The use of SEM-EDS,PIXE and EDXRF for obsidian provenance studies in the Near East: a case study from Neolithic Çatalhöyük (central Anatolia)

In this paper we evaluate the relative analytical capabilities of SEM-EDS, PIXE and EDXRF for characterizing archaeologically significant Anatolian obsidians on the basis of their elemental compositions. The study involves 54 geological samples from various sources, together with an archaeological case study involving 100 artifacts from Neolithic Çatalhöyük (central Anatolia). With each technique the artifacts formed two compositional groups that correlated with the East Göllü Da? and Nenezi Da? sources. The non-destructive capabilities of these methods are emphasized (albeit with certain analytical limitations in the case of SEM-EDS), suggesting important new techniques for Near Eastern obsidian provenance studies.     

THE EFFECT OF SALTS ON THERMAL AND HYDRIC DILATATION OF POROUS BUILDING STONE*

Fifteen desalinated sandstone drill core samples from Umm Ishrin Sandstone Formation in Petra (Cambrian age) were used for this study. The samples were mineralogically analysed using X‐ray diffraction and their physical properties were also determined. Samples with similar physical properties and mineralogical composition were taken for further experimental work. After desalination, thermal and hydric dilatation coefficients were measured, then three types of salts (NaCl, KCl and Na₂SO₄·10H₂O), which have high solubility and consequently are the most dangerous to building stone (and are also detected in the sandstone monuments in Petra), were introduced into the samples and their contents were calculated. The results show that salt crystallization in the pores of building stones can increase their thermal dilatation and decrease their hydric dilatation to varying extents, depending on the nature of the salt. The average increase in the thermal dilatation coefficient per unit mass of salt is the lowest for the Na₂SO₄·10H₂O‐salted samples with a value of 5.3%, while the NaCl‐salted samples have the highest value with 7.8% per salt mass. The average percentage of the decrease of the hydric dilatation coefficient is 1061% for Na₂SO₄·10H₂O‐salted samples per mass of salt content; the NaCl‐salted samples have a value of 1510% per mass of salt content, and the KCl‐salted samples almost the same value. For the salt‐free samples, it was found that in climatic conditions with a high temperature range, the deterioration of sandstone due to temperature fluctuation is more effective than that caused by change in the moisture content, while samples with high salt content suffer more from hydric dilatation.     

Fracture mineralization and fluid flow evolution: an example from Ordovician–Devonian carbonates,southwestern Ontario,Canada

Petrography, geochemistry (stable and radiogenic isotopes), and fluid inclusion microthermometry of matrix dolomite, fracture‐filling calcite, and saddle dolomite in Ordovician to Devonian carbonates from southwestern Ontario, Canada, provide useful insights into fluid flow evolution during diagenesis. The calculated δ¹⁸O_fluid, ΣREE, and REE_SN patterns of matrix and saddle dolomite suggest diverse fluids were involved in dolomitization and/or recrystallization of dolomite. The ⁸⁷Sr/⁸⁶Sr ratios of dolomite of each succession vary from values in the range of coeval seawater to values more radiogenic than corresponding seawater, which indicate diagenetic fluids were influenced by significant water/rock interaction. High salinities (22.4–26.3 wt. % NaCl + CaCl₂) of Silurian and Ordovician dolomite–hosted fluid inclusions indicate involvement of saline waters from dissolution of Silurian evaporites. High fluid inclusion homogenization temperatures (>100°C) in all samples from Devonian to Ordovician show temperatures higher than maximum burial (60–90°C) of their host strata and suggest involvement of hydrothermal fluids in precipitation and/or recrystallization of dolomite. A thermal anomaly over the mid‐continent rift during Devonian to Mississippian time likely was the source of excess heat in the basin. Thermal buoyancy resulting from this anomaly was the driving force for migration of hydrothermal fluids through regional aquifers from the center of the Michigan Basin toward its margin. The decreasing trend of homogenization temperatures from the basin center toward its margin further supports the interpreted migration of hydrothermal fluids from the basin center toward its margin. Hydrocarbon‐bearing fluid inclusions in late‐stage Devonian to Ordovician calcite cements with high homogenization temperatures (>80°C) and their ¹³C‐depleted values (approaching ?32‰ PDB) indicate the close relationship between hydrothermal fluids and hydrocarbon migration.     

TECHNOLOGY AND PROVENANCE OF A COLLECTION OF ISLAMIC COPPER‐BASED OBJECTS AS FOUND BY CHEMICAL AND LEAD ISOTOPE ANALYSIS*

Chemical and lead isotope analyses were utilized to determine the composition, technology and origin of a collection of Islamic copper‐based objects found in Jordan. The atomic absorption spectrometry results show that the objects were made of different types of copper‐base alloys that contain various amounts of zinc, tin and lead. The use of brass, highly leaded brass and quaternary alloys of Cu‐Zn‐Sn‐Pb in the manufacture of everyday, household objects strongly points to Islamic traditions. The lead isotope compositions of the objects match very well that of the copper ore mined from the Dolomite‐Limestone‐Shale unit of the Arabah copper mines.     

