NMR as a new tool for cultural heritage application: The provenance of ancient white marbles

Identifying the origin of marble used in antiquity brings back to light details of the economic, social and political organization of classical societies, and characterizing in depth the chemistry of marble is key to discovering its provenance. Beyond X‐ray diffraction, which could reveal the presence of discriminant secondary crystalline phases and the quantification of accessory minerals combined with a multivariate analysis approach, solid‐state nuclear magnetic resonance (NMR) enables one to recognize the local structure arrangement of both crystalline and amorphous materials by looking at one or more selected atoms. In present paper targets the ¹³C nuclide, and thus the major component of marble, calcium carbonate. Whatever their geological origin, marbles ¹³C‐NMR spectra present only one resonance corresponding to the carboxyl function whose intensity and line width vary from one marble to another. If the variation of the NMR signal intensity observed is the result of great T1 variations (from 220 to 5300 s) and is linked to iron content, the line width reflects defects in the calcite crystal in which calcium has been replaced by another element such as magnesium, aluminium or strontium. The specific profile of the NMR signal has been used successfully to help determine the origin of some archaeological items.     

Age of the final Middle Palaeolithic and Uluzzian levels at Fumane Cave,Northern Italy,using C,ESR, U/Th and thermoluminescence methods

This article presents and discusses the chronological layout of the final Mousterian and Uluzzian levels of Fumane Cave in northern Italy using ¹⁴C, ESR and TL methods. Given its complex sedimentary and cultural succession, Fumane is a key site to assess the Middle–Upper Palaeolithic transition in Southern Europe and to explore Neanderthal behaviour and to compare it with the first Aurignacians. Large ranges defined by the ESR and TL dates cover the radiocarbon ages for units from A11 to A4, respectively, from 42.8 to 32.5 ka BP become progressively younger in agreement with the stratigraphy, despite high dispersions within the same unit. Our estimates using chronometric data seem to support the hypothesis that the sequence may cover almost 10,000 radiocarbon yr and that from comparison with the sedimentological and palaeoecological data, the late Middle Palaeolithic and the early Upper Palaeolithic at Fumane occur in sediments formed under moderately cool to mild climatic conditions correlated to the Hengelo-Interstadial, shifting towards cooler and drier conditions. Finally, comparisons between the Fumane data set and other sites in the North-Adriatic region are discussed.     

How old are Australia's pictographs? A review of rock art dating

Australia contains some of the world's richest and apparently longest traditions of rock pictographs. Dating this art, however, has been problematic, with few ‘direct’ and reliable dates of Pleistocene or early Holocene age having been obtained from visible, representational imagery. This paper critically reviews the evidence for the antiquity of pigment rock art in Australia by examining the various dating techniques employed. The accurate and reliable dating of rock art worldwide is crucial to understanding the evolution of modern human symbolism and whether cognitive modernism came about after, rather than with, the first signs of full biological modernism; understanding the pitfalls and devising proper methods are crucial prerequisites. Towards these ends, this paper reviews the results and techniques that have been employed to date the apparently earliest known pictographs in Australia.     

The Potential of EBSD and EDS for Ceramics Investigations—Case Studies on Sherds of Pre‐Columbian Pottery

The work focuses on the potential of structural and chemical examinations by scanning electron microscopy based methods for archaeometric studies on ceramics. Achieved by a single preparation technique (polished block sections), the feasibility and benefits of electron backscatter diffraction are demonstrated as case studies using polychrome examples of pre‐Columbian pottery (Wari, Moche and Cajamarca). Elemental and phase maps allow for separate consideration of clay and temper. Identification of mineral phases and intergrowths of temper particles provide information for clarifying clay procurement and firing techniques with respect to local versus non‐local pottery to enlighten trade relations, technological transfer and shared heritage of pre‐Columbian cultures.     

Interactions between Weather Stochasticity and the Locations of Pollution Sources and Receptors in Air Quality Planning: A Chance-Constrained Approach

Optimization models for the design of regional air quality control strategies have been developed under the assumption that the annual frequencies of the different meteorological conditions remain constant from year to year. This paper demonstrates empirically that this assumption is not correct, and that the solutions of such models lead either to violation of the annual air quality standard or to unnecessarily high costs for pollution abatement. A chance-constrained, geographically based approach is formulated to account for the interannual randomness of the meteorological conditions and for the locations of pollution sources and receptors and is applied with different approximation methods. The policy implications of the results in terms of optimal standard selection and implementation of the optimal chance-constrained pollution abatement plan through decentralized decision-making by individual pollution sources are assessed.     

Paleodemographic analysis of a fossil porcupine (Hystrix refossa Gervais, 1852) population from the Upper Pleistocene site of Geula Cave (Mount Carmel,Israel)

For decades zooarchaeological studies mainly focused on teeth age profiles to derive central hypotheses concerning human subsistence during the Pleistocene. Behavior was often related to hunting and/or scavenging strategies according to two models: attritional versus catastrophic. However, few studies have estimated basic demographic parameters using standard methods of population ecology, which are necessary for a more confident interpretation of animal paleopopulation structures. Thanks to a remarkably rich fossil bone assemblage from the Upper Pleistocene cave of Geula (Mount Carmel, Israel), in this paper we perform a paleodemographic analysis of Hystrix refossa, Gervais 1852 (Mammalia, Rodentia). We first consider phylogenetic and morphometric dental criteria for the comparison of Pleistocene porcupine species, followed by an examination of taphonomic conditions of the bone assemblage. We focus strongly on the age structure of the fossil population, presenting a new methodological approach that combines life tables and Leslie matrix models – one of the best-known methods in population ecology for assessing population growth and age distribution. We detail demographic parameters derived from cross-sectional life tables and past trends in the porcupine population at Geula Cave using simple matrix projection model. Finally, we were able to perform an elasticity analysis to identify which demographic component was potentially the most critical for influencing growth. We show that the population of H. refossa did not decline or shrink but was stable. Our results permit us to characterize Geula Cave as a natural shelter for porcupines, with limited evidence to scavenging and hunting by either hyenas or humans.     

A 28,000 year old excavated painted rock from Nawarla Gabarnmang,northern Australia

We report new archaeological excavations from northern Australia revealing part of a charcoal design likely to be c. 28,000 years old (and chrono-stratigraphically constrained within the period 15,600–45,600 cal BP) on a small rock slab fallen from the ceiling at the rockshelter of Nawarla Gabarnmang in Jawoyn country, Arnhem Land. This represents the oldest confirmed pictograph in Australia.