Chemical and Microscopic Study of Masonry Mortar in Ancient Pagodas in East China

Ancient mortars played a crucial role in the construction of historical architectures due to their physical and chemical compatibility with traditional building materials such as stones and bricks. Therefore, the analysis and optimization of the ancient mortar formula are significant in the restoration and preservation of historical sites. In this work, 20 mortar samples selected from five ancient stone pagodas in Zhejiang Province, China, were analyzed. The results showed that mud, lime-soil mortar, lime-sand mortar, and lime-gypsum mortar were used as binders in these pagodas. The Ca(OH)₂/aggregate ratio ranging from 0.3 to 2.7 was usually used to prepare lime mortar. Protein and polysaccharide were also found in some samples.     

Potential Use of Foamed Mortar (FM) for Thermal Upgrading of Chinese Traditional Hui-Style Residences

The Hui-style residence is an important architectural heritage of China. The hollow wall structures are widely used to build its exterior wall system. However, the thermal performance of the hollow wall is no longer able to meet the new energy-saving and environmental requirement. This article describes a laboratory study of the development of foamed mortar (FM), with the potential for use in thermal upgrading of the Hui-style hollow wall system without dramatically changing its traditional structure. The key early age, physical, mechanical and thermal properties were systematically measured. Two extended models were respectively developed to calculate compressive strength and thermal conductivity, as a function of porosity. Environment chamber test was also employed to investigate the effectiveness of this novel thermal upgrading approach and the results show that filling the voids with FM can effectively improve the overall thermal resistance of the hollow wall system by 44%, which is almost equal to the overall thermal resistance when using the more expensive commercial inorganic stucco system. In addition, the combination of these two methods yielded an overall thermal resistance of 0.701 m²·K/W, which is even higher than 0.67 m²·K/W for the code required in the hot summer/cold winter climate zone.     

Qadhat—a comparative study of ancient and new lime mortar from the Marib province/Yemen

Qadhat is the name for a lime mortar in Southern Arabia. Its usage has a long tradition. This work describes physical and mineralogical properties of ancient, historical and new samples, which seem to have been produced the same way. XRD, thin sections and SEM analyses show the similarity of the material. It consists of aggregates of volcanic material that are rich in volcanic glass and lime as binder. The production process includes several hours of crushing the material, which produces fine-grained splinters of aggregates in the binder matrix and gives the mortar a high stability. A weathering test with sodium sulphate on different samples confirms that the stability of this mortar is the result of the production process.     

Characterization of lime mortar additivated with crystallization modifiers

Additivating mortars with crystallization modifiers is a novel approach to mitigate salt crystallization damage in historic masonry. Once verified the effectiveness of crystallization modifiers in bulk solution, the next step consists in verifying whether: (i) modifiers are still effective when mixed in mortar and going through the carbonation process and (ii) modifiers alter any mortar properties which might limit their application. This research addresses these issues for sodium ferrocyanide and borax, modifiers for sodium chloride, and sodium sulfate, respectively. Several experimental techniques have been applied to elucidate these questions. The results show that the selected modifiers are still able to alter the salt crystallization after going through the carbonation process of the mortar. Besides, no major effects of the modifiers on the fresh and hardened mortar properties were observed. It can therefore be concluded that there are no restraints for the future use of these crystallization modifiers in restoration mortars.     

Kinetic effect of carbonic anhydrase enzyme on the carbonation reaction of lime mortar

The effect of carbonic anhydrase enzyme on the precipitation kinetics and phase transformations of calcium carbonate, and on the strength development of lime mortars has been investigated with saturated lime solutions, lime pastes and lime mortars under atmospheric conditions. The results clearly show that carbonic anhydrase catalyzes the reaction between carbon dioxide and aqueous lime, and increases the rate of calcium carbonate crystallization, the yield of the carbonation reaction and mortar strength at early ages. This is most likely a kinetic effect associated with the increased rate of carbonate ions supply to the solution by the enzyme. In addition, this enzyme favors the formation of stable calcite and significantly modifies its morphology by developing new crystal faces. These results suggest a novel approach for accelerating the hardening of lime mortars using carbonic anhydrase enzyme, which may offer a potentially novel approach with significant benefits on the applications of lime mortars in architectural heritage conservation as well as in construction.     

