Anthropological and physicochemical investigation of the burnt remains of Tomb IX in the ‘Sa Figu’ hypogeal necropolis (Sassari,Italy) – Early Bronze Age

Excavations carried out in Tomb IX of the hypogeic necropolis of ‘Sa Figu’, near the village of Ittiri (Sassari, Italy), supplied burnt human bone remains and pottery unambiguously referred to the Early Bronze Age (characterised by the local culture of ‘Bonnannaro’). Besides the anthropological study, we have investigated and evaluated the possibility of a funerary cremation practice in Sardinian pre‐history, a subject that has previously not been considered from a scientific point of view. Making use of a calibration procedure based on X‐ray diffraction (XRD) line‐broadening analysis, related to the microstructural properties, it was possible to estimate the combustion temperature to which the fragmented bones were subjected. It was found that the studied bones reached temperatures varying from 400°C up to a maximum of 850°C. This spread of values suggested inhomogeneous combustion of the bones, which seems compatible with funerary cremation practices. Copyright © 2007 John Wiley & Sons, Ltd.     

‘Not All That Is White Is Lime’—White Substances from Archaeological Burial Contexts: Analyses and Interpretations

Archaeological burial contexts may include a variety of white substances, but few analyses have been published. This study reports on the physico‐chemical characterization of such residues from seven archaeological sites. It is often assumed that white materials from burial contexts are lime. Our findings demonstrate that they can be gypsum, calcite (chalk), aragonite, brushite, degraded metal, natural (gum) resins or synthetic polymer–based products. These may be present as the result of diagenetic processes, funerary practices or modern contamination. This paper provides an analytical approach for the holistic investigation of white materials encountered in burial contexts.     

Analytical study of Roman and Arabic wall paintings in the Patio De Banderas of Reales Alcazares’ Palace using non-destructive XRD/XRF and complementary techniques

A portable XRD/XRF system and complementary laboratory techniques were employed to improve the knowledge of the procedures used to create Roman and Arabic wall paintings. Integrated physico-chemical investigations were conducted on fragments of artworks collected from the archaeological excavation of the Patio de Banderas in the Reales Alcazares’ Palace of Seville (Spain), and a comparative study on the pigments from both historical periods was performed. As a result, pigments such as vermilion, red ochre, yellow ochre, green earth, Egyptian blue, carbon and phosphor-based black pigments were detected in Roman samples; however, in the Arabic fragments, only haematite was observed. In addition, the size and shape of the particles of the wall paintings were studied with an XRD 2-dimensional detector and SEM-EDX.     

Florence baptistery: chemical and mineralogical investigation of glass mosaic tesserae

A recent restoration of the mosaics of the Baptistery in Florence enabled the collection and analysis of a group of glass tesserae. Twenty-three tesserae, dated between the end of the 13th century and the first half of the 14th century, showing different colors were sampled and analyzed to identify the raw materials, colorants and opacifiers employed in their production.     

Pre-Roman glass from Mozia (Sicily-Italy): the first archaeometrical data

This study present the results of an archaeometrical investigation performed on a series of opaque pre-Roman glass (vessels and ornaments) dated from the 6th to 4th century BC coming from Sicily. Sixteen core formed vessels, twelve beads, three pendants and one spindle-whorl recovered in the Phoenician-Punic sites of Mozia and Birgi were analysed thought a micro destructive approach. The complete chemical analyses and X-Ray diffraction analyses were performed on small fragments of glass. The aims of this work are: 1) to obtain a chemical characterization of these samples in order to understand the raw materials employed for their production; 2) to obtain information regarding the opacifying phases dispersed in the glass; 3) to make a comparison with the results recently obtained on coeval and similar finds recovered in other cultural context, in particular in Northern Italian Etruscan contexts in order to understand whether they could belong to the same Greek-Eastern production.     

