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Mouhsin El Mansouri Abderrahmane El Fouikar Bernard Saint-Martin 《Journal of archaeological science》1996,23(6):803-809
The Upper Palaeolithic site of the Abri Pataud (Dordogne, France) has been the subject of numerous14C age determinations which cover the period from 20,400±450 years
(OXA-373) to 34,250±675 years
(Grn-4507). The racemization ratios of aspartic acid have been determined in 26 fossil bones. The bones are present in two different sedimentary surroundings: levels (fine deposits with numerous artefacts and fossil bones) and “éboulis” (coarse deposits derived from the neighbouring limestone cliff). Racemization ratios for total aspartic acid have a poor correlation with14C ages (respectivelyr2=0·59 and 0·82 for the two environments) but apparent racemization rates are clearly dependent on the type of deposits (levels: K=4·4×10−6year−1; éboulis: K=9×10−6year−1).Racemization ratios of aspartic acid in a high molecular weight protein fraction (>10,000 Da) correlate much better with14C ages (r2=0·999) for the samples from the levels (k=2·1×10−5year−1). From this regression line we estimate ages for two Aurignacian levels: level 6≈29,560 years
and level 9≈30,440 years
.It is noteworthy that none of the regression lines intercepts the origin. Racemization of aspartic acid appears to occur only after a delay of many thousands of years. This phenomenon could be the result of a coupling between the degradation of proteins and the racemization of amino acids. 相似文献
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