Chloride ion concentrations during the compression of rocks to extract pore water

Pore water needs to be extracted from rocks with low permeabilities to allow the major ion concentrations in the pore water to be estimated. Compressing a rock is the most widely used method of extracting the pore water. However, ion concentrations have been found to change during compression in previous studies, and the mechanisms involved in such ion concentration changes have not yet been fully assessed. In this study, two natural rocks and four artificially prepared samples were compressed, and changes in the chloride ion (Cl^?) concentrations as the compression pressure increased were investigated. Mechanisms that could have caused the changes observed were then assessed. The Cl^? concentrations in squeezed water decreased as the pressure increased if the sample contained a significant amount of smectite. The strong dependence of Cl^? concentration on the amount of smectite indicated that smectite played an important role in decreasing the Cl^? concentration. The dilution of the pore water with interlayer water from the smectite appeared to be the dominant mechanism involved in the decrease in Cl^? concentration found in a Kunigel‐V1 sample, because dilution of the pore water with interlayer water quantitatively explained the decrease in the Cl^? concentration. The filter effect caused by the anion exclusion effect did not appear to be a dominant mechanisms in our case. However, Cl^? concentration decrease found in natural rocks could not be fully explained by dilution with interlayer water, so other mechanisms must be involved the phenomenon in natural rocks.     

IIR Compensation in Real-Time Hybrid Simulation using Shake Tables with Complex Control-Structure-Interaction

This article considers the use of actuator compensation in real-time hybrid simulation (RTHS) containing experimental substructures with complex control-structure-interaction (CSI). The existence of CSI in shake table testing is derived using theoretical relations. An infinite-impulse-response (IIR) compensator is developed to compensate for the shake table time delay as well as the effects of CSI. The efficacy of the IIR compensator is verified through numerical and experimental investigations of substructure shake table testing completed at Johns Hopkins University. IIR compensation is not limited to substructure shake table testing, and the concept is applicable to any RTHS that suffers from complex CSI.     

Can argillaceous formations isolate nuclear waste? Insights from isotopic,noble gas,and geochemical profiles

There is considerable interest in the use of thick argillaceous geologic formations to contain nuclear waste. Here, we show that diffusion can be the controlling transport process in these formations and diffusional time scales for δ¹⁸O and δ²H in water, dissolved He, and Cl transport in shale‐dominated aquitards are typically over 10⁶ years, well exceeding the regulatory requirements for isolation in most countries. Our scientific understanding of diffusive solute transport processes through argillaceous formations would benefit from the application of additional isotopic tracers (e.g., using new ⁴He sampling technology), multidimensional diffusive‐dispersive modeling of groundwater flow and diffusive‐dispersive solute transport over long geologic time scales, and an improved understanding of spatial heterogeneity as well as time‐dependent changes in the subsurface conditions and properties of argillaceous formations in response to events such as glaciation. Based on our current isotopic and geochemical understanding of transport, we argue that argillaceous formations can provide favorable long‐term conditions for isolating nuclear wastes.     

Mixed Force and Displacement Control for Testing Base-Isolated Bearings in Real-Time Hybrid Simulation

This paper presents a robust mixed force and displacement control strategy for testing of base isolation bearings in real-time hybrid simulation. The mixed-mode control is a critical experimental technique to impose accurate loading conditions on the base isolation bearings. The proposed mixed-mode control strategy consists of loop-shaping and proportional-integral-differential controllers. Following experimental validation, the mixed-mode control was demonstrated through a series of real-time hybrid simulation. The experimental results showed that the developed mixed-mode control enables accurate control of dynamic vertical force on the base isolation bearings during real-time hybrid simulation.     

New collaborations in old institutional spaces: setting a new research agenda to transform Indigenous-settler relations

ABSTRACT

Aboriginal and Torres Strait Islander people navigate the social and political order of the Australian settler state in ways that seek to increase their personal freedoms and political autonomy. For some groups this means seeking a firmer place within the social, political and economic life of Australia, and for others it means navigating away, towards a more distant relationship based in the resurgence of Indigenous nationhood. This navigation is composed of multifaceted and multidirectional relations between Indigenous Australians, settler Australians, and the settler state. As a discipline, political science must move beyond the study of settler institutions and begin to engage more comprehensively in research that considers the dynamics and structures of Indigenous-settler relations as a matter of priority.