Strontium isotope analysis in ancient glass from South Asia using portable laser ablation sampling

In order to carry out strontium (Sr) isotope analysis, glass artefacts from South Asia were sampled with portable laser ablation (pLA), a relatively novel sampling technique that leaves damage invisible to the naked eye. Subsequently, thermal ionization mass spectrometry (TIMS) was used to obtain Sr isotope ratios after sample dissolution and separation. In this study, the goal was twofold: to determine whether the measurements of Sr isotope ratios were impacted by using a portable laser as a sample tool; and to assess the pertinence of using Sr isotope ratios to provenance Indian glass. Despite a deterioration in the precision of the measurement of the Sr isotope ratios for artefacts sampled with pLA compared with the traditional sampling method, the Sr isotope ratios of certain Indian glass are so different that this does not affect their separation but a comparison of data sets obtained using standard methods and pLA might be challenging.     

Study on the strontium isotope standard in pig teeth excavated from Zaoshugounao site,Shaanxi Province of China

In archaeology, strontium isotope analysis is developing into an efficient scientific technique for tracing the movement of prehistoric humans and animals. Determining the local bioavailable ⁸⁷Sr/⁸⁶Sr ratio range is the key to distinguishing whether the human or animal is indigenous to the local area. It has been shown that the ⁸⁷Sr/⁸⁶Sr ratio in the enamel of pigs can be an excellent sample to determine the range of local strontium isotope ratio at the site. However, pigs may not be all local at the site, and there is no special study on whether pigs’ different ages and tooth types impact the local strontium isotope characteristics. In this paper, the tooth enamel of 19 pigs from the Zaoshugounao site for strontium isotope ratio (⁸⁷Sr/⁸⁶Sr) by multicollector–inductively coupled plasma mass spectrometry. There were no significant differences in ⁸⁷Sr/⁸⁶Sr ratios of local pigs at different months and different molar types, which did not affect the determination of the local strontium isotope standard. Based on the local strontium isotope ratio range (0.711056–0.711476), we found that five pigs were non-local. The Jing and Wei river basins (in Guanzhong basin) and northern Shaanxi are likely sources of non-pigs.     

Investigating Human Migration and Horse‐Trading in Yelang (夜郎) Through Strontium Isotope Analysis of Skeletons from Zhougshui Sites,South‐West China (1300 bc – ad 25)

Yelang (夜郎), a mysterious state located in the south‐western area of early China and dating from the Bronze Age to the Early Iron Age (1300 bc – ad 25), is a cultural interactive junction between the Yunnan–Guizhou Plateau and the Yangtze River Basin. The Zhongshui Basin in Weining County, Guizhou Province, was one of the important distribution areas of the Yelang civilization. This area, which includes sites at Jigongshan (鸡公山; 1300 – 800 bc ), Hongyingpan (红营盘; 700 – 400 bc ) and Yinzitan (银子坛; 400 bc – ad 25), has provided a very integrated chronology, spanning from the Bronze Age to the Early Iron Age in the eastern Yunnan – western Guizhou area. To investigate human migration and horse‐trading at these Yelang sites, we conducted a strontium isotopic analysis on the teeth enamel of humans and horses unearthed from these three sites. The results indicated the following: (1) people at the earlier sites (Jigongshan and Hongyingpan) were all indigenous, whereas in the Yinzitan cemetery, there was a more immigrant population, and all the people who were buried in an upper limb flexed supine position were non‐local; and (2) most of the horses found at the Jigongshan and Yinzitan sites show different provenances, probably related to the famous Dian (滇) and Zuo (筰) horses recorded in historical documents, providing more clues for further study on horse‐trading in South‐West China during the Bronze Age and the Early Iron Age.     

New light on early caprine herding strategies from isotope analysis: a case study from Neolithic Anatolia

The measurement of stable carbon (δ¹³C) and nitrogen (δ¹⁵N) isotopes of caprine bone collagen from the Neolithic sites of Çatalhöyük and Aşıklı Höyük in south-central Anatolia have allowed examination of exploitation and herding practices of sheep and goats. The isotope values from protodomestic caprines at Aşıklı Höyük suggests that these animals were consuming very similar foods to each other and were all confined to the same or similar environments with no access to C₄ plants. At Çatalhöyük, the results show how the caprine management strategy develops from the strategy seen at Aşıklı Höyük into a more varied practice at an early stage as the site grows with an increasing dietary contribution obtained from C₄ plants. No change in diet is isotopically discernible at Aşıklı Höyük. Interestingly, no distinction could be made between the diets of sheep and goats at either site. Therefore, such studies are a useful method of examining the development of early herding or management strategies of caprines in the Near East.     

Nitrogen isotopes and the trophic level of humans in archaeology

Human and domesticate animal bone collagen δ¹⁵N values in prehistory differ generally by 3‰ or more from Neolithic to post- Roman times in Northwest Europe, leading to an assumed dietary animal protein fraction of 60–80% using a standard interpretation of δ¹⁵N values. We examine the assumptions on which this model rests and the limitations of our knowledge in the analysis of δ¹⁵N values in archaeology. We have developed a set of models which, with small changes made in assumptions (on the order of 1‰), can produce substantially lower estimates of the dietary animal protein fraction for given δ¹⁵N values. We consider the implications of various dietary animal protein fractions on agricultural carrying capacities and human population densities in prehistory.     

