Characterizations of palace lantern tassels preserved in The Palace Museum,Beijing, by UPLC-ESI-Q-TOF

Palace lanterns were important and highly visible decorations in the imperial palace in Beijing, China, during the Qing dynasty (1636–1912). Most lanterns had colourful tassels made of fibres. The study performed a comprehensive investigation of the materials and dyes used for palace lantern tassels preserved in The Palace Museum, Beijing. Eight samples with different colours, including yellow, green and red, from five palace lanterns were analysed. By using ultra-performance liquid chromatography combined with time-of-flight mass spectrometry, the compositions of the dyes were identified quickly, and thus the dyes' origins were explored. A X-ray fluorescence spectrometer assisted in the detection of whether a mordant was used during the dyeing process. As a result, the tassels were all made of silk, discovered through the use of microscopic observation and micro-Fourier transform infrared spectrometry analysis. Different dyeing techniques were found in these tassels: yellow tassels were dyed by cork tree or turmeric by a direct dyeing method; greens were dyed by pagoda bud with an iron mordant, or by the combination of cork tree and indigo using multi-dyeing method; and red tassels were coloured with different acid red industrial dyes. These results provide valuable data for the conservation of ancient textile tassels and contribute to the investigation of other hanging tags.     

季节时空交互视角下老年人公交移动性的影响因素研究——以芜湖市为例

公共交通是我国老年人出行的主要交通方式之一,公交移动性是衡量老年人生活质量和幸福感的重要指标。从季节和空间双重维度分析老年人公交移动性的影响因素有助于深入理解老年人出行行为机制。利用公交刷卡数据和地理探测器方法分析了季节时空因子对老年人公交移动性的影响。研究发现：①不同季节中空间因子对老年人移动频率、移动半径和移动熵的解释力和显著性存在明显差异,对老年人移动性影响机制的分析应考虑时空变化的双重影响;②不同空间因子之间以及季节与空间因子之间的交互作用可以显著增强对老年人移动性空间分异的解释力,考虑多个因素的协同效应对深入理解老年人行为有一定帮助。研究试图拓宽老年人移动性影响因素的分析思路,为老年宜居城市建设和城市移动性规划提供重要支撑。     

基于三维扫描模型的兵马俑足踝有限元分析

利用三维扫描技术获取兵马俑残片的三维点云数据,结合Geomagic Studio和Hypermesh建立高精度的兵马俑足踝残片三维实体网格模型。通过基于ABAQUS的重力作用下的有限元分析,研究足踝部分的Von Mises应力和变形特征,以确定足踝处的受力薄弱部位。为进一步探究模型各残片的最佳点云简化比例,采用点云简化模型进行相同工况的有限元分析,以验证点云简化的可靠性。结果表明:结构在重力作用下可保持安全稳定的状态,相对薄弱部位位于左腿足踝处;对于大部分残片,其最佳简化比例在60%～70%,简化后可有效缩短模型实体化处理时间;采用简化模型得到的有限元结果,其最大Mises应力相比于原始模型的误差小于15%,且应力云图和变形图形状接近,模型简化具有可靠性。     

聚醋酸乙烯酯乳液的表征、性能及其在彩绘类文物保护中的应用

聚醋酸乙烯酯(PVAc)乳液是常见的彩绘类文物保护材料。采用激光粒度仪、热重/差热分析、红外光谱、X-射线衍射、扫描电镜、透射电镜等表征了PVAc乳液的粒径以及胶膜的热稳定性、结构和形貌;采用粘度计、表面张力仪、pH计、电导率仪等研究了乳液浓度与其粘度、表面张力、pH、电导率的关系;通过冻融、室温-高温放置、离心分离研究了乳液的稳定性;同时用PVAc乳液对模拟起甲和酥碱的壁画进行了修复。结果表明,PVAc乳液粒径呈双峰分布,小粒子的平均粒径为380 nm,大粒子的平均粒径为5.85μm;乳液胶膜为非结晶物质,胶膜热重的最终质量残留为1.54%,335℃出现放热峰。PVAc乳液的电导率随浓度的增大而增大,pH随浓度的增大而下降;相同温度下表面张力随浓度的增大而基本呈现低浓度下降,高浓度上升的趋势。相同浓度下,表面张力随温度升高而无显著变化,表明PVAc乳液的表面张力受温度变化影响不大。相同温度下,乳液粘度随浓度的增大而增大;相同浓度下,乳液的粘度随温度的升高而降低。冻融、离心分离和不同温度下静置发现,该乳液出现分层。用该乳液对模拟起甲和酥碱壁画修复后,再分别老化20个循环和12个循环,发现颜料层再次空鼓、起甲。综合分析,说明实验中所使用的该种PVAc稳定性和抗老化能力较弱,在修复彩绘类文物中应慎重选择PVAc的种类,综合考虑PVAc的使用浓度、环境因素对其性能的影响,以达到最佳使用效果。     

