Infiltration of basinal fluids into high-grade basement, South Norway: sources and behaviour of waters and brines

Quartz veins hosted by the high‐grade crystalline rocks of the Modum complex, Southern Norway, formed when basinal fluids from an overlying Palaeozoic foreland basin infiltrated the basement at temperatures of c. 220°C (higher in the southernmost part of the area). This infiltration resulted in the formation of veins containing both two‐phase and halite‐bearing aqueous fluid inclusions, sometimes with bitumen and hydrocarbon inclusions. Microthermometric results demonstrate a very wide range of salinities of aqueous fluids preserved in these veins, ranging from c. 0 to 40 wt% NaCl equivalent. The range in homogenization temperatures is also very large (99–322°C for the entire dataset) and shows little or no correlation with salinity. A combination of aqueous fluid microthermometry, halogen geochemistry and oxygen isotope studies suggest that fluids from a range of separate aquifers were responsible for the quartz growth, but all have chemistries comparable to sedimentary formation waters. The bulk of the quartz grew from relatively low δ¹⁸O fluids derived directly from the basin or equilibrated in the upper part of the basement (T < 200°C). Nevertheless, some fluids acquired higher salinities due to deep wall‐rock hydration reactions leading to salt saturation at high temperatures (>300°C). The range in fluid inclusion homogenization temperatures and densities, combined with estimates of the ambient temperature of the basement rocks suggests that at different times veins acted as conduits for influx of both hotter and colder fluids, as well as experiencing fluctuations in fluid pressure. This is interpreted to reflect episodic flow linked to seismicity, with hotter dry basement rocks acting as a sink for cooler fluids from the overlying basin, while detailed flow paths reflected local effects of opening and closing of individual fractures as well as reaction with wall rocks. Thermal considerations suggest that the duration of some flow events was very short, possibly in the order of days. As a result of the complex pattern of fracturing and flow in the Modum basement, it was possible for shallow fluids to penetrate basement rocks at significantly higher temperatures, and this demonstrates the potential for hydrolytic weakening of continental crust by sedimentary fluids.     

The origin of overpressure in 'old' sedimentary basins: an example from the Cooper Basin, Australia

Overpressure in ‘old’ sedimentary basins that have not undergone rapid, recent sedimentation cannot be easily explained using traditional burial‐driven mechanisms. The last significant burial event in the Cooper Basin, Australia, was the Late Cretaceous deposition of the Winton Formation (98.5–90 Ma). Maximum temperature in the basin was attained during the Late Cretaceous, with cooling beginning prior to 75 Ma. Hence, overpressure related to rapid burial or palaeomaximum temperatures (e.g. hydrocarbon generation) must have developed prior to 75 Ma. Retaining overpressure for 75 Ma in ‘old’ basins such as the Cooper Basin requires extremely low seal permeabilities. An alternative explanation is that overpressure in the Cooper Basin has been generated because of an increase in mean stress associated with an increase in horizontal compressive stress since Late Cretaceous times. Structural observations and contemporary stress data indicate that there has been an increase in mean stress of approximately 50 MPa between Late Cretaceous times to that presently measured at 3780 m. The largest measured overpressure in the Cooper Basin is 14.5 MPa at 3780 m in the Kirby 1 well. Hence, disequilibrium compaction driven by increasing mean stress can explain the magnitude of the observed overpressure in the Cooper Basin. Increases in mean stress (tectonic loading) may be a feasible mechanism for overpressure generation in other ‘old’ basins that have undergone a recent increase in horizontal stress (e.g. Anadarko Basin).     

