Analysis of adhering organic residues of two “coupes-à-socles” from the Neolithic funerary site “La Hougue Bie” in Jersey: evidences of birch bark tar utilisation

The “coupes-à-socle” (footed cups) are ceramics which can be found in domestic Neolithic contexts in Brittany (Castellic, Auzay-Sandun), but more generally in non-domestic areas. Their ceremonial function has often been evoked, in particular as a perfume burner. The analysis by GC and GC/MS of two samples from the “Hougue Bie” (Jersey) passage graves showed the presence of vegetable fatty acids, degraded n-alkanes and terpenoïds, biomarkers of birch bark tar. The presence of such substances could be explained either by the use of the “coupes-à-socle” for burning birch bark tar as an odoriferous product or their use as an everyday vessel for heating and increasing tar plasticity. However, the limited occurrence of this type of ceramic in habitat sites supports the former utilisation. This first report of the presence of birch bark tar in “coupes-à-socle” thus suggests use of this tar as an odoriferous product, in addition to its numerous, previously recognised, more technical uses.     

Chemical analyses of the earliest pigment residues from the uttermost part of the planet (Beagle Channel region,Tierra del Fuego,Southern South America)

This paper presents the results of chemical analyses of the organic and inorganic fractions of pigment residues found in three archaeological sites located in the Beagle Channel region, Tierra del Fuego, Southern South America. Twenty-one archaeological samples have been analysed through XRD, SEM–EDX, FT-IR and GC–MS in order to characterise their inorganic colouring components and to search for the presence of organic substances used as binders. Lipids found in some samples are considered as potential binders. These organic components are compared to those found in archaeological sediment samples from the same layers where the pigments have been found, in order to search for potential taphonomic contaminations of the latter by the former. Results show that such contaminations are unlikely, hence the lipid contents are deemed of anthropic origin. The pigment sample results are also compared to data from analyses of natural sediment samples collected in several localities of the Beagle Channel in order to search for potential natural pigment sources. Results show that organic and inorganic components of these sediments are not the same than those present in the archaeological pigment samples, hence the pigment raw material sources have not been yet located. All these data provide for the first time evidence of the existence of ancient activities of pigment sourcing and paint preparation with organic binders which range from 6000 BP to 1900 BP in the southernmost region of the planet.     

Bedding, hearths, and site maintenance in the Middle Stone Age of Sibudu Cave, KwaZulu-Natal, South Africa

Micromorphological analysis of sediments from the Middle Stone Age site of Sibudu Cave, KwaZulu-Natal, South Africa, provides a high-resolution sequence and evidence of site formation processes of predominantly anthropogenic deposits. This methodology allows for a detailed interpretation of individual anthropogenic activities, including the construction of hearths and bedding and the maintenance of occupational surfaces through the sweep out of hearths and the repeated burning of bedding. This analysis also provides a context for evaluating other studies at the site relating to magnetic susceptibility, paleobotany, paleozoology, anthracology, and studies of ochre.     

A new approach to recording and monitoring wet-preserved archaeological wood using three-dimensional laser scanning

The analysis and preservation of organic materials preserved within wetland environments represents one of the most costly parts of any post-excavation strategy. This paper outlines the application of high-resolution terrestrial laser scanning to one class of preserved material, worked archaeological wood. Scanning allowed the recording of the artefacts in three dimensions and the identification of features such as toolmarks. Features can be measured and volumetrically modelled within the digital environment, which may not always be possible for these often fragile materials using conventional techniques. Repeat scanning of the artefacts provided an opportunity to use comparative analysis software to investigate changes in the morphology of artefacts under contrasting conditions of short-term storage. The results suggest that immersion in water results in the least deterioration, whereas both freezing and air-drying caused distortion and degradation. This paper demonstrates that laser scanning provides a viable alternative post-excavation method for the recording, analysis and long-term ‘virtual archiving’ of organic archaeological materials, which may be more cost-effective in some instances than other methods of preservation.     

Subsistence practices and pottery use in Neolithic Jordan: molecular and isotopic evidence

This paper presents direct evidence of subsistence practices and pottery use at a Late Neolithic site at al-Basatîn, northern Jordan. Measurable concentrations of C_16:0 and C_18:0 were recovered from 8 of 10 archaeological pottery fragments through use of a microwave-assisted silica gel and aminopropyl solvent protocol developed for the isolation and concentration of free fatty acids in marine sediments. Subsequent isotopic analysis of the surviving C_16:0 and C_18:0 saturated fatty acids revealed ∂¹³C ratios consistent with those of adipose fats of ruminant and non-ruminant animals pastured on lands adjacent to the Jordan Valley. The high recovery of diagnostic compounds from the al-Basatîn material is discussed in context of a wider examination of the initial development and use of pottery in the Fertile Crescent, and the emerging debate concerning the efficacy of stable carbon isotope values in characterizing organic residues embedded in pottery fragments recovered from the earliest ceramic horizons in the Middle East and Europe.     