A 'Hut pot'in the National Museum, Bahrain

This note presents a fine softstone vessel which has not previously been fully published. Its findspot supports the recent suggestion that such pots continued to be manufactured until the end of the third millennium.     

CONSTRUCTION OF THE KHOJA ZAYNUDDIN MOSQUE: USE OF ANIMAL GLUE MODIFIED WITH URINE*

As part of an ongoing project at the World Heritage Site of Bukhara, we investigated the glue used in the construction of the Khoja Zaynuddin mosque. Analysis by a range of techniques confirmed that it consisted of a collagen‐based glue. However, the glue contained many non‐protein constituents. The presence of lipid material suggests that the glue was produced by a relatively unsophisticated process. More surprisingly, various marker compounds of urine were found. Study of the viscosity of a mixture of a modern collagen‐based glue and urea showed that the presence of urea at a concentration typical of human urine reduced the viscosity of the glue, thus improving its spreading characteristics and enabling its use at a lower temperature. Whilst the advantages of adding urea to glue were known to craftsmen in Europe and America in the 19th century, it would appear that the builders of Bukhara were aware of the technique, using less pure components, at a significantly earlier date.     

Characterization of archaeological obsidians from Lagartero, Chiapas Mexico by PIXE

Obsidian samples from the archaeological site of Lagartero, Chiapas, Mexico and other samples from Mexican and Guatemalan sources were analyzed by proton induced X-ray emission. Statistical treatments such as principal-component analyses were applied to the data set. Obsidians from Lagartero were identified as coming from two obsidian sources in Guatemala and one in Mexico, thus indicating that there was contact between people of Lagartero and other Mayans or Mesoamericans.     

ÉVOLUTION DE L'AGRICULTURE MARAÎCHÈRE AU QUÉBEC DE 1940 À 1990: SUPERFICIES,PRODUCTIONS ET DIVERSITÉ

Depuis plus d'un siècle, l'agriculture québécoise en général, et la production maraîchère en particulier, ont subi d'importantes transformations. Cette étude historique vise à comprendre comment la production maraîchère a évolué par rapport aux changements dans l'environnement décisionnel général de l'agriculture entre 1940 et 1990. L'analyse des données statiques de superficie, de production et de rendement pour 12 légumes ont permis d'identifier trois périodes, intercalées d'années transitoires, dans l'évolution de la production maraîchère référant chacune à une stratégie agricole particulière. La première (1940–1957) correspond à une stratégie agricole de type familial traditionnel; la seconde (1963–1975), à une agriculture marchande spécialisée fondée sur la maximisation des revenus à court terme par intensification; la troisième (1980–1990), à une agriculture marchande diversifiée fondée également sur une maximisation à court terme. Les facteurs externes de l'environnement décisionnel qui ont entraîné ces changements sont identifiés et discutès. For more than a century, Quebec agriculture in general, and market-gardening production in particular, have experienced important changes. This study, using a historical perspective, seeks to understand how market gardening evolved in relation to changes in the broad decision environment for agriculture between 1940 and 1990. Statistical analysis of data on the areas cultivated, production levels, and yields for 12 vegetable crops revealed three distinct periods, separated by periods of transition, in the evolution of market gardening. Each period is characterized by a particular type of agricultural development strategy. The first period (1940–1957) is characterized by a focus on the traditional family form; the second (1963–1975), by a specialized market agriculture driven by short-term income-maximization intensification; the third (1980–1990), by a diversified marketoriented agriculture, also based on short-term income maximization. External environmental factors that stimulated these changes are identified and discussed.     

A seal in the collections of the National Museum, Bahrain

This article describes a Murghab seal amulet recently identified in the collections of the National Museum of Bahrain and discusses some of the other evidence for contact between Central Asia and the Gulf in the early second millennium.     

The Museum for the History of the University of Pavia and the Birth of Histology

A brief overview is provided on the development of histology as an independent discipline at the University of Pavia, through documents and preparations preserved in the Museum for the History of the University. Studies on the organization of tissues and cells started blooming in the mid-1850s, when morphological observations were supported by significant technical advancements in microscopy and tissue preparation. The role of Albert Koelliker, the great father of European Histology in the second half of 19 th century, is also discussed. Koelliker had several contacts with Camillo Golgi and promoted the diffusion of Golgi's discoveries. The authors also underline the innovative role of Camillo Golgi in the histological approach to research and in the foundation of modern histology.