Discovery of Beeswax as binding agent on a 6th-century BC Chinese Turquoise-inlaid Bronze sword

Recent archaeological field surveys and excavations at Qiaojiayuan, a platform 40 km west of the Yun County in present-day northwestern Hubei Province (central China), revealed four tombs (M₃, M₄, M₅ and M₆) dating back to around 6th to 5th century BC. The grave's layout, artifact assemblages and burial practice indicate that the owners of these four graves were aristocrats of the Chu state. Five turquoise-inlaid bronze artifacts (two swords and three dagger-axes) were excavated. The sword from M₄, imbedded with pieces of well-cut and finely-polished turquoise on its handle, was in a very bad state of preservation and underwent conservation treatment. Some sticky, whitish pastes were exposed when the inlaid turquoises dropped off. The pastes were supposed to be residues of unknown binding agents. Samples of the pastes were collected for FTIR (Fourier Transform Infrared Spectroscopy) and XRD (X-Ray Diffraction) analyses to determine the chemical component(s). The results revealed that the pastes were composed of almost pure beeswax. This indicated that beeswax was used as binding agent in turquoise-inlaid bronzes as early as the 6th to 5th century BC in China. Review of recent technical studies suggested that beeswax was used in early China in several different regions (mostly southern part of China) for at least two different purposes (binding agent and lightening).     

THE DETERMINATION OF BRICK PROVENANCE AND TECHNOLOGY USING ANALYTICAL TECHNIQUES FROM THE PHYSICAL SCIENCES*†

This work applies established analytical techniques from the physical sciences to Irish brick, in order to gather evidence of ceramic technologies, provenance and sources of raw materials. Petrographic microscopy, X‐ray diffractometry and scanning electron microscopy with an energy‐dispersive X‐ray diffraction attachment were used to study the brick of Rathfarham Castle, Dublin, built c. 1618, where clay brick was introduced in 1771. Local clay was fired in the laboratory and analysed in a similar manner. The petrography of the pointing mortar was studied in order to gather evidence of ceramic provenance. This paper concludes that the brick was hand‐ moulded with a silica‐based, predominantly non‐calcareous clay of glacial origin, gathered locally, including fluxes and a high percentage of non‐plastic material. The mineralogy and petrography of the brick, together with the presence of pebbles and a coarse matrix, suggest that the raw clay was probably gathered from a glacial deposit. The presence of abundant pebbles and colour inhomogeneities suggests a lack of processing of the raw clay. The brick was probably fired in clamps at top firing temperatures ranging from 750°C to above 900°C. Transformation of limestone temper involving the breakdown of calcite and the generation of calcium silicates, and the new formation of plagioclase, high‐temperature quartz, hematite and spinel were revealed. The presence of spinel in ‘hot spots’ indicates that fuel was added to the raw clay in order to assist firing.     

Effect of natural polymers from cissus glauca roxb on the mechanical and durability properties of hydraulic lime mortar

The tradition of using lime as a binder has been in practice over the centuries and is cited in the architectural feats of all kinds of civilizations. Besides the basic ingredients of lime, sand and water, organic admixtures were also mixed into the mortars to modify fresh and hardened state properties as well as to enhance its durability. The motivation of the present study was to develop a replacement of synthetic admixtures by the bio-admixtures. The plant extract of Cissus glauca Roxb (CGR) which is being used in ancient temples and monuments in Kerala has been tested as admixture in varying concentrations and fermentation periods in lime mortar mix. The admixture is polysaccharide rich and a moisturizing agent.

Tests were conducted to measure changes in microstructure of the mortar; fresh state properties such as setting time and workability, mechanical properties such as compressive strength and flexural strength. Also, physical characteristics of admixture modified mortars such as bulk density, porosity and water absorption were also determined. Morphological analysis using SEM with EDX, mineralogical analysis using XRD and organic analysis adopting FT- IR have been done to validate the results of mechanical and physical tests. Capillary water and salt absorption by suction and resistance to salt crystallization cycles were measured as an indicator of durability properties.

The admixture modified mortar resulted in increased mechanical properties and reduced water absorption. It also limits the capillary rise of water and salt intrusion through the hydrophobic nature. The admixture modified mortar have also offered better resistance against the damaging action of deteriorating salts such as sodium chloride and sodium sulphate crystallization cycles. Polysaccharides and proteins in the plant extract interact with the calcium hydroxide of slaked lime and forms complexes. Hence the, natural polymer has increased the durability of hydraulic lime mortars used for repair and it could be a natural alternative to synthetic admixture.