A STUDY OF GLASS TESSERAE FROM MOSAICS IN THE MONASTERIES OF DAPHNI AND HOSIOS LOUKAS (GREECE)

In this work 51 glass mosaic tesserae from decorations of the two Greek monasteries of Daphni and Hosios Loukas were analysed by inductively coupled plasma optical emission spectroscopy, electron microprobe analysis and X‐ray powder diffraction. On the basis of the chemical analyses, after discrimination between the tesserae of the original decorations and those from other periods, it was possible to outline the distinctive traits of Byzantine mosaic tesserae. In both the monasteries, the original mosaics were decorated with tesserae produced with plant ash based glass, either of the typical composition or a mixture with natron type glass. The samples from the Hosios Loukas decorations show a more homogeneous composition compared with those from Daphni. The major differences among the original samples are due to the presence of opacifiers and colourants.     

IDENTIFICATION AND DIFFERENTIATION OF OPAQUE CHINESE OVERGLAZE YELLOW ENAMELS BY RAMAN SPECTROSCOPY AND SUPPORTING TECHNIQUES*

Using Raman spectroscopy, energy-dispersive X-ray fluorescence and X-ray diffraction, the Pb–Sn–Sb triple oxide yellow and lead–tin yellow have been identified on two pieces of cloisonné enamel (Falangcai) porcelains. Lead–tin yellow and lead antimonate yellow have been identified on famille rose porcelains manufactured before and after 1911, respectively. The replacement of the Pb–Sn–Sb triple oxide yellow by lead–tin yellow and that of the lead–tin yellow by lead antimonate yellow are discussed.     

INTERPRETING THE SOCIAL MEANING OF DIFFERENT SHAPES OF HOUSE STRUCTURES BY EXAMINING THE FLOW OF RESOURCES: A CASE STUDY OF SAQACENGALJ AT THE SOUTHERN TIP OF TAIWAN

Social differentiation is characterized by differences in social status and wealth, which are established and maintained by controlling and constraining the labour and flow of resources. This would affect the development of various aspects of a settlement in establishing hierarchical relationships. This study focuses on identifying the variations in the distribution of certain resources, such as imported goods, that help interpret the social meaning, particularly with regard to social status and wealth, of house structures having different shapes in an ethnic settlement in Taiwan. A petrographic study and residue analysis of the pottery along with spatial examination of the material remains were conducted to achieve the goal.     

NON‐DESTRUCTIVE SOURCING OF BRONZE AGE NEAR EASTERN OBSIDIAN ARTEFACTS: REDEVELOPING AND REASSESSING ELECTRON MICROPROBE ANALYSIS FOR OBSIDIAN SOURCING*

Despite predictions in the 1980s that electron microprobe analysis (EMPA) would become a popular technique for obsidian sourcing, few studies have used it with this goal, and most of them are now outdated and unrepresentative of modern EMPA. For example, Merrick and Brown (1984 ) recorded their data on punch cards. Furthermore, these studies destructively prepared artefacts for analysis. The research at hand endeavoured: (1) to establish the modern capabilities of EMPA for obsidian sourcing; and (2) to develop and evaluate procedures for non‐destructive artefact analysis. Issues such as diagenetic effects and compatibility with NAA and XRF data were also investigated.     

SELECTION AND HEATING OF COLOURING MATERIALS IN THE MOUSTERIAN LEVEL OF ES‐SKHUL (c. 100 000 YEARS BP,MOUNT CARMEL,ISRAEL)

The transformation of yellow goethite into red hematite by heating has long been assumed for Palaeolithic red artefacts excavated close to fireplaces. However, this transformation is extremely rare. Using SEM–FEG–EDX, PIXE–PIGE, TEM and μXRD, we characterized the mineralogical and chemical compositions of four microsamples of colouring materials from the Mousterian layer B in the es‐Skhul rock‐shelter, from about 100 kya ago. For some colouring materials, the Mousterian people of es‐Skhul chose to gather remote yellow lumps for heating. Their significant transport distance provides evidence of the possible high cultural value of these colouring materials for transformation into red pigments.     