Seismic constraints on the effects of gas hydrate on sediment physical properties and fluid flow: a review

The formation of gas hydrates in marine sediments changes their physical properties and hence influences fluid flow. Here, we review seismic indicators of gas hydrates and relate these indicators to gas hydrate formation and fluid migration. Analyses of seismic data from sediments containing gas and gas hydrates in a variety of locations have shown that the characteristic bottom‐simulating reflector (BSR), which commonly marks the hydrate phase boundary is caused mainly by the presence of gas beneath the gas hydrate stability zone (GHSZ). The amplitude of the BSR is also dependent on the hydrate concentration and on the porosity of the sediment. The presence of gas hydrate alters the elastic properties of sediments, particularly if it cements sediment grains. However, multifrequency studies in various geological provinces show that any loss of reflectivity or blanking observed within the GHSZ is dependent on both the nature of the sediments and concentration of hydrate present. Gas beneath the BSR may cause amplitude anomalies and may result in bright spots and enhanced reflections. The presence of gas beneath the BSR is the primary cause of observed amplitude versus offset (AVO) anomalies, but the amplitude of these anomalies is also dependent on the amount of cementation brought by the gas hydrates within the GHSZ. Fluid migration appears to play an important role in the formation and dissociation of gas hydrates in both active and passive margin settings. Fluid migration in accretionary prisms influences hydrate accumulation and may therefore control the spatial distribution of BSRs. Fluid migration may influence also the type of hydrate formed by bringing thermogenic gas containing higher order hydrocarbons to the GHSZ from below. Fluid advection may cause local dissociation of gas hydrates by bringing heat from below, thus shifting the gas hydrate phase boundary. Fluid flow within the GHSZ is limited by the formation of hydrate in the pore space, which reduces the permeability of the sediment. Features such as pockmarks, acoustic masking and acoustic turbidity are indirect indicators of fluid flow and identification of these features in seismic sections within and beneath the GHSZ may also suggest the formation of gas hydrate.     

Magmatic fluids immiscible with silicate melts: examples from inclusions in phenocrysts and glasses, and implications for magma evolution and metal transport

The first occurrence of immiscibility in magmas appears to be most important in the magmatic–hydrothermal transition, and thus studies of magmatic immiscibility should be primarily directed towards recognition of coexisting silicate melt and essentially non-silicate liquids and fluids (aqueous, carbonic and sulphide). However, immiscible phase separation during decompression, cooling and crystallization of magmas is an inherently fugitive phenomenon. The only remaining evidence of this process and the closest approximation of natural immiscible magmatic liquids and vapours can be provided by melt and fluid inclusions trapped in silicate glasses and magmatic phenocrysts. Such inclusions are often used as a natural experimental laboratory to model the process of exsolution and the compositions of volatile-rich phases from a wide range of terrestrial magmas. In this paper several examples from recent research on melt and fluid inclusions are used to demonstrate the significance of naturally occurring immiscibility in understanding some large-scale magma chamber processes, such as degassing and partitioning of metals.     

Sources and composition of fluids associated with fluorite deposits of Asturias (N Spain)

The fluorite deposits of Asturias (northern Iberian Peninsula) are hosted by rocks of Permo‐Triassic and Palaeozoic age. Fluid inclusions in ore and gangue minerals show homogenization temperatures from 80 to 170°C and the presence of two types of fluids: an H₂O–NaCl low‐salinity fluid (<8 eq. wt% NaCl) and an H₂O–NaCl–CaCl₂ fluid (7–13 wt% NaCl and 11–14 wt% CaCl₂). The low salinity and the Cl/Br and Na/Br ratios (Cl/Br_molar 100–700 and Na/Br_molar 20–700) are consistent with an evaporated sea water origin of this fluid. The other end‐member of the mixture was highly saline brine with high Cl/Br and Na/Br ratios (Cl/Br_molar 700–13 000 and Na/Br_molar 700–11 000) generated after dissolution of Triassic age evaporites. LA‐ICP‐MS analyses of fluid inclusions in fluorite reveal higher Zn, Pb and Ba contents in the high‐salinity fluids (160–500, 90–170, 320–480 p.p.m. respectively) than in the low‐salinity fluid (75–230, 25–150 and 100–300 p.p.m. respectively). The metal content of the fluids appears to decrease from E to W, from Berbes to La Collada and to Villabona. The source of F is probably related to leaching of volcanic rocks of Permian age. Brines circulated along faults into the Palaeozoic basement. Evaporated sea water was present in permeable rocks and faults along or above the unconformity between the Permo‐Triassic sediments and the Palaeozoic basement. Mineralization formed when the deep brines mixed with the surficial fluids in carbonates, breccias and fractures resulting in the formation of veins and stratabound bodies of fluorite, barite, calcite, dolomite and quartz and minor amounts of sulphides. Fluid movement and mineralization occurred between Late Triassic and Late Jurassic times, probably associated with rifting events related to the opening of the Atlantic Ocean. This model is also consistent with the geodynamic setting of other fluorite‐rich districts in Europe.     

