Geochemical evidence for the manufacture,logistics and supply‐chain management of Emperor Qin Shihuang's Terracotta Army,China

Non‐invasive materials characterisation of reconstructed statues of Emperor Qin Shihuang's Terracotta Army has revealed distinct micro‐geochemical patterning within the clay paste used in their manufacture. The significance of this is explored in terms of the production sequence, logistics and supply‐chain management involved in the construction of this enormous funerary assemblage. Of particular interest is a compositional distinction between figures marked with the names ‘Gong’ (宫) and ‘Xianyang’ (咸阳). These seem to represent the products of two workshops involved in the supply of ceramic objects for this ambitious, large‐scale building project undertaken by the Qin Empire during the third century bce .     

Roman pottery production in Civitas Tungrorum,central Belgium,during the first–third centuries ce

Aspects of Roman pottery production at the workshops of Kontich, Tienen, Rumst, Grobbendonk and Clavier-Vervoz in the Civitas Tungrorum of central Belgium are explored. A total of 150 wasters from five sites were studied macroscopically, as well as via a combination of thin-section petrography, geochemistry and scanning electron microscopy, in order to gain insights into ceramic technology and aspects of the organization of production. Particular emphasis was given to the individual technological sequences and shared strategies of raw material selection, paste preparation and firing employed at the five adjacent sites. The integration of petrographic and geochemical data permitted the establishment of compositional reference groups for the Roman kiln sites of Civitas Tungrorum, which can be used to track their products within the surrounding landscape.     

Geoarchaeology and spatial distributions of the ‘Coche Quemado' obsidian source in north-western Patagonia

In north-western Patagonia, obsidian was used during the entire Holocene, and its importance increased with time. Recent fieldwork discovered a new obsidian source located in the Río Grande, which was called ‘Coche Quemado' (CQ). The results indicate that the CQ source has a different geochemical signal than all other sources in the region. Its use is spatially restricted to piedmont and, to a lesser extent, the plains. Chronologically, CQ was exploited in the middle and late Holocene, and its use accounts for a range of spatial distribution between 150 and 200 km.     

Chemical and isotopic signatures of Na/HCO3/CO2‐rich geofluids,North Portugal

Geochemical and isotopic studies have been undertaken to assess the origin of CO₂‐rich waters issuing in the northern part of Portugal. These solutions are hot (76°C) to cold (17°C) Na–HCO₃ mineral waters. The δ²H and δ¹⁸O signatures of the mineral waters reflect the influence of altitude on meteoric recharge. The lack of an ¹⁸O‐shift indicates there has been no high temperature water–rock interaction at depth, corroborating the results of several chemical geothermometers (reservoir temperature of about 120°C). The low ¹⁴C activity (up to 9.9 pmC) measured in some of the cold CO₂‐rich mineral waters (total dissolved inorganic carbon) is incompatible with the presence of ³H (from 1.7 to 4.1 TU) in those waters, which indicates relatively short subsurface circulation times. The δ¹³C values of CO₂ gas and dissolved inorganic carbon range between ?6‰ and ?1‰ versus Vienna‐Peedee Belemnite, indicating that the total carbon in the recharge waters is being diluted by larger quantities of CO₂ (¹⁴C‐free) introduced from deep‐seated (upper mantle) sources, masking the ¹⁴C‐dating values. The differences in the ⁸⁷Sr/⁸⁶Sr ratios of the studied thermal and mineral waters seem to be caused by water–rock interaction with different granitic rocks. Chlorine isotope signatures (?0.4‰ < δ³⁷Cl < +0.4‰ versus standard mean ocean chloride) indicate that Cl in these waters could be derived from mixing of a small amount of igneous Cl from leaching of granitic rocks.     

The origin of black pigmentation in a sample of Mexican prehispanic human bones

The study of black patches and spots in prehispanic bones of Tlatelolco and Tlapacoya is presented. The chosen characterization techniques, X-ray Fluorescence, X-ray Diffraction, Scanning Electron Microscopy, Energy Dispersive X-ray Spectroscopy, Infrared Spectroscopy and Gas Chromatography are complementary and they all conclude that the bone black pigment is constituted, mainly, by amorphous carbon and some mineral inclusions. Gas Chromatography and Infrared Spectroscopy show that the pigment is constituted by organic compounds as aromatic hydrocarbons, mainly bitumen. An explanation on how the spots were formed is proposed.     

