Bone diagenesis in the European Holocene II: taphonomic and environmental considerations

We have applied cluster analysis to mercury intrusion porosimetry data from 219 archaeological bones (121 human and 98 animal) and soil chemistry data from 219 accompanying soil samples (1 per bone sample), to investigate the influence of soil chemistry on bone preservation. The samples chosen for the study were obtained from sites ranging in time from the pre-modern to the Mesolithic and were representative of burial environments across Europe (from the Baltic to the Mediterranean). These results represent the single largest database for archaeological bone preservation in the European Holocene to date and demonstrate the potential for large-scale diagenetic studies to help develop long term preservation strategies for our European heritage. Despite the variety of sites and environments, bones could be categorised into only four main diagenetic types. Furthermore, soil chemistry appears to significantly affect only one type of preservation, the pathway characterised by loss of mineral. In neutral to basic soils, taphonomy and in particular the differences between the treatment of human and animal remains, becomes the dominating factor in determining preservation. Using these results, strategies for heritage management of archaeological sites can be suggested; grouping sites into those requiring immediate excavation and those where in situ preservation is viable.     

Retrograde P–T evolution and high temperature–low pressure fluid circulation in relation to late Hercynian intrusions: a mineralogical and fluid inclusion study of the Charroux-Civray plutonic complex (north-western Massif Central, France)

The calc‐alkaline plutonic complex from Charroux‐Civray (north‐western part of the French Massif Central) displays multiphase hydrothermal alteration. Plutonic rocks, as well as early retrograde Ca–Al silicate assemblages, which have crystallized during cooling and uplifting of the plutonic series, are affected by multiphase chlorite–phengite–illite–carbonate alteration linked to intense pervasive fluid circulation through microfractures. The petrographic study of alteration sequences and their associated fluid inclusions in microfissures of the plutonic rocks, as well as in mineral fillings of the veins, yields a reconstruction of the P–T–X evolution of the Hercynian basement after the crystallization of the main calc‐alkaline plutonic bodies. This reconstruction covers the uplift of the basement to its exposure and the subsequent burial by Mesozoic sediments. Cooling of the calc‐alkaline plutonic series started at solidus temperatures (～650°C), at a pressure of about 4 kbar (1 bar = 10⁵ N m^?2), as indicated by magmatic epidote stability, hornblende barometry and fluid inclusion data. Cooling continued under slightly decreasing pressure during uplift down to 2–3 kbar at 200–280°C (prehnite–pumpellyite paragenesis). Then, a hot geothermal circulation of CO₂‐bearing fluids was induced within the calc‐alkaline rocks leading to the formation of greisen‐like mineralizations. During this stage, temperatures around 400–450°C were still high for the inferred depths (～2 kbar). They imply abnormal heat flows and thermal gradients of 60–80°C km^?1. The hypothesis of the existence of one large or a succession of smaller peraluminous plutons at depth, supported by geophysical data, suggests that localized heat flows were linked to concealed leucogranite intrusions. As uplift continued, greisen mineralization was subsequently affected by the chlorite–phengite–dolomite assemblage, correlated with aqueous and nitrogen‐bearing fluid circulations in the temperature range of 400–450°C. In a later stage, a continuous temperature decrease at constant pressure (～0.5 kbar) led to the alteration of the dolomite–illite–chlorite type in the 130–250°C temperature range.     

气候对中国古代塔砖材料性能劣化影响的研究

在气候影响下,塔砖材料性能的劣化加剧了中国古塔结构的损伤,减少了古塔的结构寿命。为此,课题选择两个极具代表性的中国古代砖塔—1500年历史的嵩岳寺塔和1200年历史的法王寺塔进行同一性研究,欲证明两塔在地理位置、环境气候、形制、塔体古砖制造原料和制造工艺等方面均具有很强的相似性和同一性。采用X射线荧光光谱法分析了两塔塔砖的材料成分,采用压汞法对两塔塔砖材料的孔隙率、孔隙结构和孔隙分布特征进行了实验。两塔塔砖材料实验结果的差异证明:在公元5世纪到公元8世纪的300年气候影响下(该气候为自然营力而非实验室人工模拟),塔砖材料孔隙率的增大是导致中国古代塔砖性能劣化的主要原因,大约30%左右的孔隙从小于1000nm孔径发展扩大到10000～50000nm孔径是塔砖材料孔隙率增大的主要表现形式。因此,预防小孔径孔隙(小于1000nm)在气候影响下发展扩大的防治措施应该成为中国古代砖塔保护工作的研究重点。同时,对因塔砖材料性能劣化而产生的古塔塔体的表观特征进行了分析,分析结果有利于中国古代砖塔的保护。     

Fluidized sandstone intrusions as an indicator of Paleostress orientation, Santa Cruz, California

