Carbon and nitrogen isotope signals in eel bone collagen from Mesolithic and Neolithic sites in northern Europe

Carbon and nitrogen isotope analysis was undertaken on collagen extracted from eel bone from six Mesolithic and Neolithic sites in northern Europe. The results were compared with data obtained on other archaeological fish remains and modern eel caught in fresh and brackish water and from the sea. The possibility of discriminating between freshwater, brackish and marine signals in archaeological eel bone is evaluated and the implications for archaeology discussed. Our data suggest that eel found at coastal Mesolithic and Neolithic sites have carbon isotope signals consistent with a marine origin with no evidence of freshwater residency. The sample of eel bone from one inland site is small but indicates carbon isotope values more consistent with freshwater residency or at least values intermediate between freshwater and marine carbon pools.     

Isotopic and zooarchaeological investigation of later medieval and post-medieval cattle husbandry at Dudley Castle,West Midlands

Abstract

Zooarchaeological analysis of a substantial assemblage of animal bones excavated from Dudley Castle, West Midlands, revealed two significant changes in cattle management in the late medieval and post-medieval periods: a statistically significant increase in size in the later 14th century; and a gradual reduction in slaughter age. To explore whether these altered husbandry practices were accompanied by modifications to the diet and environment of these animals, a targeted study of carbon and nitrogen stable isotope values from 135 cattle bones was conducted. This analysis revealed that δ¹³C and δ¹⁵N values were broadly consistent between the mid-13th and mid-18th centuries. Only two statistically significant diachronic variations were identified: a temporary decrease in δ¹³C values in phase 7 (1397–1533); and lower variation in δ¹³C values in phase 9 (1647–1750). A number of explanations for these changes are offered. While the zooarchaeologically attested shifts in cattle husbandry were not accompanied by isotopically detectable changes to diet and environment, the analysis of stable isotopes highlighted other changes that were not detected using traditional zooarchaeological analysis. The complimentary benefits of zooarchaeological and isotopic approaches are extolled.     

Crenostrea sp. cf. C. cannoni (Marwick, 1928) (Bivalvia: Ostreoidea) and associated fauna from east of Heard Island,Kerguelen Plateau: age and palaeoenvironmental value

Quilty, P.G., Clark, N. & Hibberd, T., 21.01.2015. Crenostrea sp. cf. C. cannoni (Marwick, 1928) (Bivalvia: Ostreacea) and associated fauna from east of Heard Island, Kerguelen Plateau: age and palaeoenvironmental value. Alcheringa 39, xxx–xxx. ISSN 0311-5518

A well-preserved single left valve of a large oyster embedded in coarse volcaniclastic sediment and identified as Crenostrea sp. cf. C. cannoni (Marwick, 1928) was dredged from east of Heard Island, central southern Indian Ocean. It is accompanied by a fragment of the pectinid bivalve Austrochlamys sp. indet. and foraminifera. Austrochlamys sp. indet. and other bivalve fragments were analysed for ⁸⁷Sr/⁸⁶Sr, δ¹⁸O and δ¹³C, the results yielding an age of 17.5 Ma (later early Miocene) and a water temperature of ca 10°C. Foraminifera and sediment characteristics indicate that accumulation occurred in mid-continental shelf depths, at a location where nutrient supply was good.

Patrick G. Quilty [p.quilty@utas.edu.au], School of Earth Sciences (Private Bag 79) and Institute for Marine and Antarctic Studies (IMAS: Private Bag 129), University of Tasmania, Hobart, Tasmania 7001, Australia. Nicola Clark [nc118@leicester.ac.uk], Department of Geology, University of Leicester, University Road, Leicester LE1 7RH, UK. Ty Hibberd [ty.hibberd@aad.gov.au], Australian Antarctic Division, Channel Highway, Kingston, Tasmania 7050, Australia.     

Establishing collagen quality criteria for sulphur isotope analysis of archaeological bone collagen

Sulphur isotope measurements of bone collagen from archaeological sites are beginning to be applied more often, yet there are no clear criteria to assess the quality of the collagen and therefore the validity of the sulphur isotope values. We provide elemental data from different methods (DNA sequences, amino acid sequences and mass spectrometric measurements) which are used to establish a reliable system of quality criteria for sulphur isotope analyses of bone collagen. The difference in the amount of sulphur from fish and mammalian collagen type I led to the suggestion to use different criteria to assess the in vivo character of the collagen between these two categories. For establishing quality ranges, the bone collagen of 140 modern animals were analysed. The amount of sulphur in fish and mammalian bone collagen is 0.63 ± 0.08% and 0.28 ± 0.07%, respectively. Based on these results we define for mammalian bone collagen an atomic C:S ratio of 600 ± 300 and an atomic N:S ratio of 200 ± 100, and for fish bone an atomic C:S ratio of 175 ± 50 and an atomic N:S ratio of 60 ± 20. These quality criteria were then applied to 305 specimens from different archaeological contexts.     

