Reflections into Ptolemaic glass: Colorless,white, blue,and green inlays from the workshop of Tebtynis

Inlays range among the most aesthetically pleasing and technically challenging glasses produced in the Ptolemaic period. Despite the central role of this phase in the history of glass technology, little is known about the recipes and the technological knowledge of the Egyptian artisans. This paper will thus focus on the study of the materials from the secondary workshop of Tebtynis (Fayum oasis, Egypt). We report the first multi-methodological study comprising textural, chemical, and mineralogical analyses (optical microscopy, scanning electron microscopy coupled with energy-dispersive system, electron probe microanalysis, and μ-Raman spectroscopy) on a set of 81 colorless, white, blue, and green samples carefully selected among the 800+ glasses from the craft area now stored at the Museo Egizio, Turin (Italy). Our study offers the biggest compositional database of well-dated Ptolemaic glasses currently available in the literature, highlighting some interesting novelties regarding the silica and alkali sources, and the coloring and opacifying techniques employed. The results suggest a specialized craft of traditional origin, but open to innovation and experimentation, as expected from transitional phases.     

Phase‐field modeling of epitaxial growth of polycrystalline quartz veins in hydrothermal experiments

Mineral precipitation in an open fracture plays a crucial role in the evolution of fracture permeability in rocks, and the microstructural development and precipitation rates are closely linked to fluid composition, the kind of host rock as well as temperature and pressure. In this study, we develop a continuum thermodynamic model to understand polycrystalline growth of quartz aggregates from the rock surface. The adapted multiphase‐field model takes into consideration both the absolute growth rate as a function of the driving force of the reaction (free energy differences between solid and liquid phases), and the equilibrium crystal shape (Wulff shape). In addition, we realize the anisotropic shape of the quartz crystal by introducing relative growth rates of the facets. The missing parameters of the model, including surface energy and relative growth rates, are determined by detailed analysis of the crystal shapes and crystallographic orientation of polycrystalline quartz aggregates in veins synthesized in previous hydrothermal experiments. The growth simulations were carried out for a single crystal and for grain aggregates from a rock surface. The single crystal simulation reveals the importance of crystal facetting on the growth rate; for example, growth velocity in the c‐axis direction drops by a factor of ~9 when the faceting is complete. The textures produced by the polycrystal simulations are similar to those observed in the hydrothermal experiments, including the number of surviving grains and crystallographic preferred orientations as a function of the distance from the rock wall. Our model and the methods to define its parameters provide a basis for further investigation of fracture sealing under varying conditions.     

ELEMENTS OF SKILL: TRAITS,INTELLIGENCES, EDUCATION,AND AGGLOMERATION*

ABSTRACT There are many fundamental issues in regional and urban economics that hinge on worker skills. This paper builds on psychological approaches to learning to characterize the role of education and agglomeration in the skill development process. While the standard approach of equating skill to worker education can be useful, there are important aspects of skill that are missed. Using a measure of skill derived from hedonic attribution, the paper explores the geographic distribution of worker traits, intelligences, and skills and considers the roles of urbanization and education in the skill development process.