Assessment of Construction Techniques and Material Usage in İzmir Rural Houses

The domestic architecture in the rural villages of ?zmir comprises a unique built environment with their masonry wall textures, semi-open sofas, round tiled-hipped roofs, and chimneys, and represents an important part of the cultural and architectural heritage. This assessment is mainly based on field observations that focus on the architectural and structural layout of intact, damaged, and destroyed houses. During field observation and the analysis of data certain plan typologies and relationships between the geological formations of the region and choice of materials and construction techniques were observed. While load-bearing masonry and timber skeleton systems are common, extensive use of timber laces, stone, and fired or adobe brick masonry with mud mortar and timber frames infilled with masonry materials were frequently seen. Generally, round timber elements such as wall plates, laces, lintels, posts, and frames of flooring systems are used. Architectural degenerations in authentic houses, defective details and partially due to the earthquake-prone nature of the region seismicity have been evaluated. An overall approach for the preservation and sustainability of this heritage is suggested.     

Characterization of archaeological lime mortars in a Ming dynasty tomb: A multi-analytical approach

Lime mortars have played an important role in constructing ancient Chinese masonry structures, including city walls, buildings, and tombs. A tomb built with lime mortars and stones belonging a Ming high-ranking official, Xu Jie, was discovered in Huzhou City of China. Eight different samples from Xu Jie’s tomb, representing four types of lime-mortar-based materials: joint mortar between stone bricks, bedding mortar, grouting mortar, and plaster mortars were collected for analysis and comparison. The characterization of the construction materials has therefore become of primary importance. The function of each mortar was reported and studies into the micro-textural features and mineralogical compositions of those mortars were performed via a multi-analytical approach. The joint mortars were all found to be aerial lime mortars with predominately lime. The bedding mortar was found to consist of lime, soil and sand, typical of a tabia mortar. The grouting mortar was found to consist of lime and ground contact metamorphosed limestone. Analysis of plaster sample taken from the roof of the main tomb identified the presence of calcium stearate/palmitate, indicating the usage of plant-based tung oil as an additive. The analytical results will promote our understanding of Ming architectural technology and craftsmanship, and provide critical information for the conservation of Xu Jie’s tomb.     

以糯米灰浆为代表的中国传统有机-无机复合灰浆研究进展和新发现

在中国数千年的建筑实践中,已发现许多具有中国特色的创造,其中以糯米灰浆为代表的中国传统有机-无机复合灰浆就是其中的一类。本文综述了自2007年以来相关研究的进展,包括：针对传统灰浆中有机残留物的化学检测和免疫分析技术的创新发展;全国252处古建筑遗址的1149个灰浆样品的检测结果及解读;糯米灰浆和桐油灰浆等传统胶凝材料固化作用机理及效果的实验验证;糯米灰浆研究成果对世界的影响及在世界复合材料历史上的地位;最近在新石器时代“白灰面”中新发现的有机添加物及相关溯源;传统糯米灰浆的改良研究及在文物保护工程中的应用情况等。这一系列的探索性研究不仅可为古建筑保护提供材料和技术,也为弘扬中华文明提供了鲜活的案例。     

Materials Characteristics of Roman and Arabic Mortars and Stuccoes from the Patio De Banderas in the Real Alcazar of Seville (Spain)

This study discusses the materials and traditional knowledge used in the manufacture and application of lime mortars and stuccoes by Romans and Arabs in Seville (southern Iberian Peninsula). All of the samples studied contain calcite as a binder, combined with aggregates based on river sand from the filling materials of the Guadalquivir River's depression, located in the vicinity of the Real Alcazar Palace in Seville, Spain, where the artefacts were discovered. The Romans used high‐quality production technology, as evidenced by the careful selection of raw materials as well as by the adequate binder‐to‐aggregate ratio and the elevated homogeneity of the mortars and stuccoes. The suitable distribution of aggregates resulted in higher density values for Roman fragments than for Arabic ones. Results derived from Arabic samples suggest a decline in technology manufacture over time. This work provides useful information, particularly regarding the Roman and Arabic periods in the Iberian Peninsula. The analytical techniques employed in this study were X‐ray diffraction (XRD), X‐ray fluorescence (XRF)—using conventional and portable systems, scanning electron microscopy (SEM), petrographic microscopy, differential thermal analysis/thermogravimetry (DTA/TG), particle‐size analysis and mercury intrusion porosimetry.