Pottery production and distribution in prehistoric Bronze Age Cyprus. An application of pXRF analysis

Portable X-ray Fluorescence (pXRF) analysis of over 400 samples of Early and Middle Bronze Age Cypriot pottery from four widely separated sites identifies both local and non-local products at each. A series of analyses of sub-sets of the data highlights differences in the clays used at each site and for some distinctive types and wares. When assessed in the context of general typological, technological and stylistic factors these variations provide the basis for considering patterns of local production and inter-regional relationships across the island. Although the great majority of pots were locally made, particular wares and shapes were brought in from elsewhere. For some sites finer, more highly decorated vessels are mostly imports, but at others both simpler and more complex vessels were made of the same local clays. While small juglets or flasks may have been containers for transporting small quantities of rare substances, larger vessels are likely to have held less precious material. Open vessels, especially small bowls – some of which are plain, utilitarian items – represent another aspect of social behaviour and inter-regional relationships.     

Among Polynesia's first pots

X-ray fluorescence spectroscopy and petrographic thin section microscopy are applied to a sample of anomalous appearing Lapita pottery sherds from Nukuleka, the earliest archaeological site in Polynesia. Both analyses indicate non-local origins for the ceramic vessels, suggesting they were brought on founding canoes. Mineral inclusions in ceramic tempers eliminate sources to the west of Tonga in eastern Melanesia; rather the temper source is most probably a dacitic high island from a distant island arc of central Melanesia. Polynesian origins and settlement are issues more complex than currently recognized by the orthodox progressive settlement model for Lapita expansion across Oceania.     

Non-destructive provenance study of cuneiform tablets using portable X-ray fluorescence (pXRF)

Portable X-Ray Fluorescence (pXRF) apparatus of the last generation was tested to determine its potential for routine provenance determination of clay cuneiform tablets, which cannot be analyzed by “classical” intrusive methods. A group of tablets from Hattuša (Bo?azköy) and from el Amarna, which were previously provenanced using optical mineralogy (OM) and instrumental neutron activation analysis (INAA), was analyzed by pXRF and the results were used to establish the grouping according to their elemental concentrations. These groups were compared with the previous results retrieved by OM and INAA in order to confirm their validity. The results corroborate the high potential of the pXRF for non-destructive study of well-defined, ‘closed’ assemblages of clay-derived, delicate artifacts, such as cuneiform tablets, bullae, and fine-ware pottery. Consequently, a group of previously unexamined tablets from Hattuša was analyzed by pXRF and the results are discussed with implications on future research.     

Tongan and Samoan volcanic glass: pXRF analysis and implications for constructs of ancestral Polynesian society

A provenance study of volcanic glass specimens from 12 archaeological sites in the Kingdom of Tonga is carried out employing pXRF (portable X-ray fluorescence) analysis. To accomplish this, volcanic glass samples from previously identified sources in northern Tonga and the adjacent islands of Samoa are analyzed. Results indicate inter-island voyaging and interaction over a 600 km linear distance along the Tongan island chain from first Lapita settlement ca 2900 BP throughout later prehistory. Tongan volcanic glass, however, is not found in Samoa and, with the exception of one late prehistoric specimen, Samoan volcanic glass is not present in Tonga. This distribution challenges current concepts of an integrated ancestral society and homeland common to Tonga and Samoa from the Lapita period onward.     

The Early Bronze Age settlement of Fidvár,Vráble (Slovakia): reconstructing prehistoric settlement patterns using portable XRF

This paper presents first results of chemical analyses of sediment samples from the Early Bronze Age (EBA) settlement Fidvár near Vráble (Slovakia). Large-scale geomagnetic prospection revealed detailed architectural remains of a fortified settlement. Other structures such as an earthwork of the linear pottery culture and at least two Roman march camps were found too. An Auger programme provided sediment samples of different depths, A) from an EBA house and the outer fortification ditch, B) from a potential metal workshop area as indicated by surface finds, and C) from an area located in the settlement's centre. The samples were analysed by a portable X-ray fluorescence (pXRF) spectrometer in order to investigate the vertical and horizontal distribution of chemical signatures. The comparison of geophysical data and three-dimensional chemical patterns gives us the opportunity to determine the human impact and to reconstruct activity patterns. The potentials and limits in the application of pXRF in archaeological soil chemical surveys are evaluated by systematic comparisons with high resolution laboratory measurements, including atomic absorption spectrometry (AAS) and inductively coupled plasma optical emission spectrometry (ICP-OES). The pXRF analyses can be reproduced well and show a good accuracy. Whilst (p)XRF analyses reflect the total composition of archaeological soil samples, the results of the AAS and ICP-OES analyses are fundamentally influenced by the acid digestion or extraction methods used. The pXRF analyses of the Vráble soils showed typical patterns of human occupation. For example, there are strong positive correlations between phosphorous, strontium and calcium. Phosphorous shows an enrichment in pathways and the fortification ditch. It is less strongly enriched within the sediments of house structures. Similar results apply to calcium and strontium distribution. But compared to the respective concentrations in sediment samples from the ditch they show a considerably higher variation in samples associated with house structures; that is, individual samples of sediments from house structures contained high concentrations of both, calcium and strontium. The deposits of an area that according to surface finds was thought to represent a potential metal workshop did not show indicative chemical signatures. Targeted excavations confirmed the absence of such as workshop. Finally it was shown that the refill history of the innermost fortification ditch (sample area D) and the overall cultural occupation sequence at the site correlate strongly with the chemical signatures of the respective ditch profile. The systematic variation of key elements along the profile opens up an entirely new perspective for interpreting the site's history. Overall, the study shows the great potential of pXRF as valuable part of an archaeological survey toolkit.     

