一种油画颜料层裂纹的修复技术分析

油画颜料层裂纹是一种常见的病害类型,严重的裂纹会影响作品的视觉效果。裂纹修复所采取的措施应以缓解病害,延续寿命为目标,避免不当修复对其文物价值的改变。本研究通过红外光谱和便携式X荧光能谱分析,初步确定了裂纹产生的原因与材料技法和机械作用力有关,长期的温湿度波动则是最终形成老化裂纹的重要因素。对两类常见的裂纹加固方法比较后得出结论,色蜡改变了原画的光泽度和肌理层,动物胶调碳酸钙更适宜作为裂纹的填补材料。观察修复后的油画保存状况,发现经过修复的颜料层仍存在继续劣化的风险,必须维持保存环境的相对稳定,方可延长修复周期。     

Degradation processes in colourless Roman glass: cases from the Bocholtz burial

A group of Roman glass objects from the Bocholtz burial in the SW of Limburg (The Netherlands) was found to have been subject to varying degrees of degradation. Many of the 25 colourless glass objects were fragmented to pieces <0.1 cm (“sugared”), whereas the three transparent blue-green glass objects were in near-pristine state. Analyses using SEM, XRF and EDS revealed that the fragmentation was the direct result of the intense leaching of Na₂O from the glass structure and its replacement with water. The resulting gel layers with low-Na₂O contents and large amounts of water are sensitive to cracking when they dry out. Thin-walled glass appears to be less sensitive to cracking from the resulting stress than thick-walled glass. Local differences in the moisture regime during burial also influence the severity of the glass degradation. Glass with low concentrations of CaO seems to be the most sensitive to this form of degradation. The typical blue-green Roman glass is less sensitive as it generally has considerably higher concentrations of CaO.     

An experimental and modeling study of Na-rich hydrothermal alteration

Sodic alteration assemblages including clinoptilolite, mordenite, analcime and Na‐montmorillonite were locally observed in sediments in the eastern part of the Hachimantai geothermal region, northeast Japan. This study investigated the mechanisms of sodic enrichment in the sediments during alteration. Kinetic results for water/rock interaction experiments are reported here. Batch‐type experiments were conducted at 150–250°C under saturated vapor pressure. Pyroclastic rocks dissolved incongruently in these experiments, and the solubility and dissolution rates among elements varied as follows: the apparent steady‐state concentrations of major elements are Si > Na ? K > Ca > Al and the order of the dissolution rates is Si > Al > Na ? K > Ca. Na had the highest steady‐state concentration and fastest dissolution rate of the alkali and alkali earth metal ions. Based on surface analysis of plagioclase, dissolution was effected via a reaction layer of Na‐montmorillonite on the mineral surface. Additionally, a reaction model constructed based on the experimentally observed reaction mechanism quantitatively explains the dissolution behavior. These results show that Na‐montmorillonite can be precipitated by pyroclastic rock/meteoric water interactions without seawater involvement: the Na is derived from the host rocks.     

青铜器锈蚀结构组成及形态的比较研究

采用X射线衍射(XRD)、扫描电镜(SEM)、X射线电子能谱(EDS)和金相显微镜(OM)等方法,分析比较了染有“粉状锈”与未染“粉状锈”的典型青铜残片的锈蚀产物的矿物组成、腐蚀层分层结构及金相组织。结果发现,未染有“粉状锈”的青铜样品腐蚀层一般分为二层,外层是二价铜化合物,合金组织中未见α (α δ)组织,锈蚀产物中不含碱式氯化铜;而染有“粉状锈”的青铜样品都含有碱式氯化铜,其断面腐蚀层分三至四层,且每层锈体的结构和元素组成各不相同,在靠近合金基体层的锈层中发现了大量的CuCl存在。结果表明,青铜文物表面锈蚀覆盖层的致密性、空气中的湿度及锈层中CuCl层状分布的存在,是青铜器表面“粉状锈”形成和发展的根本原因。     

Chemical modification of pyroclastic rock by hot water: an experimental investigation of mass transport at the fluid–solid interface