The Movement and Exchange of Dogs in the Prehistoric Caribbean: An Isotopic Investigation

This study explores the feasibility of using strontium isotope (⁸⁷Sr/⁸⁶Sr) analyses of enamel from domestic dogs (Canis familiaris) to investigate networks of exchange in the prehistoric Circum‐Caribbean. Dog teeth were obtained from burial and domestic contexts from two prehistoric sites (Anse à la Gourde and Morel) on Grande‐Terre, Guadeloupe (Lesser Antilles). Strontium isotope results were compared with local biosphere ⁸⁷Sr/⁸⁶Sr data at the scale of the site, island and archipelago. The isotope results indicate both local and nonlocal origins with three dogs (30%) identified as nonlocal (one from Anse à la Gourde and two from Morel). The variance in ⁸⁷Sr/⁸⁶Sr ratios of the nonlocal dog teeth is consistent with diverse multiple origins external to the island of Grande‐Terre but consistent with origins from other islands of the Lesser Antilles. The diverse origins of the nonlocal dog samples indicate that the prehistoric circulation of dogs occurred at multiple scales from regional to long distance. Significantly, the ⁸⁷Sr/⁸⁶Sr ratios of some of the dog teeth are comparable with values of nonlocal humans at Anse à la Gourde determined in previous studies. It is possible that these comparable ⁸⁷Sr/⁸⁶Sr ratios result from similar natal origins, for example if individuals were migrating to Guadeloupe with dogs. The results of this study contribute to an ongoing regional investigation of the economic, social and political roles of animals and animal remains and the multiscalar networks of prehistoric mobility and exchange in the Circum‐Caribbean region. Copyright © 2013 John Wiley & Sons, Ltd.     

Stable Isotopic Evidence of Ancient Maya Diet at Caledonia,Cayo District,Belize

The skeletal remains of 18 individuals interred at the ancient Maya site of Caledonia (100 to 1000 C.E.), located in the Cayo District of Belize, w ere sampled for stable carbon and nitrogen isotope analysis in order to reconstruct their diet. Stable carbon and nitrogen isotope ratios in 18 bone collagen samples and stable carbon isotope ratios in bioapatite from 15 bone and 6 tooth enamel samples were assessed. Small sample sizes precluded the assessment of dietary variation with respect to age, sex, social status or time period among the Caledonia Maya. However, the sampled individuals consumed a varied diet consisting of maize, supplemented with some C₃ plants, terrestrial herbivores and/or lower order freshwater resources such as snails and molluscs and possibly maize‐fed animals. This dietary variability with an emphasis on maize is unsurprising given the biological diversity surrounding the site and the known importance of this crop to the ancient Maya. As expected, the isotopic values from Caledonia are similar to those from nearby sites from similar time periods. However, four individuals exhibit a marine dietary signature, possibly indicating inland trade of marine resources from coastal sites, or the migration of coastal people to Caledonia. This study demonstrates the validity of sampling small, fragmented collections from minor Maya centres in order to gain valuable insight into ancient Maya dietary practices. Copyright © 2013 John Wiley & Sons, Ltd.     

显色液组成对二氧化氮检测结果的比较分析

用吸收采样法分析检测空气中二氧化氮时,亚硝酸根离子的显色反应直接关系到检测结果的灵敏度和检测下限。显色液的主要成分为重氮化试剂和偶合试剂。为了提高检测灵敏度和寻找优化的显色体系,本工作比较了对氨基苯磺酰胺和N-1-萘乙二胺盐酸盐组成的显色液在不同浓度比和不同酸性介质中(磷酸pH=1.5和1:1盐酸pH<0.5)对NO_2~-的显色情况。实验结果表明,当显色剂浓度适量,用磷酸为酸性介质(pH=1.5)时,短时间显色更快速灵敏。合适的显色液组成为:对氨基苯磺酰胺4g/L,N-1-萘乙二胺盐酸盐0.06g/L,磷酸28ml/L。本工作还比较了Salzman显色剂对同一标准系列亚硝酸根的测定结果,经线性回归分析得出:Salzman显色剂具有显色稳定等优点,但用于二氧化氮固体吸收剂的分析时,显色灵敏度偏低。     

Isotopic Evidence for Marine Consumption and Mobility in the Atacama Desert (Quillagua,Northern Chile)

Archaeological research in the Atacama Desert has recovered evidence of considerable cultural variability. This variability seems to have increased during the Late Intermediate Period (AD 950–1400). The oasis of Quillagua, located at the margins of the Loa River in northern Chile, between the Andes and the coast (70 km from the Pacific Ocean), has shown important evidence regarding this cultural diversity. The variety in the archaeological evidence found at Quillagua has been interpreted as the result of two different cultural influences at the oasis: the Pica‐Tarapacá who occupied the coastal and inland regions to the north of Quillagua and the Atacama who occupied the oasis and fertile areas southeast of Quillagua. Here, we present the results of stable carbon, nitrogen and oxygen isotope analyses of 23 individuals recovered from the Cementerio Oriente in Quillagua, in order to test whether the observed cultural variability is also reflected in diet and mobility patterns. Results from carbon and nitrogen isotope measurements indicate the importance of marine protein, as well as a contribution of maize in the diet of some individuals. Four individuals show low δ¹⁸O values, suggesting a possible highland or non‐local origin, whereas values for the remaining individuals are consistent with lowland populations. Together, the results support the idea that the Quillagua oasis represented an important site of interaction between the Tarapacá and Atacama cultures, with close contacts with the coast but also with the presence of individuals from the highlands. Copyright © 2015 John Wiley & Sons, Ltd.