The late Miocene sandstone intrusions of northern Santa Cruz County, California, are the largest subaerial exposures of clastic intrusions on earth. The intrusions are sourced from a sandstone, underlying mudstone, accumulated in an outer shelf to upper slope environment. Dikes are the most frequent intrusion type, reach the greatest thickness and tend to strike north‐east and dip steeply. One giant dike is more than 150 m wide. Sills are least frequent, locally > 8 m thick and have no clear preferred geographical distribution. Clustered intrusions are commonly < 10 cm thick and mostly composed of dikes of various attitudes. The majority of the intrusions probably were injected shallowly as some extrude onto the seafloor. The local seafloor extrusion also indicates injection during the deposition of the Santa Cruz Mudstone (7–9 Ma). The intrusions are concentrated at the basin margin. Fluid pressure at the centre of the basin and perhaps hydrocarbons were communicated to the basin margin through the then sand, causing fluid overpressures that contributed to the fluidization and intrusion into the overlying mudstone. Primarily north‐east‐striking, steeply dipping dikes and secondarily, shallowly dipping sills are most significant in terms of regional connectivity of intrusions and physical dilation of the formation. The orientation of the dikes and sills indicates a regional stress field with a horizontal NE–SW maximum and a NW–SE minimum compressive direction. The simultaneous development of dikes and sills suggests similar magnitudes of the minimum and intermediate principal stresses. Preferential weakness along bedding contributed to the development of sills. Palaeomagnetic data indicate no significant block rotation around a vertical axis. The maximum principal stress direction indicated by the intrusions is about 55° to the San Gregorio Fault and about 70° to the San Andreas Fault during the late Miocene. This stress field is similar to the modern stress field and suggests moderate fault weakness.     

Sub‐micron spongiform porosity is the major ultra‐structural alteration occurring in archaeological bone

Total pore volume and pore size distribution are indicators of the degree of post‐mortem modification of bone. Direct measurements of pore size distribution in archaeological bones using mercury intrusion porosimetry (HgIP) and back scattered scanning electron microscopy (BSE‐SEM) reveal a common pattern in the changes seen in degraded bone as compared to modern samples. The estimates of pore size distribution from HgIP and direct measurement from the BSE‐SEM images show remarkable correspondence. The coupling of these two independent approaches has allowed the diagenetic porosity changes in human archaeological bone in the >0.01 µm range to be directly imaged, and their relationship to pre‐existing physiological pores to be explored. The increase in porosity in the archaeological bones is restricted to two discrete pore ranges. The smaller of these two ranges (0.007–0.1 µm) lies in the range of the collagen fibril (0.1 µm diameter) and is presumably formed by the loss of collagen, whereas the larger pore size distribution is evidence of direct microbial alteration of the bone. HgIP has great potential for the characterization of microbial and chemical alteration of bone. Copyright © 2002 John Wiley & Sons, Ltd.     

Influence of porosity on lipid preservation in the wall of archaeological pottery

Porosity of archaeological pottery is a key parameter used to assess its ability to trap lipids during the use of the pot and to preserve them over time. Mercury intrusion porosimetry and gas chromatography were used to study the distribution of porosity and the preservation of lipids in different chrono‐cultural contexts. The data obtained show that the porosity pattern, related to the raw materials and the savoir‐faire of the potters, influences the amount of lipids accumulated in the pottery. A significant overall porosity together with a high level of small pores is generally favourable for the preservation of lipids, but variations related to the environmental context are observed.     

The connectivity of pore space in mudstones: insights from high‐pressure Wood's metal injection,BIB‐SEM imaging,and mercury intrusion porosimetry

Study of the pore space in mudstones by mercury intrusion porosimetry is a common but indirect technique and it is not clear which part of the pore space is actually filled with mercury. We studied samples from the Opalinus Clay, Boom Clay, Haynesville Shale, and Bossier Shale Formations using Wood's metal injection at 316 MPa, followed by novel ion beam polishing and high‐resolution scanning electron microscopy. This method allowed us to analyze at high resolution which parts of a rock are intruded by the liquid alloy at mm to cm scale. Results from the Opalinus Clay and Haynesville Shale show Wood's Metal in cracks, but the majority of the pore space is not filled although mercury intrusion data suggests that this is the case. In the silt‐rich Boom Clay sample, the majority of the pore space was filled Wood's metal, with unfilled islands of smaller pores. Bossier Shale shows heterogeneous impregnation with local filling of pores as small as 10 nm. We infer that mercury intrusion data from these samples is partly due to crack filling and compression of the sample. This compaction is caused by effective stress developed by mercury pressure and capillary resistance; it can close small pore throats, prevent injection of the liquid metal, and indicate an apparent porosity. Our results suggest that many published MIP data on mudstones could contain serious artifacts and reliable metal intrusion porosimetry requires a demonstration that the metal has entered the pores, for example by Wood's metal injection, broad ion beam polishing, and scanning electron microscopy.     

Increasing livelihood vulnerabilities to coastal erosion and wastewater intrusion: The political ecology of Thai aquaculture in peri-urban Bangkok

Most livelihood research focuses on micro-level decisions affecting occupations but fails to examine wider scale processes that shape markets, institutions, and thus livelihood choices. A political ecology framework can help address this gap by providing ways to analyse how multi-scalar and extra-local practices, policies, and discourses affect local-level socio-environmental outcomes. In the qualitative research reported here, that framework is applied to Tha Kam, a peri-urban coastal sub-district of Bangkok, where most residents are small-scale aquaculture farmers. These farmers have experienced precipitous drops in incomes because of two major environmental changes: coastal erosion and wastewater intrusion. The causes are multiple and complex, and many originate not from practices within Tha Kham but from challenges present at a larger scale or that start upstream. The political and economic drivers of these problems stem from Thailand’s fragmented vertical and horizontal governance structure, unequal class relations in which smallholder farmers and peri-urban residents are marginalised, and lack of accountability and representation. This combination of multi-scalar factors and power imbalances has contributed to evolving injustices of peri-urbanisation, all of which are profoundly geographical in their significance.