Upper crustal fluid flow in the outboard region of the Southern Alps,New Zealand

The currently active fluid regime within the outboard region of the Southern Alps, New Zealand was investigated using a combination of field observations, carbon‐ and oxygen‐stable isotopes from fault‐hosted calcites and interpretation of magnetotelluric (MT) data. Active faulting in the region is dominated by NE striking and N striking, oppositely dipping thrust fault pairs. Stable isotopic analyses of calcites hosted within these fault zones range from 10 to 25‰δ¹⁸O and from ?33 to 0‰δ¹³C. These values reflect mixing of three parent fluids: meteoric water, carbon‐exchanged groundwater and minor deeper rock‐exchanged fluids, at temperatures of 10–90°C in the upper 3–4 km of the crust. A broad, ‘U‐shaped’ zone of high electrical conductivity (maximum depth c. 28 km) underlies the central Southern Alps. In the ductile region of the crust, the high‐conductivity zone is subhorizontal. Near‐vertical zones of high conductivity extend upward to the surface on both sides of the conductive zone. On the outboard side of the orogen, the conductive zone reaches the surface coincident with the trace of the active Forest Creek Faults. Near‐surface flow is shown to dominate the outboard region. Topographically driven meteoric water interacts, on a kilometre scale, with either carbon‐exchanged groundwater or directly with organic material within Pliocene gravels, resulting in a distinctive low ¹³C signal within fault‐hosted calcites of the outboard region. The high‐strain zone in the lower crust focuses the migration of deeply sourced fluids upward to the base of the brittle–ductile transition. Interconnected fluid is imaged as a narrow vertical zone of high conductivity in the upper crust, implying continuous permeability and possibly buoyancy‐driven flow of deeply sourced fluids to higher levels of the crust where they are detected by the isotopic analysis of the fault‐hosted calcites.     

Ancient hydrocarbon seeps from the Mesozoic convergent margin of California: carbonate geochemistry, fluids and palaeoenvironments

More than a dozen hydrocarbon seep‐carbonate occurrences in late Jurassic to late Cretaceous forearc and accretionary prism strata, western California, accumulated in turbidite/fault‐hosted or serpentine diapir‐related settings. Three sites, Paskenta, Cold Fork of Cottonwood Creek and Wilbur Springs, were analyzed for their petrographic, geochemical and palaeoecological attributes, and each showed a three‐stage development that recorded the evolution of fluids through reducing–oxidizing–reducing conditions. The first stage constituted diffusive, reduced fluid seepage (CH₄, H₂S) through seafloor sediments, as indicated by Fe‐rich detrital micrite, corroded surfaces encrusted with framboidal pyrite, anhedral yellow calcite and negative cement stable isotopic signatures (δ¹³C as low as ?35.5‰ PDB; δ¹⁸O as low as ?10.8‰ PDB). Mega‐invertebrates, adapted to reduced conditions and/or bacterial chemosymbiosis, colonized the sites during this earliest period of fluid seepage. A second, early stage of centralized venting at the seafloor followed, which was coincident with hydrocarbon migration, as evidenced by nonluminescent fibrous cements with δ¹³C values as low as ?43.7‰ PDB, elevated δ¹⁸O (up to +2.3‰ PDB), petroleum inclusions, marine borings and lack of pyrite. Throughout these early phases of hydrocarbon seepage, microbial sediments were preserved as layered and clotted, nondetrital micrites. A final late‐stage of development marked a return to reducing conditions during burial diagenesis, as implied by pore‐associated Mn‐rich cement phases with bright cathodoluminescent patterns, and negative δ¹⁸O signatures (as low as ?14‰ PDB). These recurring patterns among sites highlight similarities in the hydrogeological evolution of the Mesozoic convergent margin of California, which influenced local geochemical conditions and organism responses. A comparison of stable carbon and oxygen isotopic data for 33 globally distributed seep‐carbonates, ranging in age from Devonian to Recent, delineated three groupings that reflect variable fluid input, different tectono‐sedimentary regimes and time–temperature‐dependent burial diagenesis.     

Reassessing the northern limit of maize consumption in North America: stable isotope,plant microfossil,and trace element content of carbonized food residue

In combination, the analysis of carbonized food residue for stable C and N isotopes, elemental composition, and plant microfossils (phytoliths and starch granules) offers a powerful tool for understanding patterns of prehistoric maize (Zea mays) consumption in small-scale societies. Using this approach, we conclude that maize was more widely consumed in North America than previously suspected. Between ∼AD 700 and 1600, despite little or no archaeological evidence of gardening, corn was a widespread component of diet on the eastern Canadian prairies. This pattern, furthermore, extended into the adjacent boreal forest at about the same time. However, carbon (δ¹³C) and nitrogen (δ¹⁵N) values on food residue samples vary widely, suggesting significant overall dietary differences from one region to the next. Analysis of a subset of residue samples for elemental composition (using ICP-OES [inductively coupled plasma–optical emission spectrometry]) may help identify broad trends in the provenience of foods consumed at these sites.     

