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The graphical and linguistic interpretation of the first six Etruscan numerals has long been confronted with the ambiguous assignment of the words huth and sa to either 4 or 6. Here, we show how the systematic combinatorial analysis of the numerals appearing on ancient southern Etrurian dice dated from the eighth to the third centuries bc , together with the careful comparison of the results with the only two existing dice carrying the alphabetical translations of the numerals conserved at the Bibliothèque Nationale de France, Paris, finally allows unambiguous mathematical resolution of the linguistic riddle, allowing the firm attribution of the numeral 6 to the graphical value huth and 4 to sa. Combinatorial analysis of the numerals distribution on the six faces of the die shows that only two of the 15 possible numerical combinations were actually in use in southern Etruria, and that during the fifth century bc there was a marked shift from the typical (1–2, 3–4, 5–6) combination used in the early seventh‐ to fifth‐century bc dice to the (1–6, 2–5, 3–4) combination used at later times and still largely adopted today. The largest body of archaeometric data on dice specimens from Etruria is presented, based on macroscopic examination, X‐ray diffraction, DRIFT spectroscopy and density measurements.  相似文献   
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European geological ambers of five different localities and types, and Italian geological ambers from seven different deposits have been studied with Fourier transform infrared spectroscopy (FTIR) and diffuse‐reflectance infrared Fourier transform (DRIFT). Ambers from several localities have been characterized for the first time. The research aims to create a database of European ambers, containing both FTIR and DRIFT data. The FTIR spectra are easily comparable with the data commonly available in the literature, whereas DRIFT analyses are shown to be more useful to characterize the archaeological finds. The provenance of several archaeological ambers from northern and southern Italy, dating from the Middle Bronze Age to the Iron Age, is assessed on the basis of the developed database. Of the 35 analysed archaeological objects, all but five are composed of Baltic succinite amber.  相似文献   
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We investigated the utility of diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) for the analysis and identification of sea turtle (Family Cheloniidae) and bovid (Family Bovidae) keratins, commonly used to manufacture historic artefacts. Spectral libraries are helpful in determining the class of the material (i.e., keratin versus plastics), but do not allow for inferences about the species source of keratin. Mathematical post‐processing of the spectra employing discriminant analysis provided a useful statistical tool to differentiate tortoiseshell from bovid horn keratin. All keratin standards used in this study (n = 35 Bovidae; n = 24 Cheloniidae) were correctly classified with the discriminant analysis. A resulting performance index of 95.7% shows that DRIFTS, combined with discriminant analysis, is a powerful quantitative technique for distinguishing sea turtle and bovid keratins commonly encountered in museum collections and the modern wildlife trade.  相似文献   
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