BULK STABLE LIGHT ISOTOPIC RATIOS IN RECENT AND ARCHAEOLOGICAL RESINS: TOWARDS DETECTING THE TRANSPORT OF RESINS IN ANTIQUITY?*

We have applied and refined methods for the determination of bulk hydrogen, carbon and oxygen isotope ratios in modern and archaeological resins. The modern resins have a wide range of isotopic values and vary within the same tree, between individual trees, with species and location. For all isotopes measured, there is a general trend of increasing depletion of the heavier isotope with increasing altitude. There is also a linear trend between depletion of δD and δ¹³C values with increasing latitude; this trend is less clear for oxygen, but is related to the meteoric water line. Two case studies using archaeological resins known or suspected to have been transported in antiquity have been investigated to determine whether isotopic signatures can assist in pinpointing the geographical origin of the resin: Pistacia sp. resin from Canaanite amphorae imported into Egypt from known geographical locations in the eastern Mediterranean during the Late Bronze Age, and Roman amphorae sherds lined with Pinus sp. resin from sites ranging from Britain to the eastern Mediterranean. These results show separate groupings between the two resin types (pine/pistacia) and between the modern/archaeological resins. Some archaeological samples are distinct from the others and the modern resins show differences between geographical areas. However, there are no clear patterns relating the different Canaanite fabrics or the suggested manufacturing site of the Roman amphorae.     

LITHIC RESOURCES IN THE EARLY PREHISTORY OF THE ALPS*

Rocks, which are ubiquitous in archaeological sites as chipped or polished tools, were important factors in the prehistoric Alpine economic system. Archaeometric characterization and identification of source areas open the path to a more detailed understanding of the production and diffusion mechanisms behind Alpine lithic industries. An overview of the situation from the eastern to the western Alps in the Mesolithic, the Neolithic and the Copper Age illustrates current debates and issues.     

AN INVESTIGATION OF THE PROVENANCE OF THE ROMAN AMPHORA CARGO FROM THE PLEMMIRIO B SHIPWRECK

Eighty-six Roman amphora sherds from the Plemmirio B shipwreck, off Sicily, have been analysed by neutron activation analysis. A large group representative of the amphora cargo, mainly of forms Africana 1 and Africana 2A (from the area of modern Tunisia), was subsequently defined. No differences between Africana 1 and Africana 2A samples were observed, thus implying a similar origin for both forms. The provenance of this cargo group was then investigated by comparison with a Roman amphora kiln data base. After elimination of the more mobile elements it was shown that the cargo amphorae were more likely to have been manufactured at kilns around Sullecthum rather than Leptis Minor. The analytical conclusions are thoroughly consistent with the known archaeological information.     

LEAD ISOTOPE CHARACTERISTICS OF THE CYPRUS COPPER ORE DEPOSITS APPLIED TO PROVENANCE STUDIES OF COPPER OXHIDE INGOTS

Nearly 200 new lead isotope analyses of sulphidic and oxidized ores from 26 copper mines on Cyprus show that the mines from different geological regions group in five distinctive isotopic groups, each with a substructure, related to the geological history of the ore formation. Comparison of lead isotope compositions of Bronze Age artefacts with these data can in many cases reveal the actual mines from which the copper for particular artefacts was obtained. The particular case of the provenance of the copper for 78 Late Bronze Age copper ‘oxhide ingots’found in Cyprus, Crete, Greece, Sardinia, Turkey and Bulgaria is discussed. The data show that all oxhide ingots so far analysed, dating to the fourteenth century BC and later, were made of copper consistent isotopically with only one mining region in the geographical north of Cyprus, and especially the Apliki mine. The study provides further evidence which supports the validity of the conventional approach to the use of lead isotope analysis for provenancing metals; this evidence is antithetical to recent suggestions of a model for the production of copper oxhide ingots which involved widespread mixing of copper from a number of ore sources throughout the Mediterranean.     

THE ESTABLISHMENT OF A DATA BASE OF NEUTRON ACTIVATION ANALYSES OF WHITE MARBLE*

The establishment of a data base of trace element analysis results obtained by neutron activation analysis of 183 marble samples, each weighing about 200 mg, from eight different quarrying localities for use in provenance studies is described and a summary of the results presented. The problems of sampling museum artefacts are discussed, and details of tests of the reproducibility of the technique are given together with those obtained from multiple-samples from single museum objects. Replicate analyses of a marble standard are also discussed. Thus these data are a measure of the accuracy and precision of the technique, as well as allowing an assessment of the variation in trace element composition within quarry sources and single blocks of marble, as used for artefacts.     