SYNCHROTRON FTIR MICRO‐SPECTROSCOPY APPLIED TO THE STUDY OF POLISHED SERPENTINITE ARTEFACTS: A NON‐DESTRUCTIVE ANALYTICAL APPROACH

In prehistory, serpentinite was one of the most frequently used raw materials to produce polished stone artefacts. Several conventional analytical techniques can be applied to identify the serpentine minerals, but their application generally requires a powdered sample. This implies that the artefacts to be analysed must be damaged, and the possibility of analysing a mixture of different serpentine polytypes is high. The use of spatially resolved techniques is therefore a necessity to overcome this problem. Several thin sections of serpentinitic rocks and prehistoric axes have been analysed by synchrotron radiation Fourier transform infrared micro‐spectroscopy. The spectra were acquired directly on specific points of polished stone artefacts and this allowed the recognition of the different polytypes of serpentine minerals without causing any damage to the objects. The results show the infrared micro‐spectroscopy technique to be a useful tool for the characterization of archaeological lithic material.     

A PROVENANCE STUDY OF FRENCH LIMESTONE BASED ON VARIABLE SELECTION FROM COMPOSITIONAL PROFILES

The present study shows how multivariate analysis and variable selection techniques can be used in archaeological provenances studies to improve classification performances. Neutron activation analysis (NAA), in combination with stepwise linear discrimination analysis (SLDA) (capable of simultaneously performing variable selection and classification), was applied to differentiate among limestone samples from different quarries across the north of France based on their compositional fingerprint. A hierarchical classification approach was followed, aimed at progressively assigning limestone samples to more specific sources of origin, from the broadest classification units (French regions) to the narrowest ones (individual quarries). The application of the stepwise variable selection procedure to extract the most discriminating compositional variables prior to each classification development allowed us to obtain a perfect separation between the limestone categories considered at every classification stage (all samples were correctly classified and predicted in all cases). The high‐quality results obtained were even more remarkable considering the relatively small number of significant variables selected in each case using the SLDA method. An illustrative example was provided in order to demonstrate that the classification strategy proposed can actually allocate an unknown sculpture to a particular quarry of origin.     

GAMBLING WITH ETRUSCAN DICE: A TALE OF NUMBERS AND LETTERS

The graphical and linguistic interpretation of the first six Etruscan numerals has long been confronted with the ambiguous assignment of the words huth and sa to either 4 or 6. Here, we show how the systematic combinatorial analysis of the numerals appearing on ancient southern Etrurian dice dated from the eighth to the third centuries bc , together with the careful comparison of the results with the only two existing dice carrying the alphabetical translations of the numerals conserved at the Bibliothèque Nationale de France, Paris, finally allows unambiguous mathematical resolution of the linguistic riddle, allowing the firm attribution of the numeral 6 to the graphical value huth and 4 to sa. Combinatorial analysis of the numerals distribution on the six faces of the die shows that only two of the 15 possible numerical combinations were actually in use in southern Etruria, and that during the fifth century bc there was a marked shift from the typical (1–2, 3–4, 5–6) combination used in the early seventh‐ to fifth‐century bc dice to the (1–6, 2–5, 3–4) combination used at later times and still largely adopted today. The largest body of archaeometric data on dice specimens from Etruria is presented, based on macroscopic examination, X‐ray diffraction, DRIFT spectroscopy and density measurements.     

PREHISTORIC CULTURE,CLIMATE AND AGRICULTURE AT YUCHISI,ANHUI PROVINCE,CHINA

A palaeoculture sediment profile from the Yuchisi site, Mengcheng County of Anhui Province, China, was sampled to study the concentrations of elements, total carbon content, grain size and pollen percentages, to reveal information on food supply based on statistical analysis of elements between 5050 cal. yr bp and 4000 cal. yr bp . The variations in the reconstructed food supply and pollen percentages are in good agreement with the results of other archaeological methods. The results from pollen and element analyses indicate that the Longshan Culture at the Yuchisi site was not developed from the local Dawenkou Culture, and the cultural transition corresponds with an extremely dry event, which may have caused the change.     

UNIQUE PRE‐ROMANESQUE MURALS IN KOSTOĽANY POD TRÍBEČOM,SLOVAKIA: THE PAINTING TECHNIQUE AND CAUSES OF DAMAGE

Pre‐Romanesque murals at Kosto?any pod Tríbe?om, Slovakia, have been investigated by portable X‐ray fluorescence and by microanalytical methods to identify painting materials (pigments and binders), and to explain the degradation of colours. Today, missing green and blue shades have been reconstructed according to residual concentrations of Cu, which correspond to copper chlorides—products of salt corrosion of the copper carbonates azurite and/or malachite, accelerated by micro‐organisms. As confirmed by powder X‐ray microdiffraction, original minium (Pb₃O₄) has been transformed to brown–black plattnerite (PbO₂). In increased humidity, even insoluble pigments are washing down from the walls and the intensity of colours further diminishes.