“Mycenaean” political domination of Knossos following the Late Minoan IB destructions on Crete: negative evidence from strontium isotope ratio analysis (Sr/Sr)

Strontium isotope ratio analysis of human dental enamel and bone is applied to investigate a highly debated question of population movement and cultural discontinuity in Prehistoric Aegean Archaeology. The Late Minoan IB (ca. 1490/1470 BC) destructions on Crete are succeeded by cultural upheaval. The novel cultural features that appear at Knossos (Crete) in this period have forerunners in the Mainland. In Cretan context, the Linear B writing system, the funerary architecture and burial practices of the Mainland style are interpreted as evidence of an actual “Mycenaean” long-term settlement and political domination of Knossos. Human skeletal material from tombs that are associated with non-locals from the Mainland based upon the material culture is analysed to measure ⁸⁷Sr/⁸⁶Sr. The results of the analysis show that all the examined individuals from the Knossos tombs were born locally.     

Mobilization of ore fluids during Alpine metamorphism: evidence from hydrothermal veins in the Variscan basement of Western Carpathians,Slovakia

Hydrothermal polymetallic veins of the Gemeric unit of the Western Carpathians are oriented coherently with the foliation of their low‐grade Variscan basement host. Early siderite precipitated from homogeneous NaCl‐KCl‐CaCl₂‐H₂O brines with minor CO₂, while immiscible gas–brine mixtures are indicative of the superimposed barite, quartz–tourmaline and quartz–sulphide stages. The high‐salinity aqueous fluid (18–35 wt%) found in all mineralization stages corresponds to formation water modified by interaction with crystalline basement rocks at temperatures between 140 and 300°C. High brominity (around 1000 ppm in average) resulted from evaporation and anhydrite precipitation in a Permo‐Triassic marine basin, and from secondary enrichment by dissolution of organic matter in the marine sediments at diagenetic temperatures. Sulphate depletion reflects thermogenic reduction during infiltration of the formation waters into the Variscan crystalline basement. Crystallization temperatures of the siderite fill (140–300°C) and oxygen isotope ratios of the parental fluids (4–10‰) increase towards the centre of the Gemeric cleavage fan, probably as a consequence of decreasing water/rock ratios in rock‐buffered hydrothermal systems operating during the initial stages of vein evolution. In contrast, buoyant gas–water mixtures, variable salinities and strongly fluctuating P–T parameters in the successive mineralization stages reflect transition from a closed to an open hydrothermal system and mixing of fluids from various sources. Depths of burial were 6–14 km (1.7–4.4 kbar, in a predominantly lithostatic fluid regime) during the siderite and barite sub‐stages of the north‐Gemeric veins, and up to 16 km (1.6–4.5 kbar, in a hydrostatic to lithostatic fluid regime) in the quartz–tourmaline stage of the south‐Gemeric veins. The fluid pressure decreased down to approximately 0.6 kbar during crystallization of sulphides. U‐Pb‐Th, ⁴⁰Ar/³⁹Ar and K/Ar geochronology applied to hydrothermal muscovite–phengite and monazite, as well as cleavage phyllosilicates in the adjacent basement rocks and deformed Permian conglomerates corroborated the opening of hydrothermal veins during Lower Cretaceous thrusting and their rejuvenation during Late Cretaceous sinistral transpressive shearing and extension.     

The influence of poorly interconnected fault zone flow paths on spring geochemistry

Thermal springs commonly occur along faults because of the enhanced vertical permeability afforded by fracture zones. Field and laboratory studies of fault zone materials document substantial heterogeneities in fracture permeabilities. Modeling and field studies of springs suggest that spatial variations in permeability strongly influence spring locations, discharge rates and temperatures. The impact of heterogeneous permeability on spring geochemistry, however, is poorly documented. We present stable isotope and water chemistry data from a series of closely spaced thermal springs associated with the Hayward Fault, California. We suggest that substantial spatial variations observed in δ¹⁸O and chloride values reflect subsurface fluid transport through a poorly connected fracture network in which mixing of subsurface waters remains limited. Our measurements provide insight into the effect of fracture zone heterogeneities on spring geochemistry, offer an additional tool to intuit the nature of tectonically induced changes in fault zone plumbing, and highlight the need to consider local variations when characterizing fracture zone fluid geochemistry from spring systems with multiple discharge sites.