IN VITRO DECOMPOSITION OF BONE COLLAGEN BY SOIL BACTERIA: THE IMPLICATIONS FOR STABLE ISOTOPE ANALYSIS IN ARCHAEOMETRY*

To understand biogenic collagen type I decomposition and to establish how diagenesis may bias archaeometric data, modern mammalian bone was inoculated with a selection of ubiquitous soil bacteria. The presence of exogenous microbial biomass in the inoculated specimens was then checked microscopically prior to collagen extraction. The experimentally degraded bone collagen showed altered amino acid compositions, attributable to the selective breakdown of certain amino acids by the bacteria. While both the bulk collagen extract and the single amino acids exhibited shifts to more negative δ¹³ C-values, enrichment was recorded for general δ¹³ N, and a depletion trend relative to unaltered collagen was observed for individual amino acid δ¹³ N. One explanation for the enrichment of the global δ¹⁵N-values is cleavage of peptide bonds, which leaves ¹⁵ N within the substrate, while the change of ¹³C is mostly due to the altered amino acid composition. On the other hand, possible repolymerization of cleavage products under experimental conditions may also be responsible for the depletion trend of individual amino acid δ¹³C- and δ¹⁵ N-values. This paper discusses the results as a basis for the development of a method for the reconstruction of the isotopic abundance of the original collagen, using the amino acid composition of the degraded product, the contribution of individual amino acids to its global δ-values and of isotope discriminations implied in the microbial decomposition.     

Bone Modifications Resulting from Captive Chimpanzee Mastication: Implications for the Interpretation of Pliocene Archaeological Faunas

In order to obtain chimpanzee (Pan troglodytes) mastication damage on bones, cleaned, disarticulated ribs and long bones of bovids and cervids were coated with food substances found palatable by captive chimpanzees. The bones were then presented to four groups of mixed sex and mixed age chimpanzees from the Tulsa Zoo (Oklahoma) and the Southwest Foundation for Biomedical Research (San Antonio, Texas). In the process of feeding on the coated bones, the chimpanzees inflicted discernible mastication damage on 73·61% of the total recovered bone specimens. Analysis of these chimpanzee-induced bone modifications reveals that non-technological hominoids of the same approximate size and with comparable dentition and bite force to the gracile australopithecines and earliestHomoare very capable of inflicting the same range and degree of damage to bones as are feeding carnivores. This finding implies that zooarchaeologists must take a contextual (configurational) approach when analysing mastication damage on arch-aeological bones, rather than automatically attributing all such damage to carnivores.     

TRACE ELEMENT GEOCHEMISTRY OF NATIVE COPPER FROM THE WHITE PINE MINE,MICHIGAN (USA): IMPLICATIONS FOR SOURCING ARTEFACTS*

Eighty-five samples of native copper from the White Pine mine in upper Michigan were analysed by neutron activation to document geochemical variability within a single locality. Silver, sodium, antimony and scandium contents vary by two orders of magnitude, whereas arsenic values vary by three orders of magnitude. This variability reinforces the need for provenance studies of artefacts to examine sufficient samples to test for heterogeneity within the source area. The White Pine suite contains some of the most impure native copper that has been analysed to date. Arsenic and silver values of these impure samples overlap with those of European coppers, but consideration of several elements can still distinguish native copper from European copper.     

AMPHORAE FROM LYONS: PETROGRAPHIC AND CHEMICAL ARGUMENTS*

This paper briefly presents a method for the interpretation of quantitative petrographic data and chemical composition data from amphorae found in Lyons with the aim of determining whether or not the amphorae are of local production. We will try to define the exact place of each argument in our reasoning about the attribution of the origin of these ceramics, while insisting on the zones of uncertainty for each method. It is important to emphasize here that in assigning the origin of the Lyons amphorae all the arguments must be used conjointly. The presence of rhyolite in the temper is not enough to determine the Lyons origin of an amphora, and the geochemical arguments are often insufficient to make a decision. It is a reasoned application of petrographic, geochemical and archaeological arguments which enables us to pronounce an attribution.