Gas breakthrough experiments on pelitic rocks: comparative study with N2, CO2 and CH4

The capillary‐sealing efficiency of intermediate‐ to low‐permeable sedimentary rocks has been investigated by N₂, CO₂ and CH₄ breakthrough experiments on initially fully water‐saturated rocks of different lithological compositions. Differential gas pressures up to 20 MPa were imposed across samples of 10–20 mm thickness, and the decline of the differential pressures was monitored over time. Absolute (single‐phase) permeability coefficients (k_abs), determined by steady‐state fluid flow tests, ranged between 10^?22 and 10^?15 m². Maximum effective permeabilities to the gas phase k_eff(max), measured after gas breakthrough at maximum gas saturation, extended from 10^?26 to 10^?18 m². Because of re‐imbibition of water into the interconnected gas‐conducting pore system, the effective permeability to the gas phase decreases with decreasing differential (capillary) pressure. At the end of the breakthrough experiments, a residual pressure difference persists, indicating the shut‐off of the gas‐conducting pore system. These pressures, referred to as the ‘minimum capillary displacement pressures’ (P_d), ranged from 0.1 up to 6.7 MPa. Correlations were established between (i) absolute and effective permeability coefficients and (ii) effective or absolute permeability and capillary displacement pressure. Results indicate systematic differences in gas breakthrough behaviour of N₂, CO₂ and CH₄, reflecting differences in wettability and interfacial tension. Additionally, a simple dynamic model for gas leakage through a capillary seal is presented, taking into account the variation of effective permeability as a function of buoyancy pressure exerted by a gas column underneath the seal.     

Monitoring and Management Options in the Preservation of Urban Waterlogged Deposits,Nantwich, UK

A baseline survey in 2007 characterized the physical and chemical conditions for preservation within waterlogged remains at Nantwich. Installation of eighteen dipwells has allowed a five-year monitoring programme to be conducted from 2011. Two add-on projects supplemented this monitoring programme by examining the different methods for redox measurement, and for soil moisture measurement using Time Domain Reflectometry (TDR).

Initial results show two main zones of preservation, with reducing conditions attributed to location of the deposits in the floodplain, and a second zone uphill with more variable conditions for preservation. This study shows that sediment-coring programmes combined with dipwell installations can provide useful data to assess and monitor in situ preservation conditions, which can help to formulate management strategies for conservation of waterlogged archaeological deposits. This paper focuses on the efficacy of the methodology, referencing in particular comparative monitoring techniques and lists a series of recommendations for future studies.