Application of fluorescence lifetime measurements on single petroleum-bearing fluid inclusions to demonstrate multicharge history in petroleum reservoirs

Petroleum-bearing fluid inclusions emit fluorescent light when excited with UV or visible light. The fluorescence decay time of the emission is dependent upon the wavelengths of the excitation and emission light, and the chemical composition of the petroleum oil. In general heavy oils have short lifetimes, whereas the emission from light oils is much longer lived. One can thus use plots of the fluorescence lifetime versus emission wavelength ( τ – λ plots), to show even subtle changes in the chemical composition of the entrapped oil. As a consequence, these τ – λ plots can be used for fluid inclusion research to discriminate different oil populations in situ . In particular, it is demonstrated that τ – λ plots discriminate two sets of inclusion oils in each of four North Atlantic basins [Jeanne d'Arc Basin (Newfoundland), Porcupine Basin (Ireland), Clair field West of Shetland (UK) and Kangerlussuaq Basin (East Greenland)] where multistage oil charge is inferred from other geological evidence.     

Modeling fluid flow in a heterogeneous, fault-controlled hydrothermal system

Previous studies have shown that most hydrothermal systems discharging at the land surface are associated with faulting, and that the location, temperature and rate of discharge of these systems are controlled by the geometry and style of the controlling fault(s). Unfortunately, the transport of heat and fluid in fault-controlled hydrothermal systems is difficult to model realistically; although heterogeneity and anisotropy are assumed to place important controls on flow in faults, few data or observations are available to constrain the distribution of hydraulic properties within active faults. Here, analytical and numerical models are combined with geostatistical models of spatially varying hydraulic properties to model the flow of heat and fluid in the Borax Lake fault of south-east Oregon, USA. A geometric mean permeability within the fault of 7 × 10⁻¹⁴ m² with 2× vertical/horizontal anisotropy in correlation length scale is shown to give the closest match to field observations. Furthermore, the simulations demonstrate that continuity of flow paths is an important factor in reproducing the observed behavior. In addition to providing some insight into possible spatial distributions of hydraulic properties at the Borax Lake site, the study highlights one potential avenue for integrating field observations with simulation results in order to gain greater understanding of fluid flow in faults and fault-controlled hydrothermal and petroleum reservoirs.     

Regional groundwater flow and interactions with deep fluids in western Apennine: the case of Narni‐Amelia chain (Central Italy)

