Non-invasive on-site method for thickness measurement of transparent ceramic glazes based on depth from focus

Glazed ceramics are a common material analyzed through geochemistry, whether in the form of tableware collected during excavations or tiles observed as part of architectural features. Within the framework of these studies, measuring the thickness of the transparent glaze is one of the useful variables available for the characterization of the ceramic, contributing to searches for provenance as well as serialization. However, this task often requires invasive methods performed in the laboratory, which may not always be possible. This paper develops a non-invasive and portable on-site system for measuring the thickness of ceramic glazes. Based on the depth from focus technique, this method makes use of a classical camera, a macroscopic lens, a translation stage, and a laptop for system control. In this article, we test this method through the measurement of glaze for ten samples as compared to results obtained for sections through scanning electron microscopy.     

A non-invasive study of Roman Age mosaic glass tesserae by means of Raman spectroscopy

Ancient mosaic tesserae are a range of materials of very varied and complex nature, including pottery, stone and glass. Raman spectroscopy is a powerful tool for the analysis of all these kinds of materials. In the particular case of glasses, this technique can be used both for a study of surface weathering and for the characterization of bulk structure, but it has not yet been extensively used for the characterization of mosaic glass tesserae. We carried out Raman analyses on a set of Roman and Late Antiquity period mosaic glass samples, which allowed a good characterization of both the glass matrix and the crystalline inclusions. All the samples show the typical Raman signatures of soda-lime-silicate glasses. Several crystalline phases were also identified, being relics of raw materials used during the glass manufacturing process, such as quartz and feldspars, or linked to the glass color/opacification, such as bindheimite and cuprite. The analyses also led to the identification in some blue, turquoise and green tesserae of calcium antimonate, whose Raman signature has only recently been recognized in the scientific literature on mosaic glasses. Some emphasis is given to the analysis of red lead-containing tesserae, colored with Cu⁺ ions or even Cu⁰ (or Au⁰) metal nanoparticles. Samples with peculiar compositions, as well as “modern” (and restoration) samples, could quite easily be distinguished from the ancient ones by their Raman spectra.