AN ARCHAEOMETRIC STUDY OF MEDIEVAL GLASS FROM THE FIRST BULGARIAN CAPITAL,PLISKA (NINTH TO TENTH CENTURY AD)

Glass finds from the first Bulgarian capital, Pliska, have been analysed by instrumental neutron activation analysis. The analytical data, together with previous results from analysis of glass samples from the second Bulgarian capital, Preslav, were subjected to cluster and discriminant analysis. The local origin of part of the analysed samples was proven and some conclusions about the technology of production were possible.     

COMPOSITIONAL CHARACTERIZATION OF FRENCH LIMESTONE: A NEW TOOL FOR ART HISTORIANS*

Limestone from quarries known to medieval craftsmen and from the monuments they built and embellished, as well as from carvings now in museum collections, has been characterized by neutron activation analysis. Specimens from 38 quarries in the Lutetian and Jurassic limestone formations of France and from sculptures in American and French museums have been tested, and the results have been compiled in a data base to which art historians may refer when attempting to determine provenance for sculptures. Multivariate statistical analysis of concentration data shows stone from a particular quarry in the Paris basin to be compositionally homogeneous and distinguishable from other quarries in the same formation. The same approach to data related to quarries near the Burgundian abbey of Cluny finds general agreement between classifications based on compositional and on petrographic data, but the number of samples available for analysis at the time of writing was insufficient to achieve the finer distinctions reported for the Paris basin.     

A CHARACTERIZATION OF THE COMPOSITIONAL VARIATIONS OF ROMAN SAMIAN POTTERY MANUFACTURED AT THE LEZOUX PRODUCTION CENTRE

The study addresses the chemical variations for Roman Samian wares manufactured during various periods at different workshops within the Lezoux production centre. Instrumental neutron activation analysis and inductively coupled plasma spectrometry were used to determine the chemical constituents of the pottery. The two techniques were evaluated based on the capacity of each to identify the same compositional groups for Lezoux Samian with the use of multivariate statistics. The compositional analysis redefines and clarifies how potters used the clay sources at the site to produce fine wares. The results indicate that the majority of potters from different workshops at Lezoux shared the same clay source during the second century AD.     

NEUTRON ACTIVATION ANALYSIS OF AD 1660–1930 EUROPEAN COPPER-COLOURED BLUE GLASS TRADE BEADS FROM ONTARIO,CANADA

Blue glass trade beads from well-dated late seventeenth- to early twentieth-century sites and collections have been analysed non-destructively by instrumental neutron activation analysis. The beads display enough variations in their elemental contents to allow us to characterize the different chemistries. The implication of these results is that similar chemical analyses of blue beads from undated archaeological sites may be used to help date the sites, since each bead chemistry has a specific earliest period.     

CHEMICAL ANALYSIS OF COPPER ALLOY TRADE METAL FROM A POST-CONTACT HURON SITE IN ONTARIO,CANADA

Fifty-three copper-based metal fragments, recovered from the Robitaille site in southcentral Ontario, were analysed by neutron activation to establish their chemical make-up and to sort them by their trace elemental chemistries. Three different European copper samples, one brassy copper and 48 brass samples with five different chemistries were found. As few as eight trading actions may account for all of the recovered European metal fragments.     

ARCHAEOMETRY AT SLOWPOKE‐TORONTO

This paper describes the archaeometric research conducted at the SLOWPOKE Reactor Facility of the University of Toronto (SLOWPOKE‐Toronto) during its existence from 1971 to 1998. The contributions to student teaching and research are described, and the total contribution of the facility to studies of an eclectic assortment of ancient and historic materials is addressed.     

ANALCIME CRYSTALLIZATION AND COMPOSITIONAL PROFILES—COMPARING APPROACHES TO DETECT POST‐DEPOSITIONAL ALTERATIONS IN ARCHAEOLOGICAL POTTERY*

The approaches of comparative studies and profile measurements, often used in order to detect post‐depositional alterations of ceramics, have been applied simultaneously to two sets of Roman pottery, both of which include altered individuals. As analytical techniques, Neutron Activation Analysis and X‐Ray Diffraction have been used. Both approaches lead to substantially different results. This shows that they detect different levels of alteration and should complement each other rather than being used exclusively. For the special process of a glassy phase decomposition followed by a crystallization of the Na‐zeolite analcime, the results suggest that it changes high‐fired calcareous pottery rapidly, and so fundamentally that the results of various archaeometric techniques can be severely disturbed.     

UNOFFICIAL COINAGE IN THE THIRD CENTURY ad IN THE GALLO‐ROMAN WORLD: CHEMICAL AND PHYSICAL ANALYSES FOR DETERMINING THE LOCALIZATION OF THE WORKSHOP*

The third century ad was a complex period of crisis in the Roman world. In this paper, official and unofficial antoniniani, and double sestercii and sestercii, were analysed by fast neutron activation analysis (FNAA) to determine the alloys used by the craftsmen for producing forgeries. Moreover, at Châteaubleau, archaeologists discovered antoniniani and bronze forgeries from Postumus. Similar materials have been found in other hoards. They are believed to have been produced by a workshop called ‘atelier II’ by numismatists. The question was whether it is possible to differentiate the Châteaubleau production from the atelier II production.     

The Material Characterization of a Santamarian Ceremonial Axe

The characterization of a ceremonial bronze axe is described. The axe is assigned to the Santamarian culture of north‐west Argentina, c. 1000–1470 ad, and was selected to increase presently limited knowledge of prehistoric metallurgy in the Andean region of Argentina. The characterization methods used were electron probe microanalysis, gamma radiography, X‐ray diffraction, optical metallography and microhardness testing. The axe was well cast in a bivalve mould, with the only defects in the area of an ancient fracture. The analysis showed that it is made from a tin bronze with a, probably, accidental addition of lead. Arsenic was found as a surface contamination, probably deriving from arsenic in the water of the stream in which the axe was found. The axe shows that Santamarian craftsmen had the skill to decorate the axe in an artistic style with a strong local accent while providing a functional, annealed and cold‐worked cutting edge.     

ANALYTICAL INVESTIGATION OF ARCHAEOLOGICAL POWDERS FROM GÖLTEPE (TURKEY)*

Nine powder samples originating from the archaeometallurgical she in Göltepe, southern central Turkey, have been analysed. Bulk analyses, using X-ray fluorescence and X-ruy photoelectron spectroscopy, and single particle analyses, using electron probe X-ray microanalysis, were carried out. The analyses were focused on determining the inorganic elemental composition of the samples and the distribution of particle types in the nine powder samples. In addition, the powder samples were classified on the basis of their elemental composition using multivariate techniques. The objective of this study was to characterize the powder samples and to establish an association with archaeological data from the site