季节时空交互视角下老年人公交移动性的影响因素研究——以芜湖市为例

公共交通是我国老年人出行的主要交通方式之一,公交移动性是衡量老年人生活质量和幸福感的重要指标。从季节和空间双重维度分析老年人公交移动性的影响因素有助于深入理解老年人出行行为机制。利用公交刷卡数据和地理探测器方法分析了季节时空因子对老年人公交移动性的影响。研究发现：①不同季节中空间因子对老年人移动频率、移动半径和移动熵的解释力和显著性存在明显差异,对老年人移动性影响机制的分析应考虑时空变化的双重影响;②不同空间因子之间以及季节与空间因子之间的交互作用可以显著增强对老年人移动性空间分异的解释力,考虑多个因素的协同效应对深入理解老年人行为有一定帮助。研究试图拓宽老年人移动性影响因素的分析思路,为老年宜居城市建设和城市移动性规划提供重要支撑。     

聚醋酸乙烯酯乳液的表征、性能及其在彩绘类文物保护中的应用

聚醋酸乙烯酯(PVAc)乳液是常见的彩绘类文物保护材料。采用激光粒度仪、热重/差热分析、红外光谱、X-射线衍射、扫描电镜、透射电镜等表征了PVAc乳液的粒径以及胶膜的热稳定性、结构和形貌;采用粘度计、表面张力仪、pH计、电导率仪等研究了乳液浓度与其粘度、表面张力、pH、电导率的关系;通过冻融、室温-高温放置、离心分离研究了乳液的稳定性;同时用PVAc乳液对模拟起甲和酥碱的壁画进行了修复。结果表明,PVAc乳液粒径呈双峰分布,小粒子的平均粒径为380 nm,大粒子的平均粒径为5.85μm;乳液胶膜为非结晶物质,胶膜热重的最终质量残留为1.54%,335℃出现放热峰。PVAc乳液的电导率随浓度的增大而增大,pH随浓度的增大而下降;相同温度下表面张力随浓度的增大而基本呈现低浓度下降,高浓度上升的趋势。相同浓度下,表面张力随温度升高而无显著变化,表明PVAc乳液的表面张力受温度变化影响不大。相同温度下,乳液粘度随浓度的增大而增大;相同浓度下,乳液的粘度随温度的升高而降低。冻融、离心分离和不同温度下静置发现,该乳液出现分层。用该乳液对模拟起甲和酥碱壁画修复后,再分别老化20个循环和12个循环,发现颜料层再次空鼓、起甲。综合分析,说明实验中所使用的该种PVAc稳定性和抗老化能力较弱,在修复彩绘类文物中应慎重选择PVAc的种类,综合考虑PVAc的使用浓度、环境因素对其性能的影响,以达到最佳使用效果。     

广西玉林市博物馆馆藏七件铜鼓的初步分析研究

迄今已有2 700多年历史的铜鼓,是南方少数民族地区节日、喜庆、兵事、婚丧、祭祀、礼乐等场合使用的一种重器。为了对锈蚀状况做出科学的现状评估,为器物保护修复技术路线的制定和修复工作的开展提供科学指导,对玉林市博物馆馆藏7件铜鼓综合运用了体视显微镜、金相显微镜、激光显微拉曼光谱仪(RS)和环境扫描电镜及能谱仪(ESEM-EDAX)等仪器进行了金相组织和合金成分分析以及锈蚀产物的分析。分析结果显示:7件器物皆为泥范铸造成型,未见热、冷加工处理现象。7件铜鼓皆为铅锡青铜合金,总体呈低锡高铅的特点。组织形态呈典型α固溶体树枝晶偏析,锡含量处于6.0%～12.2%,分布较为集中,处于中等含量水平(5%≤Sn15%);铅含量处于14.4%～28.2%,铅含量普遍较高且分布较为集中,处于中高铅(10%≤Pb15%)和高铅含量(Pb≥15%)水平,合金中高铅含量配比应为工匠有意合金配比选择;铜鼓的腐蚀类型为α固溶体富铜相优先腐蚀,保存环境主要是富氧、少氯,铜鼓表面锈蚀产物主要为绿色孔雀石和蓝色蓝铜矿以及氧化物,有少量白色白铅矿。在保护修复工作中对于这些无害锈可保留,不予处理,并注重防氧。对于铜鼓表面夹杂泥土,需进行清洗去除。研究结果可为器物保护修复技术路线的制定和修复工作的开展提供科学指导。     

被“局外中立”遮蔽的历史:清政府日俄战争善后筹议

清政府的日俄战争善后,不仅涉及主权恢复与利益挽回,更与东北边圉安全以及“龙兴之地”的未来命运息息相关,清廷上下极为重视,对战争善后的筹议与“局外中立”平行展开.从战事爆发到两国议和,内外臣工数次集中讨论日俄局势因应之策与战后东北经营方略,有针对性地提出调停争端、严守中立、加强边防、改制行省、推行新政、开埠通商以及联日抗俄等涉及内政外交的多项建议,基本确定了战争善后的总体框架,拉开了清政府日俄战争善后的序幕并为之奠定基础.梳理这一过程,可见清政府应对两国战和局势、处理战争善后的心路历程,有利于把握战争善后事务的基本脉络及各项举措之间的内在联系,且对于清末新政研究不无裨益.     