西安城墙东门箭楼砖坯墙体风化因素研究报告

论述了西安城墙东门箭楼的文化背景,实地考察了风化外状,并对风化外状进行了分类测试。通过对砖坯墙体材料进行化学全分析、X－射线衍射分析、吸水率测定（含他和系数）、冻融实验、泛霜实验、环境污染与水文气象监测资料的分析,研究了东门箭楼砖坯墙体不同风化外状的风化因素,同时对现代修缮用砖的理化性能及质量进行了评估。结果表明,温度的交替变化、水的冻结与融化使得砖坯裂解成碎块;干湿引起可溶盐的结晶与潮解以及自然界中的雨水、地面水或地下水、污染气体等通过溶解、水化、水解、碳酸化、氧化等方式,使得砖坯墙体表面酥碱粉化。同时说明研究适用于古建筑修缮使用的抗风化仿古青砖是当务之急。     

Reducing Toxic Chemical Releases and Transfers: Explaining Outcomes for a Voluntary Program

Relatively little is known about the possibilities and limitations of voluntary public programs. The so-called 33/50 Program for reducing releases of certain toxic chemicals into the environment provides a useful instance for examination. In an investigation of toxics-reduction outcomes, with states as units of analysis, economic and policy variables help to explain the results. In particular, channels and approaches used In communicating policy intentions are related to outcomes. Voluntary programs can make a difference, but the details of execution, including the extent and nature of field efforts, influence outcomes.     

The Chemical Composition and Production Area of Early Western Zhou Proto‐Porcelain Unearthed from Yejiashan Cemetery,Suizhou, China

The bodies and glazes of 27 early Western Zhou proto‐porcelain samples from Yejiashan cemetery, Hubei Province, were analysed using LA‐ICP–AES, SEM, XRD, a thermal expansion instrument and other analytical methods. The results indicated that the bodies of all samples were characterized by high silicon and low aluminium, and were made with porcelain stone raw materials found in the south of China. The glazes are typical of high‐temperature calcium glazes of the CaO (MgO) – K₂O (Na₂O) – Al₂O₃ – SiO₂ series, with relatively high Mn and P content, which was probably caused by the addition of plant ashes. The physical properties and phase compositions of Yejiashan proto‐porcelain show that firing processes were still in the early stages of development in ancient China. Multivariate statistical analyses indicated that Yejiashan proto‐porcelain might have come from the Deqing area, in Zhejiang Province. These results provide new archaeological evidence for research on issues related to material flow in the Western Zhou dynasty.     

An Approach to the Diagnosis of Craniofacial Fibrous Dysplasia from the 2500‐Year‐Old Remains of a Skull from Ancient China

A human skull, buried about 2500 years ago in a Bronze Age cemetery at Jinggouzi, a site of an important ethnic group in ancient China, appeared to have characteristics of fibrous dysplasia. The CT images indicated a reduction in bone density and relatively homogeneous lesions. More features were revealed using CT reconstruction techniques. Lesions seen in low‐magnification images using a 3D deep‐field microscope had an irregular honeycomb‐like structure. At higher magnification, the trabeculae morphology and the gaps between the trabeculae were irregular and varied in size and shape. Paraffin‐embedded specimens stained with HE showed trabeculae with tortuous irregular arrangements varying in shape and width. The irregular trabeculae of woven bone has been described as having fibrous dysplasia. Molecular analysis of the GNAS gene indicated no mutation. This provides a non‐invasive approach for us to make more comprehensive diagnoses and to assist research into ancient human diseases.     

The Real vs the Imaginary: Sir William Chambers on the Chinese Garden

Sir William Chambers was one of the most important English architects in the eighteenth-century, but both in his day and later his international recognition was closely connected with his admiration for and promotion of Chinese art, particularly Chinese landscaping. Between 1757 and 1773, Chambers published three treatises praising the ingenious mixture of nature and art in a Chinese pleasure ground, criticizing the then influential English gardener Lancelot (Capability) Brown, and trying to goad English garden design into the direction of China. He did not achieve his purposes mainly because he mixed what he knew as genuine about the Chinese gardening art with what he fantasized about it. While recent scholarship has focused on his fantasy, this article examines what Chambers knew or imagined about Chinese landscaping, what he and his detractors were for and against, and how the fiasco of his 1772 and 1773 treatises, which he brought upon himself, nevertheless helped to usher in a new phase in the English reception of Chinese landscaping ideas.     

Chemical and Microscopic Study of Masonry Mortar in Ancient Pagodas in East China

Ancient mortars played a crucial role in the construction of historical architectures due to their physical and chemical compatibility with traditional building materials such as stones and bricks. Therefore, the analysis and optimization of the ancient mortar formula are significant in the restoration and preservation of historical sites. In this work, 20 mortar samples selected from five ancient stone pagodas in Zhejiang Province, China, were analyzed. The results showed that mud, lime-soil mortar, lime-sand mortar, and lime-gypsum mortar were used as binders in these pagodas. The Ca(OH)₂/aggregate ratio ranging from 0.3 to 2.7 was usually used to prepare lime mortar. Protein and polysaccharide were also found in some samples.