How the Olmec used bitumen in ancient Mesoamerica

Bitumen, found in abundance in Mesoamerica’s southern Gulf Coast region in natural seeps and in many archeological contexts, is an important economic resource and exchange item that has received little consideration in Mesoamerica. Analyses of archeological, ethnoarcheological, and experimental data provide insights on the organization of bitumen processing activities, and the end product (archeological bitumen), which the Olmec (1200–400 BC) used in the production of many items. Archeological data are derived from investigations at El Remolino and Paso los Ortices— two Early Formative period levee sites in the San Lorenzo Olmec region. Our findings suggest that among the Olmec, bitumen processing was organized as a specialized activity, involving multiple production stages, but not necessarily elite involvement or control.     

New evidence of adhesive as hafting material on Middle and Upper Palaeolithic artefacts from Gura Cheii-Râşnov Cave (Romania)

Making use of analytical, chemical and mineralogical methods, this paper focuses on the analysis of inclusions in order to address the question of the provenance of prehistoric artefacts excavated in Gura Cheii-Râ?nov Cave (Romania). The study represents the first discovery of bitumen on lithic tools belonging to the Upper and Middle Palaeolithic in Europe. The material was identified through several analytical procedures, such as Fourier transform infrared spectroscopy (FTIR), energy-dispersive X-ray fluorescence (EDXRF), inductively coupled plasma atomic emission spectroscopy (ICP-AES), and X-ray diffraction (XRD).     

The origin of black pigmentation in a sample of Mexican prehispanic human bones

The study of black patches and spots in prehispanic bones of Tlatelolco and Tlapacoya is presented. The chosen characterization techniques, X-ray Fluorescence, X-ray Diffraction, Scanning Electron Microscopy, Energy Dispersive X-ray Spectroscopy, Infrared Spectroscopy and Gas Chromatography are complementary and they all conclude that the bone black pigment is constituted, mainly, by amorphous carbon and some mineral inclusions. Gas Chromatography and Infrared Spectroscopy show that the pigment is constituted by organic compounds as aromatic hydrocarbons, mainly bitumen. An explanation on how the spots were formed is proposed.     

Sourcing archaeological bitumen in the Olmec region

Prehispanic Mesoamerican peoples collected, processed, and used bitumen for decoration, sealant, and adhesive. Among the earliest to do so were the Olmec (1200–500 b.c.) of Mexico's southern Gulf coastal lowlands. Geochemical analysis of bitumen from Olmec archaeological contexts as well as from seeps in the Olmec region reveals that seeps can be geochemically differentiated and can be correlated with archaeological samples. Groups of sites with chemically different archaeological bitumen indicate multiple procurement networks reflecting complex regional systems of exchange and interaction. Organic geochemical analysis of bitumen provides a new tool to study procurement strategies and exchange patterns in Mesoamerica.     

Molecular evidence of bitumen in the Mousterian lithic assemblage of Hummal (Central Syria)

Evidence for bitumen use in Middle Palaeolithic sites is an exception in Pleistocene archaeology. This paper presents the discovery of three tar-bearing Levallois artefacts found in the Mousterian sequence in Hummal (Central Syria). The organic residues were submitted to geochemical study. Gas chromatography–mass spectrometry analyses of saturated and aromatic hydrocarbons and isotopic data show the presence of bitumen. The most likely location of natural asphalt provisioning is the Shaaf outcrop in the Bichri desert. The bitumen-bearing stone tools add further important data to the growing knowledge about bitumen processing in the Middle Palaeolithic spring sites of El Kowm. Identification of the provisioning place for natural asphalt enables a more precise assumption about the site's catchment area. From a technological point of view, the tar-bearing specimens provide information on the range of tool forms selected for hafting. Ballistic features arguably indicate that the pointed Levallois blanks seem to be spear points that were fitted to a wooden handle. In at least one case, this technical procedure was seemingly executed during a brief episode of occupation and replacement of worn out implements. This small, bracketed window of detailed insight into Mousterian technology is linked with the more general relationship between Levallois technology and stone tool hafting.     

Asphaltum hafting and projectile point durability: an experimental comparison of three hafting methods

The design of a projectile delivery system often plays a critical role in the durability and breakage patterns associated with spent projectile points. This paper presents the results of an experimental project designed to examine projectile point durability and breakage patterns between three different hafting methods. Specifically, we compare two asphaltum hafting techniques drawn from archaeological and ethnohistoric accounts from the Central Valley of California with a more stereotypical cross-hatched sinew hafting system. Our results suggest a small yet statistically significant increase in durability among asphaltum hafted points, opening the door to future research on these ethnohistorically documented hafting techniques.     

Bulk stable carbon and deuterium isotope analyses of bitumen artifacts from Hacinebi Tepe, Turkey: reconstructing broad economic patterns of the Uruk expansion

This research addresses issue of inter-regional trade for the world's first colonial trading system, the economic expansion of state societies from southern Mesopotamia into southwest Iran and southeast Anatolia, through the use of stable carbon and deuterium isotope analyses of bitumen artifacts. The key goal of the project was to get beyond simply the identification of trade (Schwartz, M., Hollander, D., Stein, G., 1999. Paléorient 25 (1), 67–82) and examine broad regional patterns in the exchange system. To this end, the methodological approach of this research was focused on the reconstruction of general exchange patterns using a large sample set. The results of these analyses suggest the utility of bulk isotopic analyses in the identification of broad regional patterns, serving as a complement to detailed isotopic and molecular work on asphaltene extractions of bitumen (Connan, J., Nishiaki, Y., 2003. Vol. II: Chalcolithic Technology and Subsistence. The University Museum – The University of Tokyo, Tokyo, pp. 283–306). Some of the data indicate changes in the organization of trade at the site of Hacinebi in southeast Turkey and suggest large economic changes in Anatolia associated with the Uruk expansion.