西安城墙东门箭楼砖坯墙体风化因素研究报告

论述了西安城墙东门箭楼的文化背景,实地考察了风化外状,并对风化外状进行了分类测试。通过对砖坯墙体材料进行化学全分析、X－射线衍射分析、吸水率测定（含他和系数）、冻融实验、泛霜实验、环境污染与水文气象监测资料的分析,研究了东门箭楼砖坯墙体不同风化外状的风化因素,同时对现代修缮用砖的理化性能及质量进行了评估。结果表明,温度的交替变化、水的冻结与融化使得砖坯裂解成碎块;干湿引起可溶盐的结晶与潮解以及自然界中的雨水、地面水或地下水、污染气体等通过溶解、水化、水解、碳酸化、氧化等方式,使得砖坯墙体表面酥碱粉化。同时说明研究适用于古建筑修缮使用的抗风化仿古青砖是当务之急。     

Reducing Toxic Chemical Releases and Transfers: Explaining Outcomes for a Voluntary Program

Relatively little is known about the possibilities and limitations of voluntary public programs. The so-called 33/50 Program for reducing releases of certain toxic chemicals into the environment provides a useful instance for examination. In an investigation of toxics-reduction outcomes, with states as units of analysis, economic and policy variables help to explain the results. In particular, channels and approaches used In communicating policy intentions are related to outcomes. Voluntary programs can make a difference, but the details of execution, including the extent and nature of field efforts, influence outcomes.     

The Chemical Composition and Production Area of Early Western Zhou Proto‐Porcelain Unearthed from Yejiashan Cemetery,Suizhou, China

The bodies and glazes of 27 early Western Zhou proto‐porcelain samples from Yejiashan cemetery, Hubei Province, were analysed using LA‐ICP–AES, SEM, XRD, a thermal expansion instrument and other analytical methods. The results indicated that the bodies of all samples were characterized by high silicon and low aluminium, and were made with porcelain stone raw materials found in the south of China. The glazes are typical of high‐temperature calcium glazes of the CaO (MgO) – K₂O (Na₂O) – Al₂O₃ – SiO₂ series, with relatively high Mn and P content, which was probably caused by the addition of plant ashes. The physical properties and phase compositions of Yejiashan proto‐porcelain show that firing processes were still in the early stages of development in ancient China. Multivariate statistical analyses indicated that Yejiashan proto‐porcelain might have come from the Deqing area, in Zhejiang Province. These results provide new archaeological evidence for research on issues related to material flow in the Western Zhou dynasty.     

An Approach to the Diagnosis of Craniofacial Fibrous Dysplasia from the 2500‐Year‐Old Remains of a Skull from Ancient China

A human skull, buried about 2500 years ago in a Bronze Age cemetery at Jinggouzi, a site of an important ethnic group in ancient China, appeared to have characteristics of fibrous dysplasia. The CT images indicated a reduction in bone density and relatively homogeneous lesions. More features were revealed using CT reconstruction techniques. Lesions seen in low‐magnification images using a 3D deep‐field microscope had an irregular honeycomb‐like structure. At higher magnification, the trabeculae morphology and the gaps between the trabeculae were irregular and varied in size and shape. Paraffin‐embedded specimens stained with HE showed trabeculae with tortuous irregular arrangements varying in shape and width. The irregular trabeculae of woven bone has been described as having fibrous dysplasia. Molecular analysis of the GNAS gene indicated no mutation. This provides a non‐invasive approach for us to make more comprehensive diagnoses and to assist research into ancient human diseases.     

基于手机信令数据的长春市活动空间特征与社区分异研究

居民时空行为成为透视城市空间的重要视角,本文基于手机信令数据研究长春市活动空间及其社区分异,轮廓性的揭示居住空间、就业空间和消费休闲空间的分布规律,从人地互动的过程与格局的视角认识城市空间。研究发现,居住活动对中心城区依赖明显高于就业和消费休闲活动,就业活动呈现多中心连片发展格局,近郊的欧亚卖场和郊区的净月潭成为人们消费休闲活动的重要选择。就业-居住距离和消费休闲-居住距离的社区分异显著,折射出三类活动空间关系复杂,由此感知城市生活空间质量和社会空间结构。通过对社区分异的空间聚类分析明晰各地域自身问题,从而有针对性的对长春的空间调整优化和居民行为引导提出建议,构建和谐宜居的城市空间。