frequently asked question in rock art studies, but still one of the most difficult to answer. However, chronology is vital in order to understand and interpret rock art sites. Unfortunately, attempts at dating the Mikinak site, at Lake Wapizagonke, Quebec, Canada were unsuccessful. But a multi‐instrumental protocol applied to characterize paintings shows that at least three different paint recipes were employed to create the site. These may reflect three different phases of paintings, and that at least three different artists contributed to the production of this site.     

河北隆化鸽子洞元代窖藏织绣品蓝色染料分析

采用光学显微观察、激光拉曼、紫外-可见吸收光谱以及高效液相色谱对河北隆化鸽子洞蓝棉袄蓝色、浅蓝色纤维以及百衲枕顶蓝色纤维进行分析研究.通过多种分析手段相互佐证表明,该组样品采用蓝草中的靛蓝染色,色素成分有靛蓝素和靛玉红.各样品中色素成分比例均不相同,推测至少在元代,人类已经能够有意识地调整制靛工艺,染出自己需要的色光.同时靛蓝染料耐光性耐热性差,对酸、碱和氧化均敏感,耐盐性及耐细菌性较弱.在以靛蓝染色的织物清洗中,要选择性地使用洗涤剂,进行点滴试验后才可使用,同时在存放过程中要做到避光、避免高温.     

Pigment analysis in Bronze Age Aegean and Eastern Mediterranean painted plaster by laser-induced breakdown spectroscopy (LIBS)

Laser-Induced Breakdown Spectroscopy (LIBS) was used in the examination of Bronze Age painted plaster samples from several sites in the Aegean and Eastern Mediterranean. The elemental content of paint materials was determined in most cases leading to the identification of the pigment used in agreement with data from analyses of the same samples with other established techniques. The analyses demonstrate that a virtually non-destructive technique such as LIBS provides sufficient data for the elemental characterisation of painting materials while in parallel has the capability for routine, rapid analysis of archaeological objects enabling the quick characterisation or screening of different types of artefacts. This certainly shows an important way forward in technological studies of fragile and scarce archaeological material.     

常熟赵用贤宅无地仗层彩绘的保护研究

赵用贤宅彩绘是江苏明代无地仗层彩绘的重要遗物。为对其进行保护,采用XRD、FT-IR、EDS及视频显微镜等检测分析彩绘成分和结构层次,较为成功地解决了旧木材内油溶性成分极易因溶剂作用带出,部分彩绘上人为涂饰石灰、涂料的去除等技术难点。同时采用接近原胶粘剂性能的复合天然材料(脱色明胶和壳聚糖复配物)加固彩绘,并以溶剂型有机硅材料封护保护。结果表明,保护处理后不仅有效地延长了加固材料的寿命,同时符合可再处理原则。