A Discussion on the Emergence and Development of Ancient Chinese Artificial Barium Copper Silicate Pigments from Simulation Experiments

The ancient Chinese barium copper silicate minerals mainly comprise Chinese purple (BaCuSi₂O₆) and Chinese blue (BaCuSi₄O₁₀), which were widely used from the late Warring States Period to the late Eastern Han Dynasty. In order to clarify the raw material of the pigment, a series of simulation experiments was conducted to produce Chinese purple pigment under varying mineral conditions. The minerals that we applied in the experiment were quartz as the source of silicon, malachite and copper oxide as the sources of copper, barite and witherite as the sources of barium and lead oxide as the source of lead. Simulation experiments showed that the barium copper silicate minerals and the purple pigment can be produced easily when witherite is used as the barium‐containing raw material. From the perspective of mineral resources, the birth of the ancient Chinese pigment associated with a unique barium mineral resource. The Chinese copper‐based pigments are assumed to have been developed independently and are presumably an outcome of historical developments in glazing techniques.     

广东“南澳Ⅰ号”明代沉船出水铜器腐蚀产物分析

由于海水环境中含有大量氯化物,海洋出水铜器在出水前已发生腐蚀,生成铜的氧化物及氯化物等。本文以广东"南澳Ⅰ号"明代沉船出水的22件铜器残片为研究对象,运用X-射线荧光仪(XRF)、X-射线衍射仪(XRD)和扫描电镜与能谱仪(SEM-EDS)等分析其腐蚀产物和矿物组成,结果表明腐蚀产物主要为铜的碱式氯化物,如Cu2(OH)3Cl和Cu(OH)Cl等,与国外已有研究成果类似,但Cu(OH)Cl在国外海洋出水铜器腐蚀产物中并不常见。     

云南祥云县检村石棺墓出土铜器的初步研究

为研究滇西地区青铜文化及相关铜器的制作技术,本研究采用扫描电镜和金相分析的方法,对云南祥云检村石棺墓出土的17件样品进行取样分析,结果表明祥云检村石棺墓出土的铜器以红铜为主,少数为Cu-Sn合金。这些器物的制作工艺主要是铸造、铸后冷加工等,制作工艺相对单一。3件编钟均为Cu-Sn合金,并且锡成分具有等比递增的现象。兵器矛经过鉴定后说明由于墓主身份的不同,随葬的矛也有实用器和随葬器两类。农具锸和工具锥和凿的鉴定表明有冷加工或使用过的痕迹,可能曾是实用器;而农具锄经鉴定并没有在农作中使用过,仅作为随葬品,进一步证明随葬铜锄是青铜时代滇西地区的一种丧葬习俗。分析表明,当时已根据不同器物的用途进行了不同的制作和加工。本研究结果对研究滇西青铜文化及金属技术有一定的意义。     

三至六世纪东西文化交流的见证：南朝铜器的科技考古研究

西亚地区的响铜技术何时传入中国及东亚列国,是一个重要的学术问题。经对江苏句容、江都及南京出土的南朝铜器作科技考古研究,发现最迟在南朝刘宋元嘉年间,来自西亚的新型的响铜技术已经在中国南北方地区立足,此后可能相继传入韩国（百济）,并进而到达日本地区。过去,响铜及黄铜（输石）技术的考古学研究作为相对独立的领域在日本受到重视．但中国考古界则鲜有研究。新发现的这批南朝响铜器及黄铜制品时研究3-6世纪时期东西方不同国家和地区的响铜和黄铜（输石）工艺的传播乃至更广泛的文化交流有重要意义。     

Exchange Rate Policy and Economic Growth after the Financial Crisis in Central and Eastern Europe

In a paper on the effects of the global financial crisis in Central and Eastern Europe (CEE), a European Union economist reacts to a companion paper (Åslund, 2001) published in the same issue of Eurasian Geography and Economics on the influence of exchange rate policies on the region's recovery. The author argues that post-crisis corrections in current account deficits in CEE countries do not in themselves signal a return to steady economic growth. Disagreeing with Åslund over the role of loose monetary policy in fostering the region's economic problems, he outlines a number of competitiveness problems that remain to be addressed in the 10 new EU member states of CEE, along with improvements in framework conditions supporting future macroeconomic growth.     

微量元素示踪古代青铜器铜矿料来源的可行性

目前,微量元素示踪法在青铜器矿料来源研究中的应用不尽人意。为此,模拟熔铸青铜器,对它们的微量元素作多元统计分析,旨在探讨利用微量元素探索古代青铜器铜矿料来源的可行性。分析表明：若舍弃冶炼后富集亍炉渣中的亲石亲铁元素,而仅选取富集于铜料中的亲铜元素及一些凡具有亲铜性,又具有亲铁性元素的成分数据,则通过多元统计分析,能较好地区别不同产地的铜矿料。     

安徽淮北部分地区出土青铜器的铜矿来源分析

内容提要本文利用地球化学示踪的原理,以特征微量元素作为判别标志,对安徽省淮北部分地区出土的先秦时期铜器的铜料来源进行了初步分析,其中部分样品的铜料可能来自铜陵地区,有的可能来自铜绿山及其它地区。     

A truly refractory crucible from fourth millennium Tepe Hissar, Northeast Iran

From the Early Chalcolithic to the Late Iron Age, melting and smelting crucibles were usually made from non-refractory ceramic fabrics, which required heating of the charge from within the crucible to avoid collapsing the ceramic itself. In this paper, an unusual melting crucible from Northeast Iran, radiocarbon-dated to the Late Chalcolithic (ca. 3600 BCE), will be presented that significantly changes our understanding of the development of technical ceramics in Southwest Asia. This crucible, made of a highly refractory talc-based ceramic held together by an outer layer of traditional non-refractory ceramic, is to our knowledge unprecedented at such an early date. As will be argued, this ancient crucible was heated from the exterior or from below and not from the interior. This method of firing, combined with the highly-specialized construction technique, makes this crucible so far unique in prehistoric metallurgy, and forces us to re-examine traditional models for the development of technical ceramics and metallurgical practices in the Old World.     

The agricultural basis of Umm an-Nar society in the northern Oman peninsula (2500–2000 BC)

This paper argues that the agricultural aspect of the Umm an-Nar economy has been largely ignored by researchers, due to an overemphasis on copper production and trade. This is true at the level of the smallest rural settlements, villages and settlements whose primary focus was agricultural production.
The key social developments of this period have often been explained by linking them to the exploitation of copper ore and its trade with surrounding regions such as Mesopotamia and the Indus. However, this paper will argue — based on quantified pottery analysis — that it is during this time that we see the development, for the first time in the Oman peninsula, of widespread sedentary occupation that was based on small agricultural villages where there is no evidence of copper ore exploitation, thus suggesting that the economic basis of Umm an-Nar society was essentially agricultural.
Furthermore, it will be argued that, through the use of a new survey methodology, it is possible to locate such settlements, even where they have left no traces of monuments, such as tombs or round towers. The methodology allows preliminary comparisons to be made between the intensity of occupation in different periods. The paper also argues that the Umm an-Nar period was one of the most intensive periods of occupation in pre-Islamic history.     

楚金币的发现与研究

本文概述了楚国金币的发现情况,对楚金币的种类、形制、印记、重量与刻文诸问题加以探讨,对楚金币出土情况进行剖析,认为,楚金币是流通中的秤量货币,它与铜贝是主币与辅币的关系;并对楚金币的币材产地、冶炼技术与铸造年代等进行研究。