A Preliminary Study on the Loss of Iron and Arsenic in the Re‐Melting of Iron‐Bearing Arsenical Copper

Re‐melting experiments were conducted with specimens made of high‐arsenic copper alloys containing lead, iron and sulphur. The melting treatment at 1000°C in ambient conditions for 5 min was found to cause an almost complete removal of iron and sulphur along with a notable reduction of arsenic levels. Evidence was found that the preferential oxidation of iron and arsenic was responsible for this change in composition. The treatment also brought about perfect dissolution of speiss particles scattered throughout the original specimen, suggesting the possibility of the addition of speiss to molten copper for the production of arsenical copper.     

New field and geochemical evidence from vitrified forts in South Morar and Moidart,NW Scotland: further insight into melting and the process of vitrification

New field and laboratory work has been carried out on two vitrified forts, Rhubh Aird Ghamhsgail near Arisaig and The Torr near Acharacle. Fieldwork confirms that both are constructed from rubble largely comprising local psammitic Moine Supergroup rocks and that their walls are relatively well preserved with large portions of vitrified material remain, particularly at The Torr, where remnants of up to four courses of stone facing occur. The preserved wall fills comprise mostly psammitic rubble set in a dark brown, vesicular, glassy to aphanitic matrix that in many places preserves evidence of downward flow. Conventionally, vitrification is explained through combustion of timber interlacing within the walls leading to melting that has been modelled in the granite system. However, considering Iron Age smelting technology, this leads to problems in obtaining high temperatures (≥1000 °C) over tens of metres of wall length. Geochemical analysis of the vitrification indicates that modelling the melting within the granite system is incapable of providing a partial melt matching the composition of vitrification. At The Torr, pelite fragments have been found near the base of the wall where partial melt occurs as black bubbles. In these fragments it appears that micas (largely biotite) have formed the melt via the reaction biotite + quartz = sanidine + orthopyroxene + liquid which takes place at temperatures c. 850 °C. Quench crystals in the melt include orthopyroxene, plagioclase, spinels, ilmenite, magnetite, anatase and apatite confirming that it was not a granite melt. These melted fragments are found next to material with biotite that, superficially, appears unmelted, suggesting that some of the heating took place perhaps away from the edifice and unmelted residue was utilised as part of the rubble fill, suggesting that in situ partial melting of the rubble is unlikely. However, in other parts of the edifice heat affected, yet unmelted, fragments are dominant. The new evidence indicates that vitrification occurred at lower temperatures than previously modelled and thus the melts could have been achieved more easily than previously thought.     

Rediscovering famous assemblages: A rare Bronze Age crucible from El Argar,Spain

A rare open shallow crucible from the British Museum collection, excavated at the Bronze Age site of El Argar in south-east Spain by Louis and Henri Siret, was studied using X-radiography and scanning electron microscopy. The crucible has relatively thick walls, a spout and a non-refractory fabric. It was used for melting copper alloys for various possible purposes, such as alloying, refining, recycling or before casting, at around 1100°C. Both arsenic and tin were detected in various places and concentrations in the analysed specimens. This crucible could have been used during the period of transition from arsenic-rich copper to tin bronzes in the El Argar culture, or used for the recycling of arsenic-rich copper artefacts being alloyed with tin to produce tin bronzes. This melting crucible is a rare example of its kind to have been investigated scientifically, as most crucibles from contemporary sites on the Iberian Peninsula are generally associated with smelting. This study has also crucially shed more light on the types of alloys and variety of activities undertaken during that transitional period between the use of arsenical copper and tin bronzes in this region.     

Experimentally produced glass compared with that occurring at The Torr, NW Scotland, UK: vitrification through biotite melting

It is proposed that the vitrification in some Iron Age forts in NW Scotland can be explained through decomposition of micas (largely biotite) giving melts that react with or dissolve quartz and crystallise orthopyroxene and feldspars, so equating with the reaction biotite + quartz = sanidine + orthopyroxene + liquid. A sample of Moine semi-pelite has been experimentally melted at c. 850 °C demonstrating this breakdown reaction. A preserved thermal gradient across the sample reveals the progressive degradation of biotite towards the melting (upper) surface. Degradation is evident from the initial emphasis of mica cleavages in grains at the bottom of the sample, and then appearance and progressive increase in size of bubbles associated with biotite and melt towards the top of the sample. A chocolate-brown melt was produced as a coating on the upper surface and along micaceous layers. A near equivalent sample was located from the fort at The Torr that, whilst being more thoroughly affected by heat, with no unaffected biotite, preserved similar textures. Compositions of original Moine minerals are used to constrain the melts produced and melt evolution is tracked through quenched crystals. These include ternary feldspars as well as sanidine, spinels and orthopyroxene. Spot geochemical evidence demonstrates the heterogeneity of the melts, plus varying contributions of Ca and Na that could be attributed to the onset of reactions involving feldspars and other minerals from the original assemblage. It is thus concluded that a similar temperature to that of c. 850 °C derived in the experiment was reached in the vitrification process at The Torr in order to produce the glass observed.