Hydrothermal water–(pyroclastic) rock interactions were examined using flow-through experiments to deduce the effect of mass transport phenomena on the reaction process. A series of experiments were conducted over the temperature range 75–250°C, with a constant temperature for each experiment, and at saturated vapour pressure, to estimate the apparent rate constants as a function of temperature.
Based on the chemistry of analysed solutions, the water–rock interaction in the experiments was controlled by diffusion from the reaction surface and by the existence of a surface layer at the rock–fluid interface, which regulated the chemical reaction rate. The reaction progress depended to a high degree on flow velocity and temperature conditions, with element abundances in the fluid significantly affected by these factors. Mass transport coefficients for diffusion from the rock surface to the bulk solution have been estimated. Ca is selectively depleted under lower temperature conditions ( T  < 150°C), whereas Na is greatly depleted under higher temperature conditions ( T  > 150°C), and K reaction rates are increased when flow velocity increases. Using these conditions, specific alkali and alkali earth cations were selectively leached from mineral surfaces. The 'surface layer' comprised a 0.5–1.8 mm boundary film on the solution side (the thickness of this layer has no dependence on chemical character) and a reaction layer. The reaction layer was composed of a Si, Al-rich cation-leached layer, whose thickness was dependent on temperature, flow velocity and reaction length. The reaction layer varied in thickness from about 10⁻⁴ to 10⁻⁷ mm under high temperature/low fluid velocity and low temperature/high fluid velocity conditions, respectively.     

基于旅游行为的旅游目的地空间层次与管理

关于旅游目的地的空间研究比较丰富,视点主要在于经济与地理空间。但是,旅游业是市场导向非常明显的行业,从旅游行为角度研究旅游目的地的空间层次更具有现实意义,对指导旅游目的地的开发和管理更具有操作性。本论文从旅游行为导向、管理方便性角度,融入社区理念,提出了新的旅游目的地解读,将其划分为三个空间层次,即游览服务区、社区服务区和社会服务区,并分析了它的空间层次结构关系和主要要素。论文最后从规范管理角度提出管理层次与关系。     

世界城市全球化空间的演变与重塑模式——以柏林波茨坦广场为例

全球化空间的产生与发展是世界城市以及发展中的世界城市具有普遍意义的空间议题。运用问卷分析、半结构访谈及文本分析相互佐证的数据,借助三角验证法,对柏林波茨坦广场全球化空间的形成动力与影响因素进行了系统研究。研究表明：①柏林波茨坦广场全球化空间形成的核心动力是跨国政治的作用,以一种历史层累的模式,不断杂糅、混合进生产性服务业集聚的经济动力和世界性艺术文化设施集聚的文化动力。②不同时期全球政治局势、国家及城市发展历史、政府作用、城市重建是波茨坦广场全球化空间形成的影响因素。这些因素在不同历史时期作用于波茨坦广场,综合了跨国政治、跨国经济、跨国文化的空间形态要素,引发波茨坦广场数次地景变迁与功能重组,最终形成了世界上“独一无二”的全球化空间。③波茨坦广场的重建是其全球化空间重塑的关键环节,其空间重塑模式为由单一要素主导转向多种要素融合的国家主导发展模式。对中国世界城市全球化空间的建设与治理具有启示作用。     

19世纪中国外销油画的白色颜料研究——以《上海外滩》油画为例

外销油画(export oil painting)作为中国早期油画遗存,不仅呈现了中国南方沿岸城市的地理风貌和风土民俗,而且蕴藏着中国早期本土油画的制作技艺。本研究采用X射线荧光光谱、扫描电子显微镜-能谱,并结合傅里叶变换显微红外光谱和拉曼光谱调查了一幅19世纪中国外销油画《上海外滩》中所用白色颜料的种类及其使用方法。研究结果表明:该幅清代油画画作底子所使用的白色颜料主要为白垩(CaCO₃)和石英(SiO₂);在颜料层中发现含锌颜料与油性媒介发生化学反应的产物羧酸锌(金属皂)。本研究为中国早期外销油画的材料与技法研究及修复保护提供了参考依据。     

Studies On Lacquerwares from Between the Mid‐Warring States Period and the Mid‐Western Han Dynasty Excavated in the Changsha Region

The development of lacquerwares reached its peak between the Warring States Period and the Han Dynasty (390–87 bc ) in the Changsha region of China. By studying excavated fragments of lacquers from this period, this paper examines the constitution of various pigmented layers, such as red, black and white layers, coloured lacquer layers, namely reddish brown or reddish orange, dark‐coloured or black, and silver lacquer layers, using non‐destructive methods. In addition, the characteristics of lacquer production techniques in Changsha are also discussed in comparison with those of other regions in China during the same period of time.     

《百苗图》传世抄本收藏情况概说

《百苗图》是清代绘画记录当时各地苗族的生产、生活、娱乐和习俗等风情的历史图册,是珍贵的历史民族志。“百”是概数,含多之意,并不是指有百幅苗族画图,也不是指有百支苗族。《百苗图》形象再现了苗族支系的繁多和丰富多彩的历史文化,具有重要的历史、艺术和科学价值。《百苗图》原本已佚,后世转抄临摩者众多,据初步查寻,目前在国内外收藏尚存的《百苗图》抄本、印本估计不下100种。主要收藏在中国大陆和台湾各图书馆现藏,在海外如德国、英国、日本等国家的图书馆也有收藏。