The elemental fluxes and heat flow associated with large aquifer systems can be significant both at local and at regional scales. In fact, large amounts of heat transported by regional groundwater flow can affect the subsurface thermal regime, and the amount of matter discharged towards the surface by large spring systems can be significant relative to the elemental fluxes of surface waters. The Narni‐Amelia regional aquifer system (Central Italy) discharges more than 13 m³ sec^?1 of groundwater characterised by a slight thermal anomaly, high salinity and high pCO₂. During circulation in the regional aquifer, groundwater reacts with the host rocks (dolostones, limestones and evaporites) and mixes with deep CO₂‐rich fluids of mantle origin. These processes transfer large amounts of dissolved substances, in particular carbon dioxide, and a considerable amount of heat towards the surface. Because practically all the water circulating in the Narni‐Amelia system is discharged by few large springs (Stifone‐Montoro), the mass and energy balance of these springs can give a good estimation of the mass and heat transported from the entire system towards the surface. By means of a detailed mass and balance of the aquifer and considering the soil CO₂ fluxes measured from the main gas emission of the region, we computed a total CO₂ discharge of about 7.8 × 10⁹ mol a^?1 for the whole Narni‐Amelia system. Finally, considering the enthalpy difference between infiltrating water and water discharged by the springs, we computed an advective heat transfer related to groundwater flow of 410 ± 50 MW.     

Geological controls on regional transmissivity anisotropy

A variety of data indicate that the Carbonate aquifer in southern Manitoba is a heterogeneous and anisotropic aquifer wherein groundwater flow follows preferred flow path networks. Specific capacity tests show that aquifer transmissivity can vary by up to four orders of magnitude within 1 km. Geostatistical analysis reveals a strong anisotropy in the transmissivity field, with better spatial continuity in NE–SW and NW–SE directions, coincident with the dominant orientations of fractures observed in bedrock exposures. However, discrepancies between the orientation of highest fracture density and best transmissivity continuity suggest that either additional geological factors control the preferred flow network or there is a biased representation of the fracture pattern because all direct fracture observations came from the northern part of the study area. In an effort to investigate whether the geographically biased fracture data set represents the fracture pattern for the whole region, Landsat images and digital elevation maps were processed to extract linear features that may indicate subsurface fracture zones in areas where bedrock is covered by glacial sediments. The results suggest a consistent fracture pattern throughout the study area, indicating that the two observed fracture groups might have gone through different processes in terms of permeability development. Alteration by mineral cementation and dissolution along fracture surfaces may have preferentially improved the fracture permeability in one orientation, while reducing it in the other. The in situ stress field is also believed to play a major role in the preferred regional flow network. This paper discusses the evidence for the preferred flow path network and possible geological factors controlling aquifer anisotropy in this region.     

Fluid dynamics and fluid‐structural relationships in the Red Lake mine trend,Red Lake greenstone belt,Ontario, Canada

The Red Lake mine trend, a deformation zone in the Archean Red Lake greenstone belt that hosts the world‐class Campbell‐Red Lake gold deposit, is characterized by abundant foliation‐parallel iron‐carbonate ± quartz veins with banded colloform‐crustiform structures and cockade breccias overprinted by silicification and gold mineralization. There is an apparent incompatibility between the cavity‐fill structures of the veins and breccias (typically developed at shallow crustal depths) and the upper greenschist to lower amphibole facies metamorphic conditions recorded in the host rocks (indicating relatively deep environments). This, together with the development of veins along the foliation plane, represents an enigmatic problem that may be related to the interplay between fluid dynamics and stress field. We approach this problem through systematic study of fluid inclusion planes (FIPs) in the vein minerals, including the orientations of the FIPs and the pressure–temperature conditions inferred from fluid inclusion microthermometry. We find that fluid inclusions in the main stage vein minerals (pregold mineralization ankerite and quartz and syn‐ore quartz) are predominantly carbonic without a visible aqueous phase, whereas many inclusions in the postore stage contain an aqueous phase. Most FIPs are subvertical, and many are subparallel to the foliation. High fluid pressure coupled with the high wetting angles of the water‐poor, carbonic fluids may have been responsible for the abundance of brittle deformation features. The development of subvertical FIPs is interpreted to indicate episodic switching of the maximum principal compressive stress (σ₁) from subhorizontal (perpendicular to the foliation) to subvertical (parallel to the foliation) orientation. The subvertical σ₁ is favorable for the formation of foliation‐parallel veins, as fractures are preferentially opened along the foliation in such a stress regime, the origin of which may be linked to the fluid source.