An early Iron Age assemblage of faience beads from Ashkelon,Israel: chemical composition and manufacturing process

The microstructure and chemical composition of eight faience beads from an early Iron Age (12th century BCE) assemblage found in the ancient city port of Ashkelon (Israel) are determined by means of FTIR spectrometry, pXRF, microRaman and SEM-EDS analysis. The results are compared with published data of Egyptian and Near Eastern artifacts. Each sample exhibits a hue which is obtained by adding a specific colorant to the glazing mixture. A new gray chalcopyrite-manganese-based colorant was identified. Cementation glazing was most likely used in the manufacturing process of the specimens analyzed, except for the blue bead, which is an Egyptian blue frit. The results suggest that these objects represent a unique assemblage, quite different from contemporary Egyptian and Near Eastern materials, and provide new information regarding the Iron Age faience evidence in the southern Levant.     

Ethno-geochemical and Phytolith Studies of Activity Related Patterns: A Case Study from Al Ma’tan,Jordan

ABSTRACT

Understanding Neolithic sites in southwest Asia is often difficult because of the lack of preservation of organic remains and the effects of various taphonomic processes that alter the original record. Here, we use an ethnographic approach to test the potential of using plant phytoliths and geochemistry to aid our interpretation of southwest Asian Neolithic sites. Our study of a recently abandoned stone and mud constructed village in Jordan, shows that for certain activity types, phytoliths and geochemistry can help distinguish different construction methods and functions, particularly for burnt areas, animal use areas and where there has been the addition of a specific construction material. For features constructed from the same source materials distinctions are more problematic. Geochemical and phytolith proxies were individually effective in distinguishing activity areas and construction materials, but signals were diminished when the statistical analysis was run on both forms of evidence combined. It is therefore recommended that the data from plant phytolith and geochemical analyses are subject to separate statistical tests and that the two sets of results are used in combination to interpret archaeological sites and their uses.     

The So‐called Venetian Enamelled Copper Artworks of the Italian Renaissance: the Technology and Provenance of the Enamels—an Analytical Approach

The so‐called Venetian enamelled coppers are a group of objects produced in Italy during the 15th century. Up to now, about 300 objects have been recognized in private collections and in European and US museums. At the end of 19th century, a Venetian origin was suggested, but their provenance is still debated. In this study, the enamel compositions from 22 enamelled copper products from Italian and French collections have been analysed by invasive and non‐invasive techniques. A comparison of the results with Tuscan and Venetian glass databases reinforces the suggestion of a Tuscan (most probably Florentine) origin for these works of art.     

Obsidian provenance analyses at Göytepe,Azerbaijan: Implications for understanding Neolithic socioeconomies in the southern Caucasus

This study presents a provenance analysis of the Neolithic obsidian assemblages from the early to mid‐sixth millennium bc settlement at Göytepe, Azerbaijan. The study is unique in that (1) it involves a complete, non‐selected obsidian assemblage (901 artefacts) from one particular area of the site; (2) the material is derived from a well‐stratified sequence of 10 securely radiocarbon‐dated architectural levels; and (3) the use of an extraordinarily wide range of sources (more than 20) was identified by provenance analysis using energy‐dispersive X‐ray fluorescence. The results reveal a previously unknown diachronic change in obsidian use in the region, suggesting the occurrence of significant socioeconomic changes during the Late Neolithic of the southern Caucasus.     

A characterisation study of Ubaid period ceramics from As-Sabbiya,Kuwait, using a non-destructive portable X-Ray fluorescence (pXRF) spectrometer and petrographic analyses

The Ubaid cultural phenomena (6500–4200 BC) of southern Mesopotamia has been used to characterise other archaeological sites in the Arabian Gulf region. The aim of this inquiry is to explore the nature of the interaction between the homeland of the Ubaid and the wider Gulf region. Through the use of a non-destructive portable X-ray fluorescence (pXRF) spectrometer, this study seeks to characterise and identify the chemical and mineralogical compositions of the ceramic assemblage from the Bahra 1 site of the As-Sabbiya region, Kuwait. The chemical results demonstrated that a combination of six trace elements [rubidium (Rb), strontium (Sr), yttrium (Y), zirconium (Zr), niobium (Nb) and barium (Ba)] occur significantly enough to delineate clay-based artifact groups—local red coarse from Ubaid, while the mineralogical analysis confirms the pXRF result and identifies the source of the raw materials and temper as well. Also, the comparison between the Ubaid and Bronze Age assemblage results suggests that potters used different clay resources within their own regions and/or production techniques.