A Multi-Method Approach to Reconstructing Occupational History and Activity Areas: A Case Study at the Formative Site of Tlalancaleca,Central Mexico

While surface collection constitutes an important component of field research at the site and regional levels, the association between surface and sub-surface materials needs to be examined through independent lines of evidence. This study employed manual bucket auger probing and soil geochemistry at the Formative site of Tlalancaleca, Central Mexico (800 b.c.–a.d. 250), to evaluate the results of surface collection and to understand the formation process of the anthropogenic landscape. The combined results at one of the largest architectural complexes at Tlalancaleca indicate that it was built during the Late Formative period (500–100 b.c.) and rebuilt during the subsequent Terminal Formative period (100 b.c.–a.d. 250), which is corroborated by radiocarbon dates. Moreover, the results suggest segregated uses of space such as cooking/storage, waste disposal, and craft production areas within the complex. Overall results demonstrate the effectiveness of this multi-method approach for reconstructing occupational history and activity areas.     

Evaluation of Fe isotope values as a provenance tool for chert artefacts from the north-eastern United States

Iron (Fe) isotope compositions of prehistoric stone tools and geological sources were compared to evaluate the robustness of this isotopic fingerprinting technique. Artefacts and source materials were collected from the Hatch site in central Pennsylvania, United States, where both veined chert (Bald Eagle chert) and stone tools coexist within several metres. Yellow artefacts (δ⁵⁶Fe = 0.38 ± 0.1, n = 7) and source materials (δ⁵⁶Fe = 0.42 ± 0.1, n = 8) isotopically matched within error. The source values also overlap yellow chert samples from three other Bald Eagle chert locations in the area. These values are different from six other chert locations in the north-eastern United States. These data suggest that the Fe isotope composition of chert artefacts reflect distinct geological sources. To enhance the mechanical characteristics of the stone tools, the chert experienced heat treatment, which induced a phase shift of the Fe oxide mineral goethite to hematite. This phase shift changes the colour of the chert to red. The red chert artefacts and source material also have overlapping Fe isotope values, but are 0.2‰ higher than the initial yellow chert. Experimental work where cherts were heated with different clays shows that Fe exchange with site soils induces the +0.2 fractionation. These data demonstrate that predictable Fe isotope fractionation occurs during heating, resulting in isotopically distinct artefacts.     

Diagenesis and elemental geochemistry under varying reservoir oil saturation in the Junggar Basin of NW China: implication for differentiating hydrocarbon‐bearing horizons

In this paper, we attempt to differentiate hydrocarbon‐bearing reservoir horizons of the Junggar Basin of NW China based on the characteristics of diagenesis and associated elemental geochemistry. Reservoirs at this site have varying levels of oil saturation that correlate with the degree of dissolution in minerals (e.g., calcite and feldspar). Four different horizons with varying diagenetic mineral assemblages were observed, including (i) kaolinite‐rich, oil‐dominated horizons, (ii) kaolinite–pyrite–hematite‐rich, oil–water‐dominated horizons, (iii) siderite–chlorite‐rich, water‐dominated horizons, and (iv) chlorite‐rich horizons with negligible hydrocarbon production. The mean MnO content of the representative diagenetic mineral (e.g., calcite) in each of the above horizons is >2.5, 2.0–2.5, 1.5–2.0, and <1.0 wt%, respectively. We propose that the above methodology can be used for the identification of reservoir hydrocarbon‐bearing horizons. We argue that the indicators presented here can be applied in oil exploration across the Junggar Basin.     

Obsidian sources in highland Yemen and their relevance to archaeological research in the Red Sea region

The Red Sea and surrounding area formed through dynamic uplift and rifting of Afro-Arabia, and associated volcanism (both oceanic and continental in character). As a result, volcanic landforms and products are widespread and play a vital role in the natural and cultural landscapes of humans occupying the highlands and lowlands on both sides of the Red Sea. Archaeologists have suggested for some time that Afro-Arabian trade in obsidian had its roots in the prehistoric period and that the region was very likely the source of an abundance of obsidian artefacts found as far afield as Egypt, the Persian Gulf and Mesopotamia, and which do not match the well-known Anatolian, Transcaucasian or Mediterranean sources. Nonetheless, the southern Red Sea is one of the few obsidian-rich regions exploited in antiquity that has been barely investigated. In this paper, we highlight new geochemical analyses (carried out by LA-ICP-MS) of obsidian sources in Southern Arabia and beyond, that enhance our knowledge of obsidian exploitation from as early as the Neolithic period, and which enable us to evaluate the role that highland Yemen obsidian sources played in prehistoric long-distance trade. In addition, we present new evidence for explosive volcanic eruptions that likely affected the highland populations of Yemen in the 4th millennium BC.