A MULTI‐ANALYTICAL APPROACH FOR THE CHARACTERIZATION OF COMMODITIES IN A CERAMIC JAR FROM ANTINOE (EGYPT)*

This paper describes a multi‐analytical chemical study performed on the original, almost totally conserved, content of a small ceramic jar from the Antinoe archaeological site (fifth to seventh centuries ad, Roman Egypt) and now belonging to the archaeological collection of the Istituto Papirologico ‘Girolamo Vitelli’ (Florence, Italy). Scanning electron microscopy with an energy‐dispersive X‐ray spectrometer (SEM–EDX), Fourier transformed infrared spectroscopy (FTIR) and X‐ray diffraction (XRD) were all used to characterize the inorganic components of the archaeological material. The organic substances were analysed using FTIR, direct exposure mass spectrometry (DE–MS) and gas chromatography – mass spectrometry (GC–MS). The inorganic component essentially consisted of halite (NaCl). Among the NaCl crystals, lamellar elements were identified. They were chemically characterized by carbonato‐apatite and showed a concentric morphology typical of the scales of small fish. The most prevalent organic constituents of the sample were monocarboxylic acids, α,ω‐dicarboxylic acids, and cholesterol and its oxidation products. The organic material composition was consistent with the occurrence of lipids of animal origin. In addition, diterpenes related to pine pitch were also identified. The overall results suggest that the material recovered in the small ceramic jar found in Antinoe is a residue of fish‐based pickles such as garum, muria, allex and liquamen, which were commonly used in Roman times.     

EVALUATION OF THE APPLICABILITY OF CONVENTIONAL METHODS FOR THE CHEMICAL CHARACTERIZATION OF WATERLOGGED ARCHAEOLOGICAL WOOD

A series of 112 waterlogged archaeological wood samples of different provenances, wood species, burial times and states of preservation were analysed with the aim of assessing the validity (in terms of limits and reliability) of procedures conventionally used in the pulp and paper industry, to evaluate the state of preservation of decayed wood. In particular, the extent of any damage wrought on decayed wood tissue by the repetitive cycles that characterize these procedures was evaluated as a function of the degradation of the samples. The results indicated that standard methodologies give reliable measurements regardless of the extent of wood decay. However, it is essential to compare these data with those of non‐decayed wood that has been measured using the same procedures to take account of the errors that are inherent in these methodologies and that affect measurements.     

THE CHARACTERIZATION OF WATERLOGGED ARCHAEOLOGICAL WOOD: THE THREE ROMAN SHIPS FOUND IN NAPLES (ITALY)*

Three apparently well‐preserved shipwrecks dating back to Roman times were brought to light near Piazza Municipio in Naples (Italy), during the excavation for the construction of Line 1 of the subway. The shipwrecks were covered by marine sand and silt, below the water table. In order to establish the nature and the extent of wood degradation and, therefore, determine how best to preserve the shipwrecks, a diagnostic investigation was carried out. The study involved the identification of wood species, chemical characterization of the residue component and physical and micro‐morphological characterization.