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This paper re‐analyses a considerable corpus of glass from the Late Bronze Age site of Nuzi, found near Kirkuk in Iraq. SEM–WDS and Sr and Nd isotopic analysis were applied, in addition to cataloguing the glass. The work showed that the glass technology at Nuzi was subtly different from contemporary Egyptian sites, using different ways of opacifying and working glass. At least two, perhaps three, Near Eastern production sites are postulated. The range of glass colours and the skill of their application at Nuzi was perhaps not on a par with the Egyptian sites. This led to a reconsideration and review of the accepted wisdom that the Near East is the source of the innovation that is glass‐making. This opinion is based on limited textual and iconographic sources and is dominated by an erroneous early date for a very developed Nuzi glass industry along with a few finds of glass vessels in early contexts. Some of this evidence has now been at least questioned, suggesting that glass‐making in Egypt, at least as early as the middle of the 15th century bc , and probably earlier, is no later than that in the Near East. It is argued that it is far from clear that the Near East was the source of the innovation and that a more cautious approach would better fit the evidence.  相似文献   
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Los Naranjos is one of the most important pre-Columbian human settlements of Honduras related to the south-easternmost border of the Mayan civilization. Although the archaeological site mostly spans from 850 BC to 1250 AD, the present obsidian study was only focused on the Preclassic and Early Classic periods (Jaral, 800–400 BC and Edén, 400 BC–550 AD) where undamaged blades and/or retouched obsidian flakes are rare. In this way, the INAA analyses of 17 obsidian samples, compared with major-trace elements data of Honduran and Guatemalan obsidian sources, are mostly representative of waste flakes. Lithic artifacts of Los Naranjos such as sandstones, basalts, and quartzites come from local geological outcrops; whereas, obsidian provenance has to be searched from sources which are located within a radius up to 300 km far away. San Luis, La Esperanza, and Güinope obsidian sources are located in Honduras while the three most exploited Highland Guatemalan obsidian outcrops, which have been dominating long-distance trade in the Maya area mostly for the Classic-Postclassic periods, are San Martin de Jilotepeque, El Chayal, and Ixtepeque. An Ixtepeque provenance, for all the investigated obsidian samples of Preclassic and Early Classic periods found in the Los Naranjos Archaeological Park, was established, thus emphasizing a long-distance source (180 km). This also confirms that Ixtepeque represents the most important provenance of the obsidian artifacts found in archaeological sites of Western and Central-Western Honduras. The possible role played by some of the most important rivers of Guatemala and Honduras as waterway networks of transport was finally pointed out. New INAA chemical data from the Honduran obsidian source of La Esperanza (“Los Hoyos”, 4 samples) are also reported in this paper.  相似文献   
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The origins of raw glass used to fashion Mycenaean beads were explored using trace elements analyzed by laser ablation ICP-TOFMS. The use of this minimally destructive technique for the in-situ analysis of these beads was ideal given that the material is exceedingly rare and thus too sensitive to make use of traditional micro-sampling (e.g., by scalpel). A wide range of trace elements were measured to compare these Greek glasses to other Late Bronze Age glass coming from Egypt and Mesopotamia. Of the eleven beads analyzed, four blue glasses colored with cobalt and two blue/green glasses colored with copper have trace element compositions consistent with an Egyptian origin of manufacture. The other five of the glasses, all colored with copper, were found to conform to the composition of Mesopotamian glass. These data are the first to demonstrate direct and clear evidence for the trade of raw glass to the Mycenaean states.  相似文献   
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