The Possible Advantage of Living in Turf Houses on Settlement Mounds

Abstract

Before timber and stone houses were introduced to northern regions, varieties of turf houses were the most commonly used architecture. These houses had a wooden structure encapsulated in a shell constructed of grass turf. The different ethnic groups of the north built their houses in different styles and constructions, but the general principle was the same. The Norse of North Norway and also on the North Atlantic islands had a tendency to build their houses on top of the ruins of previous houses. After a few centuries this arrangement produced a settlement mound of highly organic soil. In the research literature, both the turf architecture and the settlement mounds have been described as adaptations to and a function of marginality and lack of timber. This paper reports an effort to test the idea that turf houses on top of settlement mounds may have been a finely tuned ecological system that made use of the capacity of organic soil to produce heat.     

Identifying wine markers in ceramics and plasters using gas chromatography–mass spectrometry. Experimental and archaeological materials

The identification of the organic residues preserved in archaeological materials yields good insights into understanding food production, trade and consumption. Wine is one of the most important beverages produced, traded and consumed in the Mediterranean area. Consequently, it is important to identify its presence in ancient materials. Nevertheless, the identification of wine markers is still an object of discussion. We present here the results obtained from analysing different materials using gas chromatography/mass spectrometry (GC/MS), which allowed for the identification of tartaric acid and other markers of wine. The method was first tested on experimental and traditional materials that have been used until recently to store and/or produce wine and was then used for investigating archaeological materials. The experiments also involved the degradation of wine through cooking, drastic heating and burial for seven years. The results from the analysis of ceramic and plaster materials are discussed.     

Sustainability transformations in the balance: exploring Swedish initiatives challenging the corporate food regime

ABSTRACT

This paper explores to what extent organic initiatives that go beyond mainstream organic (so-called Organic 3.0) can challenge the corporate food regime and how they can push the food system towards sustainability transformations. We depart from the assumption that individual initiatives may differ in their potential to influence the corporate food regime and that this potential can be assessed by examining traits linked to reformist, progressive or radical food regime/food movement trends that they may possess. Rather than establishing a dichotomy between niche and food regime or categorizing Organic 3.0 initiatives within one of these trends, we explore the nuances in niche–regime relationships within the food system from a multi-level perspective, using the cases of two Organic 3.0 initiatives in Sweden. The results show that relations between these initiatives and the food regime share key characteristics, but also differ in important respects. While a reformist strategy facilitates niche growth, progressive and radical approaches are more likely to challenge the regime. The choice of approach in both cases involves trade-offs between growth and organic values. We conclude that one of the primary roles of Organic 3.0 initiatives may be to illustrate the viability of alternative models.     

Removal of natural organic dyes from wool–implications for ancient textile provenance studies

Ancient wool textiles recovered from archaeological sites are in many cases originally dyed with natural organic dyestuffs from vegetable sources. These include among others woad (Isatis tinctoria L.), weld (Reseda luteola L.), and madder (Rubia tinctorum L.). These dyestuffs could be a threat to the use of the strontium isotopic system as a tracer for provenance studies of ancient wool, because they could potentially contaminate the signature of the textile's raw material. We present a novel method which allows for efficient removal of organic dyestuffs in wool prior to strontium isotopic analysis. Our method is based on an oxidative release of the dyestuff constituents by ammonium peroxodisulfate [(NH₄)₂S₂O₈] solution, combined with hydrofluoric acid (HF) that has shown to effectively remove/dissolve adhering dust micro-particles. Our multi-analytical results show that such a pretreatment is capable of removing >98% of the originally present organic dyestuffs without significantly destroying the wool structure. The strontium isotopic ratios of the residual wool fraction after the application of the pretreatment are sensitive to the origin and, therefore, can be used as tracers for the provenance of the raw material. We propose to apply this method to ancient wool textiles in which positive identification of organic dyestuff constituents by High Performance Liquid Chromatography (HPLC) was made.     

Advanced design of Chinese traditional materials for the conservation of historic stone buildings

The conservation of historic stone buildings and sculptures is recently receiving growing attention and becoming a focus of research because of rapid changes in weather conditions (pollution, acid rain, etc.). Presently, techniques for stone conservation primarily involve the use of organic coating treatments, but their side effects have been recognized. In contrast, some traditional materials used in historic stone buildings function well for thousands of years. In this paper, we report our research on the reasons why traditional protective materials can provide an unexpected long-term protection. First, calcium carbonate was prepared according to a formula for making Chinese traditional consolidating materials, and its structure and morphology were examined by different instruments. Second, the reinforcing effectiveness of the prepared CaCO₃ powders was tested and analyzed by investigating its surface characteristics. The experimental results reveal that a biocontrolled process occurs, in which an organic template can induce the precipitation of a mineral structure, which in turn results in a great improvement in the conservation of the historic stone buildings protected by these traditional protective materials. This provides a contribution toward the development of new researches on biocontrolled processes and on some protective materials with excellent performance through biocontrolled synthesis.